{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["14(3)"],"submitter":["Wang W"],"pubmed_abstract":["The utilization of dative B←N bonds for the creation of crystalline organic framework (BNOF) has increasingly received intensive interest; however, the shortage of permanent porosity is an obstacle that must be overcome to guarantee their application as porous materials. Here, we report the first microporous crystalline framework, BNOF-1, that is assembled through sole monomers, which can be scalably synthesized by the cheap 4-pyridine boronic acid. The 2D networks of BNOF-1 were stacked in parallel to generate a highly porous supramolecular open framework, which possessed not only the highest BET surface area of 1345 m<sup>2</sup> g<sup>-1</sup> amongst all of the BNOFs but also features a record-high uptake of C<sub>2</sub>H<sub>2</sub> and CO<sub>2</sub> in covalent organic framework (C"],"journal":["Chemical science"],"pagination":["533-539"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9847669"],"repository":["biostudies-literature"],"pubmed_title":["Dative B←N bonds based crystalline organic framework with permanent porosity for acetylene storage and separation."],"pmcid":["PMC9847669"],"pubmed_authors":["Hou L","Zhu Z","Du F","Wang W","Liu B","Wang GD","Wang YY","Wang L"],"additional_accession":[]},"is_claimable":false,"name":"Dative B←N bonds based crystalline organic framework with permanent porosity for acetylene storage and separation.","description":"The utilization of dative B←N bonds for the creation of crystalline organic framework (BNOF) has increasingly received intensive interest; however, the shortage of permanent porosity is an obstacle that must be overcome to guarantee their application as porous materials. Here, we report the first microporous crystalline framework, BNOF-1, that is assembled through sole monomers, which can be scalably synthesized by the cheap 4-pyridine boronic acid. The 2D networks of BNOF-1 were stacked in parallel to generate a highly porous supramolecular open framework, which possessed not only the highest BET surface area of 1345 m<sup>2</sup> g<sup>-1</sup> amongst all of the BNOFs but also features a record-high uptake of C<sub>2</sub>H<sub>2</sub> and CO<sub>2</sub> in covalent organic framework (C","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jan","modification":"2025-04-05T13:31:24.834Z","creation":"2025-04-05T13:31:24.834Z"},"accession":"S-EPMC9847669","cross_references":{"pubmed":["36741528"],"doi":["10.1039/d2sc06016g"]}}