{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wang L"],"funding":["Energy Frontier Research Centers","Office of Accelerator R and D and Production","Directorate for Mathematical and Physical Sciences"],"pagination":["e202207834"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9827883"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(45)"],"pubmed_abstract":["The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal-organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe<sub>5</sub> (C<sub>6</sub> O<sub>6</sub> )<sub>3</sub> , which is a fusion of 2D Fe-semiquinoid materials and 3D cubic Fe<sub>x</sub> (C<sub>6</sub> O<sub>6</sub> )<sub>y</sub> materials, by using a different initial redox-state of the C<sub>6</sub> O<sub>6</sub> linker. The material displays high electrical conductivity (0.02 S cm<sup>-1</sup> ), broad electronic transitions, promising thermoelectric behavior (S<sup>2</sup> σ=7.0×10<sup>-9</sup>  W m<sup>-1</sup>  K<sup>-2</sup> ),"],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers."],"pmcid":["PMC9827883"],"funding_grant_id":["DMR-2002367","DE-SC0012702","DE-AC02-06CH11357"],"pubmed_authors":["Sarkar A","Cheng B","Filatov AS","Ma T","Papoular RJ","Wang L","Zhao N","Horwitz NE","Xie J","Grocke GL","Campisi D","Gagliardi L","Anderson JS"],"additional_accession":[]},"is_claimable":false,"name":"Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers.","description":"The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal-organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe<sub>5</sub> (C<sub>6</sub> O<sub>6</sub> )<sub>3</sub> , which is a fusion of 2D Fe-semiquinoid materials and 3D cubic Fe<sub>x</sub> (C<sub>6</sub> O<sub>6</sub> )<sub>y</sub> materials, by using a different initial redox-state of the C<sub>6</sub> O<sub>6</sub> linker. The material displays high electrical conductivity (0.02 S cm<sup>-1</sup> ), broad electronic transitions, promising thermoelectric behavior (S<sup>2</sup> σ=7.0×10<sup>-9</sup>  W m<sup>-1</sup>  K<sup>-2</sup> ),","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-21T14:00:50.175Z","creation":"2025-04-21T14:00:50.175Z"},"accession":"S-EPMC9827883","cross_references":{"pubmed":["36070987"],"doi":["10.1002/anie.202207834"]}}