biostudies-literaturePetrus RNarodowe Centrum Nauki2197-2212https://www.ebi.ac.uk/biostudies/studies/S-EPMC9906784biostudies-literatureUnknown62(5)In this study, a new method for the synthesis of heterometallic 3d-4f alkoxides by the direct reaction of metallic lanthanides (La, Pr, Nd, Gd) with MCl₂ (M = Mn, Ni, Co) in 2-methoxyethanol was developed. The method was applied to the synthesis of the heterometallic oxo-alkoxide clusters [Ln₄Mn₂(μ₆-O)(μ₃-OR)₈(HOR)_<i>x</i>Cl₆] (Ln = La (<b>1</b>), Nd (<b>2</b>), Gd (<b>3</b>); <i>x</i> = 0, 2, 4); [Pr₄M₂(μ₆-O)(μ₃-OR)₈(HOR)<i>_x</i>Cl₆] (M = Co (<b>4</b>), Ni (<b>5</b>); <i>x</i> = 2, 4); and [Ln₄Mn₂(μ₃-OH)₂(μ₃-OR)₄(μ-OR)₄(μ-Cl)₂(HOR)<sub>4</sInorganic chemistryHeterometallic 3d-4f Alkoxide Precursors for the Synthesis of Binary Oxide Nanomaterials.PMC99067842018/29/B/ST5/00341Kowalinski APetrus RSobota PMatuszak KLis TUtko JfalseHeterometallic 3d-4f Alkoxide Precursors for the Synthesis of Binary Oxide Nanomaterials.In this study, a new method for the synthesis of heterometallic 3d-4f alkoxides by the direct reaction of metallic lanthanides (La, Pr, Nd, Gd) with MCl₂ (M = Mn, Ni, Co) in 2-methoxyethanol was developed. The method was applied to the synthesis of the heterometallic oxo-alkoxide clusters [Ln₄Mn₂(μ₆-O)(μ₃-OR)₈(HOR)_<i>x</i>Cl₆] (Ln = La (<b>1</b>), Nd (<b>2</b>), Gd (<b>3</b>); <i>x</i> = 0, 2, 4); [Pr₄M₂(μ₆-O)(μ₃-OR)₈(HOR)<i>_x</i>Cl₆] (M = Co (<b>4</b>), Ni (<b>5</b>); <i>x</i> = 2, 4); and [Ln₄Mn₂(μ₃-OH)₂(μ₃-OR)₄(μ-OR)₄(μ-Cl)₂(HOR)<sub>4</s2023-01-01T00:00:00Z2023 Feb2025-04-04T23:52:38.06Z2025-04-04T23:52:38.06ZS-EPMC99067843669654610.1021/acs.inorgchem.2c03872