{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Ma H"],"funding":["Users with Excellence Program of Hefei Science Center CAS","National Key Research and Development Program","National Natural Science Foundation of China","National Key Research and Development Program of China"],"pagination":["e2203552"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9896047"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["10(4)"],"pubmed_abstract":["As a promising cathode material of sodium-ion batteries, Na<sub>3</sub> V<sub>2</sub> (PO<sub>4</sub> )<sub>3</sub> (NVP) has attracted extensive attention in recent years due to its high stability and fast Na<sup>+</sup> ion diffusion. However, the reversible capacity based on the two-electron reaction mechanism is not satisfactory limited by the inactive M1 lattice sites during the insertion/extraction process. Herein, self-supporting 3D porous NVP materials with different crystallinity are fabricated on carbon foam substrates by a facile electrostatic spray deposition method. The V<sup>5+</sup> /V<sup>4+</sup> redox couple is effectively activated and the three-electron reactions are realized in NVP for sodium storage by a proper crystallinity tuning. In a disordered NVP sample, an ultr"],"journal":["Advanced science (Weinheim, Baden-Wurttemberg, Germany)"],"pubmed_title":["Crystallinity Tuning of Na<sub>3</sub> V<sub>2</sub> (PO<sub>4</sub> )<sub>3</sub> : Unlocking Sodium Storage Capacity and Inducing Pseudocapacitance Behavior."],"pmcid":["PMC9896047"],"funding_grant_id":["2017YFA0402800","U1732160","2021HSC-UE009"],"pubmed_authors":["Li W","Wang P","Sheng Z","Zhao B","Ma H","Zhu X","Bai J","Sun Y","Mao Y"],"additional_accession":[]},"is_claimable":false,"name":"Crystallinity Tuning of Na<sub>3</sub> V<sub>2</sub> (PO<sub>4</sub> )<sub>3</sub> : Unlocking Sodium Storage Capacity and Inducing Pseudocapacitance Behavior.","description":"As a promising cathode material of sodium-ion batteries, Na<sub>3</sub> V<sub>2</sub> (PO<sub>4</sub> )<sub>3</sub> (NVP) has attracted extensive attention in recent years due to its high stability and fast Na<sup>+</sup> ion diffusion. However, the reversible capacity based on the two-electron reaction mechanism is not satisfactory limited by the inactive M1 lattice sites during the insertion/extraction process. Herein, self-supporting 3D porous NVP materials with different crystallinity are fabricated on carbon foam substrates by a facile electrostatic spray deposition method. The V<sup>5+</sup> /V<sup>4+</sup> redox couple is effectively activated and the three-electron reactions are realized in NVP for sodium storage by a proper crystallinity tuning. In a disordered NVP sample, an ultr","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Feb","modification":"2025-04-19T13:31:30.092Z","creation":"2025-04-19T13:31:30.092Z"},"accession":"S-EPMC9896047","cross_references":{"pubmed":["36504360"],"doi":["10.1002/advs.202203552"]}}