{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Garcon M"],"funding":["European Research Council","“la Caixa” Foundation","Australian Nuclear Science and Technology Organisation","Royal Society","la Caixa Foundation"],"pagination":["e202211948"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9828084"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["61(44)"],"pubmed_abstract":["New heterometallic hydride complexes that involve the addition of {Mg-H} and {Zn-H} bonds to group 10 transition metals (Pd, Pt) are reported. The side-on coordination of a single {Mg-H} to Pd forms a well-defined σ-complex. In contrast, addition of three {Mg-H} or {Zn-H} bonds to Pd or Pt results in the formation of planar complexes with subtly different geometries. We compare their structures through experiment (X-ray diffraction, neutron diffraction, multinuclear NMR), computational methods (DFT, QTAIM, NCIPlot), and theoretical analysis (MO diagram, Walsh diagram). These species can be described as snapshots along a continuum of bonding between ideal trigonal planar and hexagonal planar geometries."],"journal":["Angewandte Chemie (International ed. in English)"],"pubmed_title":["The Continuum Between Hexagonal Planar and Trigonal Planar Geometries."],"pmcid":["PMC9828084"],"funding_grant_id":["P6932 and DB8477","LCF/BQ/EU19/11710077","677367","UF090149"],"pubmed_authors":["Sackman GA","Phanopoulos A","Richardson C","Garcon M","Crimmin MR","White AJP","Cooper RI","Edwards AJ"],"additional_accession":[]},"is_claimable":false,"name":"The Continuum Between Hexagonal Planar and Trigonal Planar Geometries.","description":"New heterometallic hydride complexes that involve the addition of {Mg-H} and {Zn-H} bonds to group 10 transition metals (Pd, Pt) are reported. The side-on coordination of a single {Mg-H} to Pd forms a well-defined σ-complex. In contrast, addition of three {Mg-H} or {Zn-H} bonds to Pd or Pt results in the formation of planar complexes with subtly different geometries. We compare their structures through experiment (X-ray diffraction, neutron diffraction, multinuclear NMR), computational methods (DFT, QTAIM, NCIPlot), and theoretical analysis (MO diagram, Walsh diagram). These species can be described as snapshots along a continuum of bonding between ideal trigonal planar and hexagonal planar geometries.","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-21T14:06:07.177Z","creation":"2025-04-21T14:06:07.177Z"},"accession":"S-EPMC9828084","cross_references":{"pubmed":["36094744"],"doi":["10.1002/anie.202211948"]}}