MetaboLights

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metabolites were identified by searching database, and the main databases were the HMDB (http://www.hmdb.ca/), Metlin ( https://metlin.scripps.edu/) and self-bu;it Database . MetaboLightsPublicLiquid Chromatography MS -Liquid Chromatography MS - alternating - reverse phaseThe LC-MS/MS analysis of sample was conducted on a Thermo UHPLC-Q Exactive HF-X system equipped with an ACQUITY HSS T3 column (100 mm × 2.1 mm i.d., 1.8 μm; Waters, USA) at Meiji Bio-Pharm Technology Co. Ltd. (Shanghai, China). The mobile phases consisted of 0.1% formic acid in water:acetonitrile (95:5, v/v) (solvent A) and 0.1% formic acid in acetonitrile:isopropanol:water (47.5:47.5, v/v) (solvent B). Positive ion mode separation gradient: 0-3 min, mobile phase B was increased from 0% to 20%; 3-4.5 min, mobile phase B was increased from 20% to 35%; 4.5-5 min, mobile phase B was increased from 35% to 100%; 5-6.3 min, mobile phase B was maintained at 100%; 6.3-6.4 min, mobile phase B was decreased from 100% to 0%; 6.4-8 min , mobile phase B was maintained at 0%. Separation gradient in negative ion mode: 0-1.5 min, mobile phase B rises from 0 to 5%; 1.5-2 min, mobile phase B rises from 5% to 10%; 2-4.5 min, mobile phase B rises from 10% to 30%; 4.5-5 min, mobile phase B rises from 30% to 100%; 5-6.3 min, mobile phase B linearly maintains 100%; 6.3-6.4 min, the mobile phase B decreased from 100% to 0%; 6.4-8 min, the mobile phase B was linearly maintained at 0%. The flow rate was 0.40 mL/min and the column temperature was 40℃.Ferulic acid alleviates aflatoxin B1-induced hepatic inflammation: targeting gut microbiota-mediated tryptophan-3-indoleacrylic acid metabolism to regulate the AhR/ferroptosis pathway.China Agricultural UniversityQianqian Wangcecummass spectrometry assayCecal content samples (50 mg) were homogenized in methanol-water (4:1, v/v) using a cryogenic grinder (50 Hz, 6 min), followed by centrifugation (13,000 g, 4 °C, 15 min). The supernatant was collected for analysis.Pekin (Duck (domestic))https://www.ebi.ac.uk/metabolights/MTBLS12942Xin Fang. fangxin@cau.edu.cn.Qiugang Ma. maqiugang@cau.edu.cn.Gaigai Wang. wanggaigai@cau.edu.cn.Yutong Fu. yutong.fu@sydney.edu.au.Qianqian Wang. China Agricultural University. No. 2 Yuanmingyuan West Road.Beijing.CHINA. wqq@cau.edu.cn.Yanan Wang. wyn@cau.edu.cn.Yongpeng Guo. guoyp@henau.edu.cn.Lihong Zhao. China Agricultural University. No. 2 Yuanmingyuan West Road.Beijing.CHINA. zhaolihongcau@cau.edu.cn.Zixin Li. lizzzx@cau.edu.cn.The pretreatment of LC/MS raw data was performed by Progenesis QI (Waters Corporation, Milford, USA) software, and a three-dimensional data matrix in CSV format was exported. The information in this three-dimensional matrix included: sample information, metabolite name and mass spectral response intensity. Internal standard peaks, as well as any known false positive peaks (including noise, column bleed, and derivatized reagent peaks), were removed from the data matrix, deredundant and peak pooled. Aflatoxin B1Ferulic acid1285156197@qq.comAfter anesthetizing the mice, the thoracic cavity was quickly dissected, the cecum was cut short, the cecum contents were removed, snap frozen in liquid nitrogen, and transferred to -80 for storageMetabolomicsThermo Scientific Vanquish UHPLC Systempooled quality control sampleferulic acidPekin (Duck (domestic))untargeted analysisThermo Scientific Q Exactive HF-XExploris480（Thermo Scientific ）Aflatoxin B1untargeted metabolitescecumThermo Scientific Vanquish Horizon UHPLC Systemexperimental sampleThermo Scientific Vanquish UHPLC Systempooled quality control sampleferulic acidPekin (Duck (domestic))untargeted analysisThermo Scientific Q Exactive HF-XExploris480（Thermo Scientific ）Aflatoxin B1untargeted metabolitescecumThermo Scientific Vanquish Horizon UHPLC Systemexperimental sampleThe mass spectrometric data were collected using a Thermo UHPLC-Q Exactive HF-X Mass Spectrometer equipped with an electrospray ionization (ESI) source operating in positive mode and negative mode. The optimal conditions were set as followed: source temperature at 425℃ ; sheath gas flow rate at 50 arb; Aux gas flow rate at 13 arb; ion-spray voltage floating (ISVF) at -3500V in negative mode and 3500V in positive mode, respectively; Normalized collision energy , 20-40-60V rolling for MS/MS. Full MS resolution was 60000, and MS/MS resolution was 7500. Data acquisition was performed with the Data Dependent Acquisition (DDA) mode. The detection was carried out over a mass range of 70-1050 m/z.Ethyl (2E,6Z)-dodecadienoateThreonyllysine1-Nonadecanoyl-glycero-3-phosphoethanolamine5-Methoxycanthin-6-oneN1,N10-DicoumaroylspermidineImidazolelactic