{"database":"biostudies-literature","file_versions":[],"scores":null,"additional":{"submitter":["Pei X"],"funding":["National Natural Science Foundation of China","Nanhu Scholars Program for Young Scholars of Xinyang Normal University"],"pagination":["1675"],"full_dataset_link":["https://www.ebi.ac.uk/biostudies/studies/S-EPMC9960431"],"repository":["biostudies-literature"],"omics_type":["Unknown"],"volume":["16(4)"],"pubmed_abstract":["Stimuli-responsive Pickering emulsions are recently being progressively utilized as advanced catalyzed systems for green and sustainable chemical conversion. Hierarchically porous metal-organic frameworks (H-MOFs) are regarded as promising candidates for the fabrication of Pickering emulsions because of the features of tunable porosity, high specific surface area and structure diversity. However, CO<sub>2</sub>-switchable Pickering emulsions formed by hierarchically porous zirconium-based MOFs have never been seen. In this work, a novel kind of the amine-functionalized hierarchically porous UiO-66-(OH)<sub>2</sub> (H-UiO-66-(OH)<sub>2</sub>) has been developed using a post-synthetic modification of H-UiO-66-(OH)<sub>2</sub> by (3-aminopropyl)trimethoxysilane (APTMS), 3-(2-aminoethylamino)p"],"journal":["Materials (Basel, Switzerland)"],"pubmed_title":["CO<sub>2</sub>-Switchable Hierarchically Porous Zirconium-Based MOF-Stabilized Pickering Emulsions for Recyclable Efficient Interfacial Catalysis."],"pmcid":["PMC9960431"],"funding_grant_id":["No","22003055"],"pubmed_authors":["Liu J","Xie Y","Xu D","Pei X","Song W","Wang Z"],"additional_accession":[]},"is_claimable":false,"name":"CO<sub>2</sub>-Switchable Hierarchically Porous Zirconium-Based MOF-Stabilized Pickering Emulsions for Recyclable Efficient Interfacial Catalysis.","description":"Stimuli-responsive Pickering emulsions are recently being progressively utilized as advanced catalyzed systems for green and sustainable chemical conversion. Hierarchically porous metal-organic frameworks (H-MOFs) are regarded as promising candidates for the fabrication of Pickering emulsions because of the features of tunable porosity, high specific surface area and structure diversity. However, CO<sub>2</sub>-switchable Pickering emulsions formed by hierarchically porous zirconium-based MOFs have never been seen. In this work, a novel kind of the amine-functionalized hierarchically porous UiO-66-(OH)<sub>2</sub> (H-UiO-66-(OH)<sub>2</sub>) has been developed using a post-synthetic modification of H-UiO-66-(OH)<sub>2</sub> by (3-aminopropyl)trimethoxysilane (APTMS), 3-(2-aminoethylamino)p","dates":{"release":"2023-01-01T00:00:00Z","publication":"2023 Feb","modification":"2025-04-04T21:43:45.535Z","creation":"2025-04-04T21:43:45.535Z"},"accession":"S-EPMC9960431","cross_references":{"pubmed":["36837307"],"doi":["10.3390/ma16041675"]}}