{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Petrus R"],"funding":["Narodowe Centrum Nauki"],"pagination":["2197-2212"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9906784"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["62(5)"],"pubmed_abstract":["In this study, a new method for the synthesis of heterometallic 3d-4f alkoxides by the direct reaction of metallic lanthanides (La, Pr, Nd, Gd) with MCl<sub>2</sub> (M = Mn, Ni, Co) in 2-methoxyethanol was developed. The method was applied to the synthesis of the heterometallic oxo-alkoxide clusters [Ln<sub>4</sub>Mn<sub>2</sub>(μ<sub>6</sub>-O)(μ<sub>3</sub>-OR)<sub>8</sub>(HOR)<sub><i>x</i></sub>Cl<sub>6</sub>] (Ln = La (<b>1</b>), Nd (<b>2</b>), Gd (<b>3</b>); <i>x</i> = 0, 2, 4); [Pr<sub>4</sub>M<sub>2</sub>(μ<sub>6</sub>-O)(μ<sub>3</sub>-OR)<sub>8</sub>(HOR)<i><sub>x</sub></i>Cl<sub>6</sub>] (M = Co (<b>4</b>), Ni (<b>5</b>); <i>x</i> = 2, 4); and [Ln<sub>4</sub>Mn<sub>2</sub>(μ<sub>3</sub>-OH)<sub>2</sub>(μ<sub>3</sub>-OR)<sub>4</sub>(μ-OR)<sub>4</sub>(μ-Cl)<sub>2</sub>(HOR)<sub>4</s"],"journal":["Inorganic chemistry"],"pubmed_title":["Heterometallic 3d-4f Alkoxide Precursors for the Synthesis of Binary Oxide Nanomaterials."],"pmcid":["PMC9906784"],"funding_grant_id":["2018/29/B/ST5/00341"],"pubmed_authors":["Kowalinski A","Petrus R","Sobota P","Matuszak K","Lis T","Utko J"],"additional_accession":[]},"is_claimable":false,"name":"Heterometallic 3d-4f Alkoxide Precursors for the Synthesis of Binary Oxide Nanomaterials.","description":"In this study, a new method for the synthesis of heterometallic 3d-4f alkoxides by the direct reaction of metallic lanthanides (La, Pr, Nd, Gd) with MCl<sub>2</sub> (M = Mn, Ni, Co) in 2-methoxyethanol was developed. The method was applied to the synthesis of the heterometallic oxo-alkoxide clusters [Ln<sub>4</sub>Mn<sub>2</sub>(μ<sub>6</sub>-O)(μ<sub>3</sub>-OR)<sub>8</sub>(HOR)<sub><i>x</i></sub>Cl<sub>6</sub>] (Ln = La (<b>1</b>), Nd (<b>2</b>), Gd (<b>3</b>); <i>x</i> = 0, 2, 4); [Pr<sub>4</sub>M<sub>2</sub>(μ<sub>6</sub>-O)(μ<sub>3</sub>-OR)<sub>8</sub>(HOR)<i><sub>x</sub></i>Cl<sub>6</sub>] (M = Co (<b>4</b>), Ni (<b>5</b>); <i>x</i> = 2, 4); and [Ln<sub>4</sub>Mn<sub>2</sub>(μ<sub>3</sub>-OH)<sub>2</sub>(μ<sub>3</sub>-OR)<sub>4</sub>(μ-OR)<sub>4</sub>(μ-Cl)<sub>2</sub>(HOR)<sub>4</s","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Feb","modification":"2025-04-04T23:52:38.06Z","creation":"2025-04-04T23:52:38.06Z"},"accession":"S-EPMC9906784","cross_references":{"pubmed":["36696546"],"doi":["10.1021/acs.inorgchem.2c03872"]}}