acid(3b,20R,22R)-3,20,27-Trihydroxy-1-oxowitha-5,24-dienolide 3-glucosideBisacurone BMethylarbutin16alpha, 17-epoxy gibberellin A9Niazirin3a,7b,12a-Trihydroxy-5a-Cholanoic acidN-Succinyl-2-amino-6-ketopimelateGabazineGlycyl-HistidineCorylifol A3-Hydroxyanthranilic Acid2,3-Dimethyl-2-cyclohexen-1-oneBenzoateCnidilide13(S)-HpODE4-Hydroxyphenyl-2-propionic acidBenzyl alcohol, 4-(2,4-diamino-5-pyrimidinylmethyl)-2,6-dimethoxy-alpha,alpha-dimethyl-N-Acetyl-D-tryptophanTerazosinGamma-Tocopherol4-Methyl-2-oxo-2H-chromen-7-yl sulfamateN-[(2R)-6,7-Dihydroxy-3-oxo-1-sulfanylheptan-2-yl]acetamide2,4-Thiazolidinedicarboxylic acid, 2-methyl-MaltitolMillefinSativan3-Hydroxy-2-methylpyridine-4,5-dicarboxylateGlutamylisoleucineLactucinD-glycero-L-galacto-OctuloseHistidyllysine[(2S,3S,4S,5S,6R)-4,5-Dihydroxy-2,6-dimethyloxan-3-yl] hydrogen sulfateL-phenylalanyl-L-prolineDesmethyl Erlotinib23S,25,26-Trihydroxyvitamin D3Glutarate semialdehydeN-(3-Oxodecanoyl)-DL-Homoserine LactonePalmitaldehyde3-Hydroxydodecanedioic acidCoumarinate2-Propylglutaric acidYohimbine2,4-Dimethyl-1,3-oxazole-5-carboxylic acidN-(1-Deoxy-1-fructosyl)alanineUrsodeoxycholic acid 3-sulfateProstaglandin C1P-Tolyl SulfateDodecanedioic AcidGlyuranolideNeopetasitenine2-Methyl-4-pentenoic acid4-Morpholinepropanesulfonic acidLysoPC(14:1(9Z)/0:0)Decanedioic acid4-Methoxybenzenepropanol 1-(2-sulfoglucoside)5-(2-Furanyl)-1,2,3,4,5,6-hexahydro-7H-cyclopenta[b]pyridin-7-oneCrocin 5Crocin 4(-)-Huperzine A (HupA)2-(p-Acetamidophenyl)-2-ethylglutarimide3a,7a,12a,19-Tetrahydroxy-5b-cholanoic acid4-Acetamido-2-aminobutanoic acid11-Hydroxy-E4-neuroprostaneDide-O-methyl-4-O-alpha-D-glucopyranosylsimmondsin5-MethoxytryptamineAlprazolam6-(2,6-Dimethoxypyridin-3-yl)-9-ethoxy-8-methoxy-1,2,3,4,4a,10b-hexahydrophenanthridin-2-olAla-pheIsovalerylcarnitineProstaglandin A14-Amino-1-[5-(hydroxymethyl)oxolan-2-yl]pyrimidin-2-oneCridanimodProtocatechuic acid 4-glucosidePolypropyleneMethyl 3-benzoyloxy-8-(3-hydroxypropyl)-8-azabicyclo[3.2.1]octane-2-carboxylatePenicilloic acidBile acidBarogeninMono-isopropyl-disopyramideAvocadene 2-acetate9-OxoODE2,4-Hexadien-1-olCyasterone(5alpha,6beta,14alpha,20R,22R)-5,6,14,20,27-Pentahydroxy-1-oxowith-24-enolide1,3,7-Trimethyluric Acid8-Methyl-8-azabicyclo[3.2.1]oct-3-yl 1H-indole-3-carboxylate3-Hydroxytetradecanedioic acidPrecocene IIFructosyl-lysine(R)-1-Methylpiperidine-2-carboxylic acid20-Carboxy-leukotriene B4MelatoninL-PhenylalanineN-Palmitoyl Leucine4'-Hydroxy NimesulideDiazepinomicinArginylphenylalaninamideN-Acetyl-D-galactosamineHydantoin-5-propionic acidGlutathione episulfonium ionRiddelliine N-oxideAlanyltryptophanLysylhistidine4-(Glutamylamino) butanoateCoumafuryl2-HydroxyundecanoateArginylphenylalanine4-(1-Hydroxy-2-methoxyethyl)-5-(hydroxymethyl)-2-methylpyridin-3-olGibberellin A4Gibberellin A5S-Glutaryldihydrolipoamide4-Tert-AmylphenolPhenylethylmalonamideTHURFYL NICOTINATEMelibiitolN(4)-Acetylsulfamethazine4-((6-Methoxyquinolin-8-yl)amino)pentanoic acidN-Acetyl-4-O-acetylneuraminic acid11b-HydroxyprogesteroneToxin FS2(9R,10S,12Z)-9,10-Dihydroxy-8-oxo-12-octadecenoic acidHydroxyprolylhydroxyprolineAminomalonic acidQuinmeracArg-Thr-Lys-Arg3-Hydroxybutanoic AcidSulfamethoxazole N1-glucuronide5-p-Coumaroylquinic acidN-Acetyl-L-TyrosineLL-2,6-Diaminopimelic AcidIbuprofen glucuronideTryptophyl-LysineBursinALA-ILE(6E,8E)-4,6,8-MegastigmatrieneDesaminotyrosine3-Methoxy-4-hydroxyphenylethyleneglycol sulfateMycaroseAromadendrin 3-rhamnosideGyromitrin1,3,2-Dioxathiolane 2,2-dioxide1-AminoglucoseDodecylbenzenesulfonic AcidTRIADIMEFONAcetylpterosin C4-Pyridoxic AcidGibberellin A29-cataboliteHomovanillinDihydroergocornineCryptodorineAcrimarine IAcrimarine N2-Aminomuconic acid18-HEPEBeta-TyrosineAdrenochrome9H-Purine-9-butanoic acid, 6-amino-alpha-hydroxy-, methyl esterL-2-Amino-4-methylenepentanedioic acid1,2-Epoxy-3-(p-nitrophenoxy)propaneVulgarinEstriol-16-GlucuronideCystine-glutamateCucurbic acidDibenzo-18-crown-6Aflatoxin B1 dialcoholDimethylaniline-N-oxideGlutaminylvaline2,4-Pentanedione5-hydroxy saxagliptin4-(10,13-Dimethyl-2,3,4,5,6,7,8,9,11,12,14,17-dodecahydro-1H-cyclopenta[a]phenanthren-17-yl)oxolan-2-one2-Methoxyestrone 3-glucuronideL-beta-aspartyl-L-leucine9,10-DihomeGanoderic acid thetaPhysostigmineBoceprevirSinomenine9-(3-Imidazol-1-yl-2,6,6-trimethylcyclohexen-1-yl)-3,7-dimethylnona-2,4,6,8-tetraenoic acidStrigolAlpha-Carboxy-delta-nonalactoneIsoleucylproline2-HydroxybenzaldehydeCerasinoneJasmine ketolactone8-Amino-7-oxononanoic acid(4-Hydroxybenzoyl)cholineArginylleucine5-[(1S,2S,3S,5R)-3,5-Dihydroxy-2-[(E,3R)-3-hydroxyoct-1-enyl]cyclopentyl]-4-oxopentanoic