{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Wang Y"],"funding":["Dutch Research Council (NWO)"],"pagination":["669"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9905078"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["14(1)"],"pubmed_abstract":["Easy-to-manufacture Li<sub>2</sub>S-P<sub>2</sub>S<sub>5</sub> glass ceramics are the key to large-scale all-solid-state lithium batteries from an industrial point of view, while their commercialization is greatly hampered by the low room temperature Li<sup>+</sup> conductivity, especially due to the lack of solutions. Herein, we propose a nanocrystallization strategy to fabricate super Li<sup>+</sup>-conductive glass ceramics. Through regulating the nucleation energy, the crystallites within glass ceramics can self-organize into hetero-nanodomains during the solid-state reaction. Cryogenic transmission electron microscope and electron holography directly demonstrate the numerous closely spaced grain boundaries with enriched charge carriers, which actuate superior Li<sup>+</sup>-conduction as confirmed by variable-temperature solid-state nuclear magnetic resonance. Glass ceramics with a record Li<sup>+</sup> conductivity of 13.2 mS cm<sup>-1</sup> are prepared. The high Li<sup>+</sup> conductivity ensures stable operation of a 220 μm thick LiNi<sub>0.6</sub>Mn<sub>0.2</sub>Co<sub>0.2</sub>O<sub>2</sub> composite cathode (8 mAh cm<sup>-2</sup>), with which the all-solid-state lithium battery reaches a high energy density of 420 Wh kg<sup>-1</sup> by cell mass and 834 Wh L<sup>-1</sup> by cell volume at room temperature. These findings bring about powerful new degrees of freedom for engineering super ionic conductors."],"journal":["Nature communications"],"pubmed_title":["Self-organized hetero-nanodomains actuating super Li<sup>+</sup> conduction in glass ceramics."],"pmcid":["PMC9905078"],"funding_grant_id":["184.035.002"],"pubmed_authors":["Li J","Li C","Sheu HS","Hu Z","Cui L","Jiang F","Chen L","Chang CK","Qu H","Zhang S","Li X","Ju J","van Eck ERH","Cui G","Liu B","Ma J","Wang Y","Kentgens APM"],"additional_accession":[]},"is_claimable":false,"name":"Self-organized hetero-nanodomains actuating super Li<sup>+</sup> conduction in glass ceramics.","description":"Easy-to-manufacture Li<sub>2</sub>S-P<sub>2</sub>S<sub>5</sub> glass ceramics are the key to large-scale all-solid-state lithium batteries from an industrial point of view, while their commercialization is greatly hampered by the low room temperature Li<sup>+</sup> conductivity, especially due to the lack of solutions. Herein, we propose a nanocrystallization strategy to fabricate super Li<sup>+</sup>-conductive glass ceramics. Through regulating the nucleation energy, the crystallites within glass ceramics can self-organize into hetero-nanodomains during the solid-state reaction. Cryogenic transmission electron microscope and electron holography directly demonstrate the numerous closely spaced grain boundaries with enriched charge carriers, which actuate superior Li<sup>+</sup>-conduction as confirmed by variable-temperature solid-state nuclear magnetic resonance. Glass ceramics with a record Li<sup>+</sup> conductivity of 13.2 mS cm<sup>-1</sup> are prepared. The high Li<sup>+</sup> conductivity ensures stable operation of a 220 μm thick LiNi<sub>0.6</sub>Mn<sub>0.2</sub>Co<sub>0.2</sub>O<sub>2</sub> composite cathode (8 mAh cm<sup>-2</sup>), with which the all-solid-state lithium battery reaches a high energy density of 420 Wh kg<sup>-1</sup> by cell mass and 834 Wh L<sup>-1</sup> by cell volume at room temperature. These findings bring about powerful new degrees of freedom for engineering super ionic conductors.","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Feb","modification":"2026-03-15T16:07:54.624Z","creation":"2025-04-05T17:07:36.478Z"},"accession":"S-EPMC9905078","cross_references":{"pubmed":["36750573"],"doi":["10.1038/s41467-023-35982-7"]}}