{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["13(6)"],"submitter":["Hashidzume A"],"pubmed_abstract":["To realize sustainable societies, the production of organic compounds not based on fossil resources should be developed. Thus, C1 chemistry, utilizing one-carbon compounds as starting materials, has been of increasing importance. In particular, the formose reaction is promising because the reaction produces sugars (monosaccharides) from formaldehyde under basic conditions. On the other hand, since microwave (MW) induces the rotational motion of molecules, MW irradiation often improves the selectivity and efficiency of reactions. In this study, the formose reaction under MW irradiation was thus investigated under various conditions. The formose reaction proceeded very fast using 1.0 mol per kg formaldehyde and 55 mmol per kg calcium hydroxide (Ca(OH)<sub>2</sub>) as a catalyst at a high set"],"journal":["RSC advances"],"pagination":["4089-4095"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9890655"],"repository":["biostudies-literature"],"pubmed_title":["Preferential formation of specific hexose and heptose in the formose reaction under microwave irradiation."],"pmcid":["PMC9890655"],"pubmed_authors":["Nakahata M","Kamon Y","Deguchi N","Todokoro Y","Kuwahara S","Tanibayashi T","Hashidzume A","Michitaka T","Imai T","Ikeda T"],"additional_accession":[]},"is_claimable":false,"name":"Preferential formation of specific hexose and heptose in the formose reaction under microwave irradiation.","description":"To realize sustainable societies, the production of organic compounds not based on fossil resources should be developed. Thus, C1 chemistry, utilizing one-carbon compounds as starting materials, has been of increasing importance. In particular, the formose reaction is promising because the reaction produces sugars (monosaccharides) from formaldehyde under basic conditions. On the other hand, since microwave (MW) induces the rotational motion of molecules, MW irradiation often improves the selectivity and efficiency of reactions. In this study, the formose reaction under MW irradiation was thus investigated under various conditions. The formose reaction proceeded very fast using 1.0 mol per kg formaldehyde and 55 mmol per kg calcium hydroxide (Ca(OH)<sub>2</sub>) as a catalyst at a high set","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Jan","modification":"2025-04-04T12:56:00.904Z","creation":"2025-04-04T12:56:00.904Z"},"accession":"S-EPMC9890655","cross_references":{"pubmed":["36756559"],"doi":["10.1039/d2ra07249a"]}}