acidBoc-D-phenylalanine4-amino-4-deoxychorismateTemocaprilat6-[2,3-Dihydroxy-1-(hydroxymethyl)propyl]-1,2-dihydro-7-hydroxy-9-methoxy-cyclopenta[c][1]benzopyran-3,4-dione8-[(Aminomethyl)sulfanyl]-6-sulfanyloctanoic acid4Alpha-hydroxymethyl-5alpha-cholesta-8,24-dien-3beta-olN-carboxymethyllysine1-MethylguanosineUbiquinone-2ArtecaninS-Prenyl-L-cysteineIsbogrel(+/-)-Enterolactone5-HydroxytryptolinePyrrole-2-carboxylic acid2-Phenylethyl beta-D-glucopyranosideHistidinyl-LeucineArlatin3,4-Dihydro-6-methoxy-2,2-dimethyl-2H-1-benzopyran-4-olMulberrinH-Arg(NO2)-Obzl3a,7a,12a-Trihydroxy-5b-cholestan-26-alSecoisolariciresinol17-Hydroxyprogesterone2-Propyl-2,4-pentadienoic acidCyclocalopin C1(2R)-2-Acetyl-1-[(2S)-2-[acetyl-[(2S)-2-[[(2S)-2-amino-3-hydroxypropanoyl]amino]-3-carboxypropanoyl]amino]-6-aminohexanoyl]pyrrolidine-2-carboxylic acidAspartyl-LeucineTamarixetin16b-HydroxystanozololPirlindoleCinncassiol C23-Methyladipic Acid(5Z)-7-[(1R,2R,5S)-5-Hydroxy-2-[(1E,3S,5Z)-3-hydroxyocta-1,5-dien-1-yl]-3-oxocyclopentyl]hept-5-enoylcarnitineAB-PinacaAlanylhydroxyprolineEicosadienoic acidPalmitoyl Serinol7-Hydroxy-2-methyl-4-oxo-4H-1-benzopyran-5-carboxylic acid 7-glucosideQH(2)L-gamma-Glutamyl-beta-phenyl-beta-L-alanineMycophenolic acidPseudoecgonineL-arogenateGibberellic AcidBrassicanal A4-Oxo-L-prolineHydroxylated N-acetyl desmethyl frovatriptan6-Hydroxy-1H-indole-3-acetamide5-Aminolevulinic acid4-(5-Chloro-3-isopropyl-1H-pyrazol-4-yl)-N-(5-(4-(dimethylamino)piperidin-1-yl)pyridin-2-yl)pyrimidin-2-amineNorethindrone oximeOxandroloneN-(3-acetamidopropyl)pyrrolidin-2-oneHippuric Acid3,7-Dimethyl-5-octene-1,7-diol 1-glucosideN-Oleoyl Leucine(6S,8Z)-6-Hydroxy-3-oxotetradecenoic acidTRIAZIQUONETriton X-100Ethyl glucoside3'-Methyl-dimethylaminoazobenzeneNorketamineHomoanserine3-Succinoylpyridine3a,7a-Dihydroxy-5b-cholestane2-Aminobicyclo[3.1.0]hexane-2,6-dicarboxylic acidL-Proline, 1-acetyl-4-hydroxy-, cis-RivenprostGlucosamine 6-sulfateDihydrocorticosterone9(S)-HODEPC(DiMe(11,3)/LTE4)SolavetivoneBeta-D-fructose 2,6-bisphosphateGluconolactoneD-Biotin2-(20-Hydroxyicosa-5,14-dienoylamino)acetic acidKynurenic AcidPimonidazole3-Hydroxypicolinic acid2,6-PipecoloxylidideEPITUMOMAB CITUXETAN2-Fluoro-2',3'-dideoxyadenosine2,4-Dihydroxy-2H-1,4-benzoxazin-3(4H)-oneHeptenophosUndecylenic acidCarbuterolHyoscyamineGamma-Glu-leuHexyl glucoside(1R,9S,10R)-17-(Cyclopropylmethyl)-17-azatetracyclo[7.5.3.01,10.02,7]heptadeca-2(7),3,5-triene-4,10-diol6-keto PGE1N4-(1,3-Benzodioxol-5-ylmethyl)-6-(3-methoxyphenyl)pyrimidine-2,4-diamineThymidine glycolN2-Acetyl-L-ornithineMenthone 1,2-glyceryl ketalCantharidin12(R)-HETE4-Vinylcyclohexene dioxideAceglutamideN-Palmitoyl CysteineAmobarbitalCalystegin A3Glycyl-PhenylalanineDoisynoestrolDaumoneAla-Phe-AlaDelphinidinAlpha-Carboxy-delta-decalactoneMyristoylglycineVal-Pro-Asp-Pro-ArgFurazabolHydroxyprolyl-ArginineTrans-Piceid4,5-DihydrovomifoliolCaramboxinMJDBISSN00000009MJDBISSN00000001MJDBISSN00000003PentadecanoylcarnitineBenzeneacetic acid, 4-(2-(diethylamino)-2-oxoethoxy)-3-ethoxy-, propyl esterIsosativanLeu-Arg-Asn-Arg2-aminophenol sulphateD-Kynurenine7(14)-Bisabolene-2,3,10,11-tetrol1-Hydroxy-2-(N-acetylcysteinyl)-3-buteneNafazatromN-(N-(3-Amino-3-carboxypropyl)-3-amino-3-carboxypropyl)azetidine-2-carboxylic acid4-Oxo-1,4-dihydroquinoline-3-carboxylic acid1,10-Epoxy-3,8-dihydroxy-4,11(13)-germacradien-12,6-olide(+-)-Carbovir6b-Angeloyl-3b,8b,9b-trihydroxy-7(11)-eremophilen-12,8-olide1-Dodecanesulfonic acidPA(10:0/i-13:0)1,4-Cyclohexanedicarboxylic acidLysoPE(20:1(11Z)/0:0)6alpha-hydroxy-castasteroneGlycine, N-[1-(phenylacetyl)-L-prolyl]-(+)-Lysergic acidHydroxyphenylacetylglycineCholic Acid16-feruloyloxypalmitate2-Aminobenzenesulfonic acid18-carboxy dinor Leukotriene B4FrangulanineCombretastatin A44-Oxododecanedioic acidAbscisic AcidN-Palmitoyl GlycineDimethyl adipate2-n-Propyl-4-oxopentanoic acid3-((4-(5-(Hydroxymethyl)-2-oxo-3-oxazolidinyl)phenoxy)methyl)benzonitrile1-(1,2,3,4,5-Pentahydroxypent-1-yl)-1,2,3,4-tetrahydro-beta-carboline-3-carboxylateN-Phenylacetylaspartic acid(3R)-3-Hydroxy-N-[(3S)-2-oxooxolan-3-yl]butanamide3-Methylsuberic acid(x)-2-Heptanol glucosideSoyasaponin A2Rutacultin2-Aminomuconic acid semialdehydeGraminealTyrosyl-HistidineRepaglinide aromatic amineIsoalliinAlpha-CEHC13-HydroxyhexadecanoylcarnitineFasoracetam3-DehydroteasteronePyruvaldehydeMethysergideN5-Acetyl-N2-gamma-L-glutamyl-L-ornithine2-(Nonylphenoxy)ethanol2,2,6,7-Tetramethylbicyclo[4.3.0]nona-1(9),4-diene-7,8-diolL-Aspartyl-4-phosphateMenthyl pyrrolidone carboxylateJasmoloneGlucolepidiin5'-O-beta-D-GlucosylpyridoxineLobucavirEpsilon-caprolactam3-Amino-2,3-dihydrobenzoic