{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Diehl T"],"funding":["Deutsche Forschungsgemeinschaft","DFG, German Research Foundation","German Federal Ministry of Education and Research (BMBF)","Kopernikus Project P2X"],"pagination":["e202201250"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9828205"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["15(22)"],"pubmed_abstract":["Catalytic conversion of CO<sub>2</sub> and hydrogen to methanol was achieved in a self-separating multiphasic system comprising the tailor-made complex [Ru(CO)ClH(MACHO-C<sub>12</sub> )] (MACHO-C<sub>12</sub> =bis{2-[bis(4-dodecylphenyl)phosphino]ethyl}amine) in n-decane as the catalyst phase. Effective catalyst recycling was demonstrated for the carbonate and the amine-assisted pathway from CO<sub>2</sub> to methanol. The polar products MeOH or MeOH/H<sub>2</sub> O generated from the catalytic reactions spontaneously formed a separate phase, allowing product isolation and catalyst separation without the need for any additional solvent. In the amine-assisted hydrogenation of CO<sub>2</sub> , the catalyst phase was recycled over ten subsequent runs, reaching a total turnover number to MeOH "],"journal":["ChemSusChem"],"pubmed_title":["A Self-Separating Multiphasic System for Catalytic Hydrogenation of CO<sub>2</sub> and CO<sub>2</sub> -Derivatives to Methanol."],"pmcid":["PMC9828205"],"funding_grant_id":["390919832","03SFK2 A0-2"],"pubmed_authors":["Francio G","Leitner W","Diehl T","Lanzerath P"],"additional_accession":[]},"is_claimable":false,"name":"A Self-Separating Multiphasic System for Catalytic Hydrogenation of CO<sub>2</sub> and CO<sub>2</sub> -Derivatives to Methanol.","description":"Catalytic conversion of CO<sub>2</sub> and hydrogen to methanol was achieved in a self-separating multiphasic system comprising the tailor-made complex [Ru(CO)ClH(MACHO-C<sub>12</sub> )] (MACHO-C<sub>12</sub> =bis{2-[bis(4-dodecylphenyl)phosphino]ethyl}amine) in n-decane as the catalyst phase. Effective catalyst recycling was demonstrated for the carbonate and the amine-assisted pathway from CO<sub>2</sub> to methanol. The polar products MeOH or MeOH/H<sub>2</sub> O generated from the catalytic reactions spontaneously formed a separate phase, allowing product isolation and catalyst separation without the need for any additional solvent. In the amine-assisted hydrogenation of CO<sub>2</sub> , the catalyst phase was recycled over ten subsequent runs, reaching a total turnover number to MeOH ","dates":{"release":"2022-01-01T00:00:00Z","publication":"2022 Nov","modification":"2025-04-21T14:03:54.174Z","creation":"2025-04-21T14:03:54.174Z"},"accession":"S-EPMC9828205","cross_references":{"pubmed":["36107441"],"doi":["10.1002/cssc.202201250"]}}