{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["14(1)"],"submitter":["Wang K"],"pubmed_abstract":["Electroluminescence efficiencies and stabilities of quasi-two-dimensional halide perovskites are restricted by the formation of multiple-quantum-well structures with broad and uncontrollable phase distributions. Here, we report a ligand design strategy to substantially suppress diffusion-limited phase disproportionation, thereby enabling better phase control. We demonstrate that extending the π-conjugation length and increasing the cross-sectional area of the ligand enables perovskite thin films with dramatically suppressed ion transport, narrowed phase distributions, reduced defect densities, and enhanced radiative recombination efficiencies. Consequently, we achieved efficient and stable deep-red light-emitting diodes with a peak external quantum efficiency of 26.3% (average 22.9% among "],"journal":["Nature communications"],"pagination":["397"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9873927"],"repository":["biostudies-literature"],"pubmed_title":["Suppressing phase disproportionation in quasi-2D perovskite light-emitting diodes."],"pmcid":["PMC9873927"],"pubmed_authors":["Chowdhury SN","Savoie BM","Finkenauer BP","Terlier T","Huang L","Gao H","Wei Z","Wang K","Meng X","Yao Y","Park JY","Chen Z","Graham KR","Guo TF","Coffey AH","Jin L","Lin ZY","Dou L","Atapattu HR","Zhu C","Boltasseva A","Zhang Z","Gao Y","Do TH","Ma K"],"additional_accession":[]},"is_claimable":false,"name":"Suppressing phase disproportionation in quasi-2D perovskite light-emitting diodes.","description":"Electroluminescence efficiencies and stabilities of quasi-two-dimensional halide perovskites are restricted by the formation of multiple-quantum-well structures with broad and uncontrollable phase distributions. Here, we report a ligand design strategy to substantially suppress diffusion-limited phase disproportionation, thereby enabling better phase control. We demonstrate that extending the π-conjugation length and increasing the cross-sectional area of the ligand enables perovskite thin films with dramatically suppressed ion transport, narrowed phase distributions, reduced defect densities, and enhanced radiative recombination efficiencies. Consequently, we achieved efficient and stable deep-red light-emitting diodes with a peak external quantum efficiency of 26.3% (average 22.9% among ","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jan","modification":"2025-04-21T23:11:38.172Z","creation":"2025-04-05T19:07:15.277Z"},"accession":"S-EPMC9873927","cross_references":{"pubmed":["36693860"],"doi":["10.1038/s41467-023-36118-7"]}}