acidN-Acetylglucosamine 6-sulfateChembl4513510N-AllylsecoboldineAzelaic Acid1-[6-(2-Carboxypyrrolidin-1-yl)-6-oxohexanoyl]pyrrolidine-2-carboxylic acidMelilotocarpan A2-[N-(ethoxymethyl)-2-Ethyl-6-methylanilino]-2-Oxoethanesulfonic AcidParachlorophenolDethiobiotin10-Hydroxy-3-methoxy-1,3,5,7-cadinatetraen-9-oneEthyl 3-oxohexanoateCichorioside J4,5-Dihydroniveusin A5-MethoxytryptopholD-Glucuronic Acid4-[4-(4-Fluorophenyl)-1-(3-phenylpropyl)-5-(4-pyridinyl)-1H-imidazol-2-yl]-3-butyn-1-olAspartameConiferyl alcoholP-Aminobenzaldehyde1-(11Z-eicosenoyl)-glycero-3-phosphateLamivudine-monophosphateCortisol 21-sulfateThalidomide8-Hydroxy-7-methylguanineHydroxyethyl methacrylic acidArecolineSorbitan stearate(S)-3-{4-[2-(5-Methyl-2-phenyl-oxazol-4-yl)-ethoxy]-phenyl}-2-propylamino-propionic acid16-oxo-palmitate3-PyridinolAucubinHydroxykynurenineTriacetic acidN-Acetyl-DL-Leucine4,11,13,15-Tetrahydroridentin BPhthalic Acid3-Hydroxykynurenamine2-Ethylphenol4-(3-Pyridin-2-yl-[1,2,4]oxadiazol-5-yl)-butyric acidTestosterone isobutyrate7,4'-DihydroxyflavoneGlucoibervirinOxyphenbutazoneLysoPC(P-16:0/0:0)4-Propylphenol5-hydroxyindole thiazolidine carboxylateCarbocyclic 3-deazaadenosineBetalamic acid3-Amino-4-oxobutanamideN-HeptanoylglycinePseudouridineGalactocerebrosideN-formimidoyl-glutamic acid3'-Hydroxyhexobarbital4-maleyl-acetoacetateRacemetirosine(1Ar,2Z,4E,14R,15aR)-8-chloro-9,11-dihydroxy-14-methyl-15,15a-dihydro-1aH-benzo[c]oxireno[2,3-k][1]oxacyclotetradecine-6,12(7H,14H)-dioneChlorprophamPeldesine(1S,2R,4R)-p-Menth-8-ene-2,10-diol 2-glucosideQuinolin-2-yl hydrogen sulfate2-Chloro-N-[1-[(2R)-2,3-dihydroxypropyl]-2-oxo-3,4-dihydroquinolin-3-yl]-6H-thieno[2,3-b]pyrrole-5-carboxamideGuanosineSinapyl alcoholBisdemethoxycurcumin3-Hydroxy-alpha-methyl-DL-tyrosine3-Mercaptopyruvic acid3-Oxocholic acidDimethylaminoparthenolide[(3-Hexyl-4-methyl-2-oxo-2H-chromen-7-yl)oxy]acetic acidChenodeoxycholic Acid(5E)-3-Hydroxyhept-5-enoylcarnitine3-MethylxanthinePiracetam11-Oxo-androsterone glucuronideHexadecanedioic acidAntroquinonolHelenalinTebuconazoleLapachenoleNonadecanoylcarnitine5-OxohexanoylcarnitineAzasetronPropionic acid, 2-methyl-2-((piperidinomethyl)thio)-Valylaspartic acidCurdioneN-Linoleoyl Isoleucine3-Hydroxy-1,4-benzodiazepineTriterpenoidBedoradrineN-Arachidonoyl Isoleucine1,1,1,3,3-PentafluoropropaneNafagrelIsoketocamphoric acidN-Arachidonoyl Arginine2H-1-Benzopyran-2-one, 7-(sulfooxy)-IsoeugenolButyric Acid5-Formyl-2H-pyran-6-carboxamideLysoPI(16:0/0:0)Alkaloid ARotundoneProlyl-ValineHuperzine bNorhygrineIsorheagenine(5Z,8Z,13E,15S)-11,12,15-Trihydroxyicosa-5,8,13-trienoylcarnitineN-Acetyl-D-phenylalanine2',3'-Didehydro-2',3'-dideoxycytidineBz-CampGanosporeric acid AFluocortin butylDG(18:3(10,12,15)-OH(9)/8:0/0:0)(Z)-3-Oxo-2-(2-pentenyl)-1-cyclopenteneacetic acidN-Valylphenylalanine(4-((5,6-Diphenylpyrazin-2-yl)(isopropyl)amino)butoxy)acetic acid7H-Pyrido(1,2,3-de)-1,4-benzoxazine-6-carboxylic acid, 9-fluoro-2,3-dihydro-3-methyl-10-(4-methyl-1-piperazinyl)-7-oxo-, N-oxide5,7,3',4'-Tetrahydroxyflavanone 7-alpha-L-arabinofuranosyl-(1->6)-glucosideEnt-16b,19-Kauranediol 19-acetateBetalamateAcoric acid11-Hydroxy-9-tridecenoic acidTerephthalic AcidTetracosahexaenic acidLysoPA(i-20:0/0:0)RisbitinGibberellin A121Taurochenodeoxycholate-3-sulfatePelubiprofenGibberellin A12010-HydroxycamptothecinCarmoxiroleExatecan2-Naphthylaminomethyl-gamma-aminobutyric acidSulfacarbamideSpectinomycin10-Hydroxy-2-decenoic acid4-Hydroxy-6-octenoylcarnitine5-Dehydroquinic acid5-(Cycloocten-1-yl)-5-ethyl-barbituric acidN-Methyl-1-deoxynojirimycinTrans-cinnamoyl-beta-D-glucosidePolygodialHydroxyoctanoic acid1-Carboxycyclohexaneacetic AcidEgtazic acidLactupicrin methyl esterSquamostanal A3-OctenoylcarnitineIsopenicillin NIndole-3-carboxilic acid-O-sulphateStavudineDesethylzaleplonPhellopterinBecocalcidiolHaloxyfop-P(3R,5Z)-5-Octene-1,3-diolCis-12-Oxophytodienoic acidDocosahexaenoic AcidAmppd4-Chloro-2-methylanilineDilept2-Hydroxypropyl methacrylamide2-Hydroxypropyl octanoate8(S)-HETrE3-[[(2R)-2-Acetamido-2-carboxyethyl]disulfanyl]-2-aminopropanoic acid4alpha-carboxy-5alpha-cholesta-8,24-dien-3beta-olButanoic acid, [(diethoxyphosphinyl)oxy]methyl esterMesylateD-Xylonate(2Z,4'Z)-2-(5-Methylthio-4-penten-2-ynylidene)-1,6-dioxaspiro[4.4]non-3-eneEmodinPolyethylene, oxidizedP-Aminobenzoic acid(E)-10-Hydroxy-8-decenoic acid1,2-Dihydroxy-3,4-epoxy-1,2,3,4-tetrahydronaphthalene2'-Deoxymugineic acidN-Docosahexaenoyl GlutamineEtidocaineDihydrobiopterin4-Hydroxystyrene3b-Hydroxy-17-(1h-1,2,3-triazol-1-yl)androsta-5,16-diene4-[2-[5,5-Dimethyl-8-(4-methylphenyl)-6H-naphthalen-2-yl]ethynyl]benzoic acidTiglic acidZizybeoside IHydroxy Tyrosol -Acetate12-hydroxyicosanoic acid(1S,2S,3S,4R)-3-(1-Acetamido-2-ethylbutyl)-4-(diaminomethylideneamino)-2-hydroxycyclopentane-1-carboxylic acidUbenimex2-(Icosa-5,8,11,14-tetraenylamino)acetic acidPiperdial20-carboxy-LTB46-Lactoyltetrahydropterin7-Sulfocholic acidLanthionine ketimine2,4'-Dichlorobiphenyl(S,E)-2-(5-Hydroxy-8,9-dihydro-5H-benzo[7]annulen-6(7H)-ylidene)acetic acidCowagarcinone DLotaustralin1,3-Dihydro-(2H)-indol-2-oneSpongothymidine3-Hydroxy-4-methoxyphenyllactic acid{4-[4-(6-Carbamoyl-3,5-dimethylpyrazin-2-yl)phenyl]cyclohexyl}acetic acidOxymetazoline7-[3-(4-Acetyl-3-hydroxy-2-propylphenoxy)-2-hydroxypropoxy]-4-oxo-8-propylchromene-2-carboxylic acidApomineBicarbonate carbonMelleolide EAbacavirRhodamine BBesifovirPhosphoserineDIPROTIN BS-(1-Propenyl)-cysteine sulfoxideN-Acetyl-b-D-galactosamineGenipinSertindoleAsparaginyl-Leucine10-Hydroxydecanoic acidAloeresin BAlectrolSulindacCitrazinic AcidN-Methacryloyl-L-glutamic acidN',N'-Diphenylhydrazinecarbohydrazide2-HydroxyestroneCitiolone8-AngeloylegelolideErinapyrone AGlycerol glutamateLysylphenylalanine8-Hydroxy-3-methyl-3,4-dihydrotetraphene-1,7,12(2H)-trioneHydroxymethyl cimetidine5alpha-Hydroxytriptolide(2S)-2-[[(2S)-2-Aminopropanoyl]-naphthalen-2-ylamino]pentanedioic acidTherafectinGanetespibHydroxyprolyl-Alanine2-Methylthioadenosine4-Ethoxyphenol1,11-Undecanedicarboxylic acidMethyl red27-Deoxy-5b-cyprinolN-[1'-(Aminocarbonyl)-2',2'-dimethylpropyl]-1-(cyclohexylmethyl)-1h-indazole-3-carboxamide2-(5-Methoxy-1H-indol-3-yl)ethyl acetatePC(17:2(9Z,12Z)/0:0)Isoleucyl-Arginine4-Hydroxy-2,6,6-trimethyl-3-oxo-1,4-cyclohexadiene-1-carboxaldehyde3alpha,7alpha,12alpha-trihydroxy-5beta-cholestanateIsoleucyl-Isoleucine2-Polyprenyl-6-methoxy-1,4-benzoquinoneGemfibrozilFluocortolone caproateP-Hydroxyphenethyl trans-ferulatePterolactamCarbinoxamineEthyl glucuronideCinncassiol AN-acetylaspartateMethyl epijasmonateErgocornine3a,6b,7a,12a-Tetrahydroxy-5b-cholanoic acidN-AllylglycinePhosphate3-phospho-L-serineTyrosyl-alanyl-glycine3-MethylcrotonylglycinePtaquilosideIsopropylmaleic acid(z)-3-Hexenyl Beta-d-GlucopyranosideDeoxycholylphenylalanineHydroxyprolyl-ProlineHypochoeroside A3-Oxohexanoic acidN-Palmitoyl ArginineIndolelactic acid3-(1H-Pyrrol-2-yl)propanoic AcidAminocaproic acidDelta3,5-DeoxyneotigogeninArctinol AMimosineThreonylleucineN-Hydroxy-2(R)-[[(4-methoxyphenyl)sulfonyl](3-picolyl)amino]-3-methylbutanamide hydrochloride(S)-Menthone 8-thioacetate2-Amino-4-oxo-4-alpha-hydroxy-6-(erythro-1',2',3'-trihydroxypropyl)-5,6,7,8-tetrahydroxypterinDopamine 4-sulfate3(2H)-Isoflavene(S)-9-Hydroxy-10-undecenoic acidGravacridonetriol glucosideCyclo(Leu-Phe)9,10-Dihydroxystearic acid5,6-epoxy,18R-HEPEThreoninyl-Gamma-glutamateLupinic acidNalpha-Acetyl-L-Lysine5-Sulfosalicylic acidHypoxanthineBuforminPE(15:0/0:0)2-O-Caffeoylhydroxycitric acidKanokoside DKanokoside CPhenylglucuronideRocuronium(4S,8R)-8,9-Dihydroxy-p-menth-1(6)-en-2-oneHypaconitine4-Hydroxycyclohexylcarboxylic acidOphthalmic acid(2S)-2-Amino-6-[(3-formylpiperidin-1-yl)amino]hexanoic acidValylthreonineFosphenytoin12-[Methyl-(4-nitro-2,1,3-benzoxadiazol-7-yl)amino]octadecanoic acidGamma-Glutamylleucine(1xi,3xi)-1,2,3,4-Tetrahydro-1-methyl-beta-carboline-3-carboxylic acidEnoxacinTetraHCA5'-o-MethylthymidineOxoadipic acidBis(2-ethylhexyl) phthalateCortisoneLysoPC(16:0/0:0)Isobutyric acidGlycine-betaxanthinDL-AllylglycineArtemisin(3beta,5alpha,9alpha,14alpha,22E,24R)-3,5,9,14-Tetrahydroxyergosta-7,22-dien-6-oneDidanosineSporolXylopineAc-Pro-Gly-Pro-OHValylhistidineAlpha-Tocopherol phosphateTyrphostin AG 126Glycyl-L-ProlineAllophanic acid(3S)-3,6-DiaminohexanoateCyclopentanecarboxylic acidCortolone3-Quinolinecarboxylic acid, 7-(3-amino-1-pyrrolidinyl)-1-cyclopropyl-6,8-difluoro-1,4-dihydro-4-oxo-(Z)-4-DodecenalArachidonic acid5,6-Dihydro-11-methoxyyangoninSaterinoneNNAL-N-glucuronide7,8-Dihydropteroic acid3,5-Dichloro-2,6-dihydroxybenzoic acidTolmetin glucuronide6-MethylnicotinamideRhodinyl phenylacetate1-Propanone, 1-(3,4-dihydroxyphenyl)-2-methyl-3-HydroxybenzylhydrazineQueuineCucurbitacin BCucurbitacin CPostinL-MethionineFluprednisoloneTributyrylglycerol(+/-)-2-Hydroxy-4-(methylthio)butanoic acidDelpazolidCucurbitacin SN-LactoylleucineL-4-Hydroxyglutamate semialdehydeL-Menthyl (R,S)-3-hydroxybutyrateLeucyl-leucineGlycyltyrosineSalidrosideOxytetracyclineAF Toxin IIAncymidolVulgaxanthin IICorynantheineN-Oleoyl PhenylalanineSobrepinPerphenazinePinolidoxinTaishoEpoxyoxophorone1,3-Dipropyl-8-p-sulfophenylxanthine4-HydroxydiphenylamineDeoxycytidylic acidPemolineAspartyl-L-prolineRepirinast1-[(5-Amino-5-carboxypentyl)amino]-1-deoxyfructoseDeoxyguanosine(Z)-3-nonenal4-Heptyloxyphenol3alpha,4,5,7alpha-Tetrahydro-5-hydroxy-1H-isoindole-1,3(2H)-dioneLysoPG(16:0/0:0)Lipoamide2-Imidazolidinone, 