{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Garci F"],"funding":["Deutsche Forschungsgemeinschaft","Tunisian Ministry of Higher Education and Scientific Research"],"pagination":["731"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9866386"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["28(2)"],"pubmed_abstract":["Two isomeric 2-bromomethylpyridine Cu(II) complexes [Cu(C<sub>6</sub>H<sub>9</sub>NBr)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] with 2-bromo-5-methylpyridine (L<sup>1</sup>) and 2-bromo-4-methylpyridine (L<sup>2</sup>) were synthesized as air-stable blue materials in good yields. The crystal structures were different with [Cu(L<sup>1</sup>)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] (<b>CuL<sup>1</sup></b>) crystallizing in the monoclinic space group <i>P</i>2<sub>1</sub>/c, while the 4-methyl derivative <b>CuL<sup>2</sup></b> was solved and refined in triclinic <i>P</i>1¯. The orientation of the Br substituents in the molecular structure (<i>anti</i> (<b>CuL<sup>1</sup></b>) vs. <i>syn</i> (<b>CuL<sup>2</sup></b>) conformations) and the geometry around Cu(II) in an overall 4 + 2 distorted c"],"journal":["Molecules (Basel, Switzerland)"],"pubmed_title":["Structure, Optical and Magnetic Properties of Two Isomeric 2-Bromomethylpyridine Cu(II) Complexes [Cu(C<sub>6</sub>H<sub>9</sub>NBr)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] with Very Different Binding Motives."],"pmcid":["PMC9866386"],"funding_grant_id":["DI 1788/2-1","Hammouda Chebbi"],"pubmed_authors":["Garci F","Disch S","Chebbi H","Sebastian SS","Ruschewitz U","Haseloer A","Klein A","Rochels L","Rouzbeh N","Anthony ET","Zid MF"],"additional_accession":[]},"is_claimable":false,"name":"Structure, Optical and Magnetic Properties of Two Isomeric 2-Bromomethylpyridine Cu(II) Complexes [Cu(C<sub>6</sub>H<sub>9</sub>NBr)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] with Very Different Binding Motives.","description":"Two isomeric 2-bromomethylpyridine Cu(II) complexes [Cu(C<sub>6</sub>H<sub>9</sub>NBr)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] with 2-bromo-5-methylpyridine (L<sup>1</sup>) and 2-bromo-4-methylpyridine (L<sup>2</sup>) were synthesized as air-stable blue materials in good yields. The crystal structures were different with [Cu(L<sup>1</sup>)<sub>2</sub>(NO<sub>3</sub>)<sub>2</sub>] (<b>CuL<sup>1</sup></b>) crystallizing in the monoclinic space group <i>P</i>2<sub>1</sub>/c, while the 4-methyl derivative <b>CuL<sup>2</sup></b> was solved and refined in triclinic <i>P</i>1¯. The orientation of the Br substituents in the molecular structure (<i>anti</i> (<b>CuL<sup>1</sup></b>) vs. <i>syn</i> (<b>CuL<sup>2</sup></b>) conformations) and the geometry around Cu(II) in an overall 4 + 2 distorted c","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jan","modification":"2025-05-29T20:01:44.743Z","creation":"2024-11-06T14:19:34.806Z"},"accession":"S-EPMC9866386","cross_references":{"pubmed":["36677789"],"doi":["10.3390/molecules28020731"]}}