biostudies-literatureUnknown13(5)He CSoft body armor with a strain-sensing function using conductive shear thickening fluids (STFs) has gradually gained research interest. In this study, conductive SiO2@Ag core-shell microspheres were synthesized and the influence of process parameters on their properties was evaluated. Subsequently, SiO2 and SiO2@Ag were used as dispersed phases to prepare two-phase STFs, the effect of the core-shell microspheres' proportion on the rheological properties of the STFs was investigated, and its mechanism was discussed. The results indicated that SiO2@Ag core-shell microspheres were coated with elemental silver and when the concentration of sodium hydroxide and glucose were 0.07 and 0.09 mol L-1, respectively, the coating surface was the most uniform and compact, and the conductivity reached the minimum value of 0.56 Ω cm. The two-phase STFs exhibited good and reversible shear thickening behaviors and the critical shear rate decreased with increasing core-shell microsphere concentration. Additionally, when the mass fraction of SiO2 and SiO2@Ag core-shell microspheres was 45% and 20%, respectively, the thickening rate was 325%, and the resistance of two-phase STFs decreased simultaneously with the emergence of shear thickening that reached the lowest value of 795.16 kΩ. This study provides a novel strategy for synthesizing conductive STFs for strain-sensing flexible stab-resistant composites.RSC advances3112-3122https://www.ebi.ac.uk/biostudies/studies/S-EPMC9869083biostudies-literatureSynthesis and properties of SiO2/SiO2@Ag two-phase STFs.PMC9869083He CLiu JWang QSun RChen MJia XfalseSynthesis and properties of SiO2/SiO2@Ag two-phase STFs.Soft body armor with a strain-sensing function using conductive shear thickening fluids (STFs) has gradually gained research interest. In this study, conductive SiO2@Ag core-shell microspheres were synthesized and the influence of process parameters on their properties was evaluated. Subsequently, SiO2 and SiO2@Ag were used as dispersed phases to prepare two-phase STFs, the effect of the core-shell microspheres' proportion on the rheological properties of the STFs was investigated, and its mechanism was discussed. The results indicated that SiO2@Ag core-shell microspheres were coated with elemental silver and when the concentration of sodium hydroxide and glucose were 0.07 and 0.09 mol L-1, respectively, the coating surface was the most uniform and compact, and the conductivity reached the minimum value of 0.56 Ω cm. The two-phase STFs exhibited good and reversible shear thickening behaviors and the critical shear rate decreased with increasing core-shell microsphere concentration. Additionally, when the mass fraction of SiO2 and SiO2@Ag core-shell microspheres was 45% and 20%, respectively, the thickening rate was 325%, and the resistance of two-phase STFs decreased simultaneously with the emergence of shear thickening that reached the lowest value of 795.16 kΩ. This study provides a novel strategy for synthesizing conductive STFs for strain-sensing flexible stab-resistant composites.2023-01-01T00:00:00Z2023 Jan2025-04-18T20:46:39.311Z2025-04-07T08:46:56.438ZS-EPMC98690833675639310.1039/d2ra06895h