4-hydroxy-1-(5-nitro-2-thiazolyl)-CelgosivirNaproxen O-glucuronideUndec-5-enedioylcarnitineDemethylphylloquinone(2R,3R,4S,5S,6R)-2-(3-(4-Cyclopropylbenzyl)-4-fluoro-1H-indol-1-yl)-6-(hydroxymethyl)tetrahydro-2H-pyran-3,4,5-triol1-Hydroxypyrene glucuronideS-AllylcysteineTetrapeptide5-Chloro-2'-deoxyuridineEltoprazine4-Hydroxyphenylpyruvic AcidLysoPE(16:0/0:0)1-Carboxyethyltyrosine(+/-)-Citronellyl acetatePyricarbateTryptophyl-Leucine3-Hydroxypropyl methacrylateTETRAHYDROURIDINEMETHYLORSELLINIC ACID, ETHYL ESTER(+/-)13-HpODEDihydro-4,4-Dimethyl-2,3-furandione4-Hydroxy-8-methoxy-2H-furo[2,3-h]-1-benzopyran-2-one11(R)-HETE(3R)-SophorolTraumatin24,25,26,27-Tetranor-23-oxo-hydroxyvitamin D31-HydroxyepiacoroneBeta-1,4-Mannosyl-N-acetylglucosamineHerniarinMaleic Acid6-(2-Hydroxyethoxy)-6-oxohexanoic acidOxycodone2-Nonene-1,4-diolSerylarginine20-Carboxyleukotriene B4Carbamoyl (2R)-2,5-diaminopentanoate2-Carboxy-4-dodecanolide(R)-Salsolinol11b-Hydroxyandrost-4-ene-3,17-dione6-Cyano-7-nitroquinoxaline-2,3-dioneMG(0:0/20:5(5Z,8Z,11Z,14Z,16E)-OH(18)/0:0)3beta-Hydroxy-17-(1H-imidazol-1-yl)androsta-5,16-dieneMG(20:3(11Z,14Z,17Z)/0:0/0:0)Beta-D-3-Ribofuranosyluric acidArctiopicrinPS(20:2(11Z,14Z)/22:2(13Z,16Z))Isocolumbin(2E)-4-hydroxy-5-methyl-2-propylidene-3(2H)-furanone14,15-DiHETrE3-Polyprenyl-4-hydroxy-5-methoxybenzoate12a-Hydroxy-3-oxocholadienic acid3-Methyl-2-benzothiazolone hydrazone1-Linoleoyl-sn-Glycero-3-PhosphocholineIsoleucyl-TyrosineTetranor 12-HETE4-(2-Amino-3-hydroxyphenyl)-2,4-dioxobutanoic acidL-RhamnuloseIsophthalic Acid6-Hydroxy-4-methoxy-3-(3-methyl-2-butenyl)-2-(2-phenylethenyl)benzoic acidTestolactone12-Oxo-20-trihydroxy-leukotriene B47a,12a-Dihydroxy-3-oxo-4-cholenoic acid3-Isopropyl-2-methoxy-5-methylpyrazineN-NitrosoprolineDeoxycholic AcidL-Histidine9-Hydroxy-7-megastigmen-3-one glucoside3[N-Morpholino]propane sulfonic acidAlpha-Bisabolol oxide BAlpha-Bisabolol oxide ASerylisoleucineCapric acid11b,13-Dihydrolactucin6-Hydroxyhexanoic AcidN-VINYL-2-PYRROLIDONENorecasantalic acidMonic acid(11S)-11-Methyl-15,17-bis(oxidanyl)-12-oxabicyclo[12.4.0]octadeca-1(18),2,14,16-tetraene-7,13-dioneP-Anisic AcidN2-Succinyl-L-ornithineN-Acetyl-DL-ValinePalmitelaidic acid3-MethoxytyrosineCumi-101Taurohyocholate(4R)-4-Hydroxy-L-glutamic acidLacto-N-biose IEmivirine2-Furanylmethyl butanoate6-DeoxocastasteroneEPIISOPILOTURINE3-Hydroxy-Butanoyl-DL-Homoserine Lactone5-Hydroxylysine(S)-7-(3-Amino-1-pyrrolidinyl)-1-cyclopropyl-6-fluoro-1,4-dihydro-4-oxo-1,8-naphthyridine-3-carboxylic acid1-(4-Methyl-5-thiazolyl)-1-phenylmethylamine2,3-Dihydro-2,3-dihydroxy-4-(4-hydroxyphenyl)-1H-phenalen-1-oneDiacetyl-L-tartaric AnhydrideL-2-Amino-3-(oxalylamino)propanoic acidN5-(4-Methoxybenzyl)glutamine7-Methylguanosine 5'-phosphate(6E,8S,10Z)-8-hydroxy-3-oxohexadecadienoic acidPyrenedecanoic acid2-Amino-3-Methylsuccinic AcidHydroxynalidixic acid3,7-Dimethyl-3-octene-1,2,6,7-tetrol12-Hydroxyheptadeca-5,8,10-trienoic acid1-StearoylglycerophosphoglycerolXi-5-Hydroxydodecanoic acidDiethyloxalpropionate3H-Pyrazol-3-one, 1,2-dihydro-4-(hydroxymethyl)-1,5-dimethyl-2-phenyl-HydroxytanshinonePE(17:1/0:0)Glycinoeclepin AMalonic Acid(3R-(3alpha,4alpha(2R*,3R*),5beta,6beta))-5-Methoxy-4-(2-methyl-3-(3-methyl-2-butenyl)oxiranyl)-1-oxaspiro(2.5)octan-6-ol carbamateIndole-3-acetic Acid2-(acetylamino)-1,5-anhydro-2-deoxy-3-O-b-D-galactopyranosyl-D-arabino-Hex-1-enitol3-(3-hydroxyphenyl)propanoic AcidDimethisteroneOcta-3,6-dienedioylcarnitineThermophillinAcetoacetic acidOxdralazineAsparaginylisoleucineDimethyl dimethoxy biphenyl25-AcetylvulgarosideMagestin8-Acetyl-T2 tetrol1,2-dibutyrinGlyceric AcidMupirocinNeobyakangelicolLycoperdic acid15-hydroxyicosanoic acidNicotine-N-oxide(1S,2S,6R,15S,16R)-5-(Cyclopropylmethyl)-16-(2-hydroxy-3,3-dimethylbutan-2-yl)-15-methoxy-13-oxa-5-azahexacyclo[13.2.2.12,8.01,6.02,14.012,20]icosa-8(20),9,11-trien-11-ol1-(4-O-beta-D-glucopyranosyl-3-methoxyphenyl)-3,5-dihydroxydecaneDecadienyl-l-carnitineAsparaginyl-Valine(2-Phenylacetyl) (2R)-2,5-diaminopentanoateNorambreinolideEthinamateDihydrophaseic acidUlimorelinEpsilon-Deoxy-fructosyl-lysineVerlukast25-Hydroxyvitamin D3-26,23-lactolNeryl formate2-HydroxynevirapineLeucyl-AspartateAcetyl-N-formyl-5-methoxykynurenamine9h-Purin-9-amine6-HydroxypseudooxynicotineRutacridone epoxideUralenneoside4-Ipomeanol(R)-2,7-Dihydroxy-2H-1,4-benzoxazin-3(4H)-oneOxyresveratrol (cis-)PterostilbeneMethyl (3b,11x)-3-Hydroxy-8-oxo-6-eremophilen-12-oateButabarbitalHomo-L-arginineDelta-Tocotrienol5-Taurinomethyl-2-thiouridineL-1,2,3,4-Tetrahydro-beta-carboline-3-carboxylic acidDG(8:0/0:0/5-iso