biostudies-literatureSievers RDFG Deutsche Forschungsgemeinschafte202211147https://www.ebi.ac.uk/biostudies/studies/S-EPMC9826324biostudies-literatureUnknown61(43)The reaction of AgBF₄ and [Rh(COD)Cl]₂ (COD=1,5-cyclooctadiene) in presence of [NEt₄ ][C₅ (CF₃ )₅ ] afforded the fluorocarbon soluble complex [Rh(COD)(C₅ (CF₃ )₅ )] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C₅ (CF₃ )₅ ]^- ligand, since its first synthesis in 1980. In addition to [Rh(COD)(C₅ (CF₃ )₅ )] also the byproduct [Rh(COD)(C₅ (CF₃ )₄ H)] was isolated and fully characterized. Accompanying DFT studies showed that the interaction energy of the [C₅ (CF₃ )₅ ]^- ligand towaAngewandte Chemie (International ed. in English)Introducing the Perfluorinated Cp* Ligand into Coordination Chemistry.PMC9826324387284271 - SFB 1349Sievers RMalischewski MSellin MRupf SMParche JfalseIntroducing the Perfluorinated Cp* Ligand into Coordination Chemistry.The reaction of AgBF₄ and [Rh(COD)Cl]₂ (COD=1,5-cyclooctadiene) in presence of [NEt₄ ][C₅ (CF₃ )₅ ] afforded the fluorocarbon soluble complex [Rh(COD)(C₅ (CF₃ )₅ )] by salt metathesis. This complex represents the first example for a successful coordination of the weakly basic [C₅ (CF₃ )₅ ]^- ligand, since its first synthesis in 1980. In addition to [Rh(COD)(C₅ (CF₃ )₅ )] also the byproduct [Rh(COD)(C₅ (CF₃ )₄ H)] was isolated and fully characterized. Accompanying DFT studies showed that the interaction energy of the [C₅ (CF₃ )₅ ]^- ligand towa2022-01-01T00:00:00Z2022 Oct2026-03-27T15:40:14.293Z2025-02-18T23:35:38.05ZS-EPMC98263243598474210.1002/anie.202211147