{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"omics_type":["Unknown"],"volume":["62(6)"],"submitter":["Audsley G"],"funding":["Tertiary Education Trust Fund"],"pubmed_abstract":["Two propeller-shaped chiral Co<sup>III</sup><sub>3</sub>Y<sup>III</sup> complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV-vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (<sup>1</sup>H, <sup>13</sup>C, and <sup>19</sup>F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a <sup>19</sup>F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented."],"journal":["Inorganic chemistry"],"pagination":["2680-2693"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9930122"],"repository":["biostudies-literature"],"pubmed_title":["Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR."],"pmcid":["PMC9930122"],"pubmed_authors":["Ulldemolins CP","Lai-Morrice J","Al-Hilaly Y","Audsley G","Essien NB","Akien GR","Coles SJ","Tizzard GJ","Kostakis GE","Carpenter H","Serpell LC"],"additional_accession":[]},"is_claimable":false,"name":"Chiral Co<sub>3</sub>Y Propeller-Shaped Chemosensory Platforms Based on <sup>19</sup>F-NMR.","description":"Two propeller-shaped chiral Co<sup>III</sup><sub>3</sub>Y<sup>III</sup> complexes built from fluorinated ligands are synthesized and characterized by single-crystal X-ray diffraction (SXRD), IR, UV-vis, circular dichroism (CD), elemental analysis, thermogravimetric analysis (TGA), electron spray ionization mass spectroscopy (ESI-MS), and NMR (<sup>1</sup>H, <sup>13</sup>C, and <sup>19</sup>F). This work explores the sensing and discrimination abilities of these complexes, thus providing an innovative sensing method using a <sup>19</sup>F NMR chemosensory system and opening new directions in 3d/4f chemistry. Control experiments and theoretical studies shed light on the sensing mechanism, while the scope and limitations of this method are discussed and presented.","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Feb","modification":"2025-04-03T22:57:12.474Z","creation":"2024-11-05T22:24:40.902Z"},"accession":"S-EPMC9930122","cross_references":{"pubmed":["36716401"],"doi":["10.1021/acs.inorgchem.2c03737"]}}