PGF2VI)L-Prolyl-4-hydroxy-L-prolin(S,E)-ZearalenoneArgatrobanAla-Leu3-Amino-4-(3-hexylphenylamino)-4-oxobutylphosphonic acidTetradecanedioic acidN-Acetyl-DL-Tryptophan(S)-N-Benzyl-2-((S)-2-(2-hydroxyacetyl)pyrrolidine-1-carbonyl)pyrrolidine-1-carboxamide4-Ethoxy-4-oxobutanoylcarnitineIdazoxanHexylresorcinolPyrethrosin2-Pyrocatechuic Acid(2R,2'R)-3,3'-disulfanediylbis(2-acetamidopropanoic acid)5Z-7-OxozeaenolZeatinDehydroepiandrosterone sulfate3-Phenyllactic AcidGuanidine, N-((2S,3S,4R)-6-amino-2-(dimethoxymethyl)-3,4-dihydro-3-hydroxy-2-methyl-2H-1-benzopyran-4-yl)-N'-cyano-N''-(phenylmethyl)-Gamma-D-GlutamylglycineImidazoleacetic acid ribosideSuccinic anhydrideN-ACETYLPROLINECyclocalopin BCyclocalopin APyrano(2,3-c)pyrazol-6(2H)-one, 3,4-dimethyl-2-(2-thienylmethyl)-3-O-MethylkaempferolThomsen-friedenreich antigenTropateEstra-1,3,5(10),7-tetraene-3,17alpha-diolApigenin 7,4'-dimethyl etherN-Desmethyl-O-hydroxy rosiglitazoneDehydrocostus lactone(R)-2-Hydroxy-2H-1,4-benzoxazin-3(4H)-onePentanochlor1-heptadecanoyl-glycero-3-phosphateTryptophyl-ThreonineProtoporphyrinogen IXTambulinBut-2-enoic acidXanthosineButanedioic acid, octenyl-N-Linoleoyl Histidine2-[(5-Methylsulfinyl)-4-penten-2-ynylidene]-1,6-dioxaspiro[4.4]non-3-eneGlycylleucineSyrosingopineSuberic AcidCilengitideLFMethidathionPimelic Acid4-Aminohex-5-ynoic acidPalatinoseM13-Oxovalproic acidGlutamylvaline9-Hydroxylinoleic acidL-trans-5-Hydroxy-2-piperidinecarboxylic acidGlycocholic acidEicosapentaenoic AcidO-Phospho-4-hydroxy-L-threonineNocodazoleAethallymalLeu-Gly-Gly(2S)-2-Amino-3-[(2S)-2-aminopropanoyl]oxypropanoic acidS-Sulfo-L-CysteineN-[(5-Hydroxy-2-pyridinyl)methyl]adenosine3-Phenoxypropylene di(acetate)1,4-IpomeadiolGlutamyl pyruvate3-Sulfopropyl methacrylateOrotidine(1R,9S,10S)-17-[(3-Hydroxycyclobutyl)methyl]-17-azatetracyclo[7.5.3.01,10.02,7]heptadeca-2(7),3,5-triene-4,10-diolHygrineN-Eicosapentaenoyl GlutamineTricarballylic Acid7-HydroxyflumequinePhenylalanylarginine5-Hydroxy-4-methoxybisabola-2,10-dien-9-oneHexathiepaneCoriandrone DPhysalolactone B3-Methoxy-4-hydroxyphenylglycolaldehydeButanoic acid, 3-((2-naphthalenylsulfonyl)amino)-4-oxo-4-((2-phenylethyl)amino)-, (S)-ThreonylglutamineN2-Ethyl-2'-deoxyguanosinePS(LTE4/22:2(13Z,16Z))3R-hydroxy-butanoic acidLeucodopachromeTrans-Cinnamyl alcohol4-Hydroxy-5-(phenyl)-valeric acid-O-sulphate2-Hydroxy-L-methionineTyrosyl-LeucineTaurolithocholic acid 3-sulfate3-Methyl-2-Oxovaleric AcidXenognosin ARilmakalimVinyl carbamate3-Oxopentanoic acidIndoxyl1-Methyluric acidL-3-Aminodihydro-2(3H)-furanoneDiglyceryl monooleateD-DigitoxoseDihydromaleimide beta-D-glucosideBaikiainThreonylhydroxyprolineD-Xylono-1,5-lactone22-Hydroxydocosanoic acidEpothilone BTaurineN-AcetylgalactosaminePteroside PLoratadineN'-Formylkynurenine2-HydroxyethanesulfonateMedicagenateProscillaridinMyristoleic acidDOPA sulfateVernakalantMenthyl ethylene glycol carbonate(17alpha,23S)-17,23-Epoxy-29-hydroxy-27-norlanosta-1,8-diene-3,15,24-trioneGanoderic acid KIsoleucyl-Tryptophan5''-(4-Hydroxy-(E)-cinnamoyl) alpha-L-arabinofuranosyl-(1->3)-beta-D-xylopyranosyl-(1->4)-D-xylopyranosideStearaldehydeFlobetair3-[(2R)-2-Aminopropyl]indole-1-carboxylic acidPS(DiMe(11,5)/MonoMe(11,5))3-(4-Hydroxyphenyl)lactate6-Hydroxynicotinic AcidSer-TyrLucidenolactone4-O-p-Coumaroylquinic acidDiosbulbin G9(S)-HpODE4-Methylbenzoic AcidGeranyl-PPL-Palmitoylcarnitine2,4-Dimethylpimelic acid2-Hydroxy-2-(2-oxopropyl)butanedioic acid16-methylnonadecanoylcarnitineDemethylated antipyrine1-HeptadecanoylglycerophosphoethanolamineBatatasin I(S)-HomostachydrineCarbocyclic thromboxane A2L-TryptophanAdouetine XN-Acetyl-a-neuraminic acidCholesterol glucuronideMethoxaminePhaseolus epsilon1H-Indole-4,6-dicarboximidamide, 2-phenyl-4-Chloro-1H-indole-3-acetic acidNigellicine5'-Thymidylic Acid5-Hydroxy-1-methylpyrrolidin-2-one1,2-Cyclohexanedicarboxylic acid, 4-methyl-3-MethyldioxyindoleNep-IN-23-[2-(6-Methyl-2-pyridinyl)ethynyl]-2-cyclohexene-1-one O-methyloximeCis,trans-5'-Hydroxythalidomide4-Methoxyindoxyl sulfateHydroxymelphalanHydroxyhexadecenoylcarnitineUracilMelleolideIodotyrosine2-Hydroxybutyric AcidN-[4-[(6-Methoxypyrimidin-4-yl)sulfamoyl]phenyl]acetamideSphingosine 1-phosphate8-Oxo-2'-deoxyadenosineN-(2-Hydroxyethyl)nicotinamideCaprylic acid9-Oxo-nonanoic acidCholesterol sulfateArtabsinDaucolPalmitoyl glucuronide(9S,10E,12S,13S)-9,12,13-Trihydroxy-10-octadecenoic acid10-(2,3-Dihydroxypropoxy)-10-oxodecanoic acidFenofibric acidGlutaminylphenylalanineSuccinic AcidTriflumizoleCarglumic acid2-MethoxyestriolOxalic acidHydrogenated MDI(3S,5R,6R,7E)-3,5,6-Trihydroxy-7-megastigmen-9-oneGamma-GlutamylphenylalanineBalofloxacin7-Amino-4-hydroxy-2-naphthalenesulfonic