biostudies-literatureWang LEnergy Frontier Research CentersOffice of Accelerator R and D and ProductionDirectorate for Mathematical and Physical Sciencese202207834https://www.ebi.ac.uk/biostudies/studies/S-EPMC9827883biostudies-literatureUnknown61(45)The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal-organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe₅ (C₆ O₆ )₃ , which is a fusion of 2D Fe-semiquinoid materials and 3D cubic Fe_x (C₆ O₆ )_y materials, by using a different initial redox-state of the C₆ O₆ linker. The material displays high electrical conductivity (0.02 S cm^-1 ), broad electronic transitions, promising thermoelectric behavior (S² σ=7.0×10^-9  W m^-1  K^-2 ),Angewandte Chemie (International ed. in English)Linker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers.PMC9827883DMR-2002367DE-SC0012702DE-AC02-06CH11357Sarkar ACheng BFilatov ASMa TPapoular RJWang LZhao NHorwitz NEXie JGrocke GLCampisi DGagliardi LAnderson JSfalseLinker Redox Mediated Control of Morphology and Properties in Semiconducting Iron-Semiquinoid Coordination Polymers.The emergence of conductive 2D and less commonly 3D coordination polymers (CPs) and metal-organic frameworks (MOFs) promises novel applications in many fields. However, the synthetic parameters for these electronically complex materials are not thoroughly understood. Here we report a new 3D semiconducting CP Fe₅ (C₆ O₆ )₃ , which is a fusion of 2D Fe-semiquinoid materials and 3D cubic Fe_x (C₆ O₆ )_y materials, by using a different initial redox-state of the C₆ O₆ linker. The material displays high electrical conductivity (0.02 S cm^-1 ), broad electronic transitions, promising thermoelectric behavior (S² σ=7.0×10^-9  W m^-1  K^-2 ),2022-01-01T00:00:00Z2022 Nov2025-04-21T14:00:50.175Z2025-04-21T14:00:50.175ZS-EPMC98278833607098710.1002/anie.202207834