{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Sievers R"],"funding":["DFG Deutsche Forschungsgemeinschaft"],"pagination":["e202211147"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9826324"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(43)"],"pubmed_abstract":["The reaction of AgBF<sub>4</sub> and [Rh(COD)Cl]<sub>2</sub> (COD=1,5-cyclooctadiene) in presence of [NEt<sub>4</sub> ][C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ] afforded the fluorocarbon soluble complex [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> )] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ]<sup>-</sup> ligand, since its first synthesis in 1980. In addition to [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> )] also the byproduct [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>4</sub> H)] was isolated and fully characterized. Accompanying DFT studies showed that the interaction energy of the [C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ]<sup>-</sup> ligand towa"],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry."],"pmcid":["PMC9826324"],"funding_grant_id":["387284271 - SFB 1349"],"pubmed_authors":["Sievers R","Malischewski M","Sellin M","Rupf SM","Parche J"],"additional_accession":[]},"is_claimable":false,"name":"Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry.","description":"The reaction of AgBF<sub>4</sub> and [Rh(COD)Cl]<sub>2</sub> (COD=1,5-cyclooctadiene) in presence of [NEt<sub>4</sub> ][C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ] afforded the fluorocarbon soluble complex [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> )] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ]<sup>-</sup> ligand, since its first synthesis in 1980. In addition to [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> )] also the byproduct [Rh(COD)(C<sub>5</sub> (CF<sub>3</sub> )<sub>4</sub> H)] was isolated and fully characterized. Accompanying DFT studies showed that the interaction energy of the [C<sub>5</sub> (CF<sub>3</sub> )<sub>5</sub> ]<sup>-</sup> ligand towa","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Oct","modification":"2026-03-27T15:40:14.293Z","creation":"2025-02-18T23:35:38.05Z"},"accession":"S-EPMC9826324","cross_references":{"pubmed":["35984742"],"doi":["10.1002/anie.202211147"]}}