{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["14(1)"],"submitter":["Li H"],"pubmed_abstract":["The removal of nitric oxide is an important environmental issue, as well as a necessary prerequisite for achieving high efficiency of CO<sub>2</sub> electroreduction. To this end, the electrocatalytic denitrification is a sustainable route. Herein, we employ reaction phase diagram to analyze the evolution of reaction mechanisms over varying catalysts and study the potential/pH effects over Pd and Cu. We find the low N<sub>2</sub> selectivity compared to N<sub>2</sub>O production, consistent with a set of experiments, is limited fundamentally by two factors. The N<sub>2</sub>OH* binding is relatively weak over transition metals, resulting in the low rate of as-produced N<sub>2</sub>O* protonation. The strong correlation of OH* and O* binding energies limits the route of N<sub>2</sub>O* diss"],"journal":["Nature communications"],"pagination":["112"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9825404"],"repository":["biostudies-literature"],"pubmed_title":["Steering from electrochemical denitrification to ammonia synthesis."],"pmcid":["PMC9825404"],"pubmed_authors":["Li H","Jing H","Long J","Xiao J"],"additional_accession":[]},"is_claimable":false,"name":"Steering from electrochemical denitrification to ammonia synthesis.","description":"The removal of nitric oxide is an important environmental issue, as well as a necessary prerequisite for achieving high efficiency of CO<sub>2</sub> electroreduction. To this end, the electrocatalytic denitrification is a sustainable route. Herein, we employ reaction phase diagram to analyze the evolution of reaction mechanisms over varying catalysts and study the potential/pH effects over Pd and Cu. We find the low N<sub>2</sub> selectivity compared to N<sub>2</sub>O production, consistent with a set of experiments, is limited fundamentally by two factors. The N<sub>2</sub>OH* binding is relatively weak over transition metals, resulting in the low rate of as-produced N<sub>2</sub>O* protonation. The strong correlation of OH* and O* binding energies limits the route of N<sub>2</sub>O* diss","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jan","modification":"2026-03-27T15:41:30.067Z","creation":"2025-04-05T10:27:32.297Z"},"accession":"S-EPMC9825404","cross_references":{"pubmed":["36611030"],"doi":["10.1038/s41467-023-35785-w"]}}