acid3'-KetolactosePi-Methylimidazoleacetic acidSalicyl-6-hydroxy-2-cyclohexene-on-oylEnterolactoneLomefloxacinKobusoneBeta-D-GalactosamineRotundifolineN-Eicosapentaenoyl Glutamic acidPimobendanN-Palmitoyl MethionineBetamethasone phosphate2-Pyrimidine Acetic AcidN-Methyl-2-phenyl-n-[(5r,7s,8s)-7-(pyrrolidin-1-yl)-1-oxaspiro[4.5]dec-8-yl]acetamideTezacitabineTetra-methoxypropane(3R)-3,4-Dihydroxy-3-(hydroxymethyl)butanenitrile 4-glucoside(3Z)-2-Propylpent-3-enoic acidPE(18:0/0:0)Gentamicin C2N-Eicosapentaenoyl ProlineChitobioseM-Coumaric acidLysoPE(18:1(9Z)/0:0)PE(18:1(9Z)/0:0)DihydrogenisteinLeucyl-Tryptophan3-Oxodecanoic acidQuinaprilatN-Formyl-L-methionineWithanolide 1Val Trp1-Naphthyl phosphateTaltirelin2-Amino-9-[2-(phosphanylmethoxy)ethyl]-1H-purin-6-one7alpha-hydroxy-3-oxochol-4-en-24-oic Acid(R)C(S)S-Alliin4-VinylphenolArticaineCorchorifatty acid DDanusertibErgothioneineEpsilon-CaprolactoneTrilostaneEthylmalonic AcidClavulanateThr-LeuProtocatechuic AcidBenzeneacetonitrile, alpha-(3-((2-(3,4-dimethoxyphenyl)ethyl)amino)propyl)-4-hydroxy-3-methoxy-alpha-(1-methylethyl)-7-Hydroxypentadecanoylcarnitine4-HydroxystachydrineN-Methylglutamic acidXanthurenic AcidL-trans-alpha-Amino-2-carboxycyclopropaneacetic acidN-LactoylphenylalanineAfzelechinMarmelineXanthinePinane thromboxane A21-(gamma-Glutamylamino)cyclopropanecarboxylic acidL-Glutamine2,3-Dihydroxypropyl 4-phenylbutanoateCoprocholic acid3,4-Methyleneazelaic acidLeucylphenylalanineUndeca-5,7,9-trienedioylcarnitine3-[4-methoxy-3-(sulfooxy)phenyl]propanoic acidHaloperidol 1,2,3,6-tetrahydropyridine5-Hydroxymethyluracil5-(4-Chloro-3-hydroxy-1-butynyl)-2,2'-bithiopheneCitronellyl beta-sophoroside2-Acetylpyrrolidine20, 22-DihydrodigoxigeninBlennin DFotemustinaGamma-L-Glutamyl-L-pipecolic acidUndecanedioic acidAlpha-Campholonic acidMalic Acid7-HydroxyhexadecanedioylcarnitineAllylestrenol3,7-Dihydroxy-12-oxocholanoic acid3a,6b,7b,12a-Tetrahydroxy-5b-cholanoic acidOrotic Acid(1R,2R,4R,5S)-(+)-p-Menthane-2,5-diolIsovaleraldehyde glyceryl acetalIbrutinibIsoliensinineEsculentic acid (Phytolacca)2-chloro-trans-dienelactone2,4(1H,3H)-Pyrimidinedione, 1-(cyclopropylmethyl)-6-(3,5-dimethylbenzoyl)-5-(1-methylethyl)-FluazifopVestitoneValproic AcidLysoPG(18:1(9Z)/0:0)FlomoxefL-CoprineAmidinophenylpyruvic acid2-Hydroxypropyl glucosinolateDhlnl3-[[5-Methyl-2-(1-methylethyl)cyclohexyl]oxy]-1,2-propanediol3-dehydrocholate2,3,4,5-Tetrahydro-2-pyridinecarboxylic acidTetracosanedioic acidHexahydro-4-methylphthalic anhydrideOxyphencyclimine(E)-indol-3-ylacetaldoximeDeoxyriboseRiboflavinProlyl-TyrosineIsopropyl beta-D-glucosideTetramethylchromanol glucosideDeoxyinosineCoumarinic acid2-[[2-(4-Hydroxyphenyl)ethylamino]methyl]-3,4-dihydro-2H-naphthalen-1-oneLysoPE(0:0/18:1(11Z))TelocinobufaginO-Succinyl-L-homoserine17alpha-TrenboloneTyrosylhydroxyproline4-(undecan-5-yl)benzene-1-Sulfonic AcidDinoprostTropinoneN-Acetylalliin3-Hydroxy-6,8-dimethoxy-7(11)-eremophilen-12,8-olide2-Methylbutyroylcarnitine2-Amino-5-phosphonopentanoic acidBemegrideBialaphos2-O-alpha-D-Galactopyranosyl-1-deoxynojirimycinHexaminolevulinate3-Ethyl-1,2-benzenediolThreonylhistidineMethyl dihydrophaseate2-Phenyl-1,3-propanediol monocarbamateIle-Val-ValLeucyl-Methionine5'-Carboxy-gamma-chromanolP-Hydroxyl-ethotoinGlutaric acid5-(Biotinamido)pentylamine9,10,13-TriHOME4,5-Dihydro-1-benzoxepin-3(2H)-oneHexahydro-6,7-dihydroxy-5-(hydroxymethyl)-3-(2-hydroxyphenyl)-2H-pyrano[2,3-d]oxazol-2-oneLysoPA(P-16:0/0:0)13,14-Dihydro PGF-1aSonolisibMiglitol2-(3,4-Dihydroxybenzoyloxy)-4,6-dihydroxybenzoateN-AcetylvanilalanineL-Formylkynurenine2-Amino-3-cyclohexylpropanoic acidL-XylonateN-Acetyl-L-methionine1-PalmitoylphosphatidylcholineGlycyl-L-Tyrosine5-(Galactosylhydroxy)-L-Lysine2,3-Pyridinedicarboxylic acidIsoleucyl-Phenylalanine1-Isopropyl-6-methylergoline-8-carboxylic acid(+)-3,4-Didehydrocoronaridine3-[7-[3-(4-Acetyl-3-hydroxy-2-propylphenoxy)-2-hydroxypropoxy]-4-oxo-8-propylchromen-2-yl]propanoic acid(4S,8R)-8,16,18-Trihydroxy-4-methyl-3-oxabicyclo[12.4.0]octadeca-1(14),12,15,17-tetraen-2-oneBiliverdinPS(22:5(7Z,10Z,13Z,16Z,19Z)/20:0)(E)-10-Oxo-8-decenoic acidFerreirin1-beta-Hydroxyeuscaphic acid3-benzyl-4-hydroxy-5-(4-hydroxyphenyl)furan-2(5H)-one1-Aminocyclopropanecarboxylic AcidUridine-5'-MonophosphatePE(13:0/0:0)UridineImazamox11-HydroxyyohimbinePolyporusterone G1,2-Cyclohexanediol, 1-methyl-4-(1-methylethenyl)-CapsiateEquolTetrahydrofurfuryl acetateHydroxypropionic Acid3,4-Dihydro-9-hydroxy-[1]benzothieno[2,3-f]-1,4-thiazepin-5(2H)-oneN-[1-[[5-(Diaminomethylideneamino)-1-oxopentan-2-yl]amino]-4-methyl-1-oxopentan-2-yl]-4-methyl-2-(propanoylamino)pentanamideLeucyl-GlutamateNaphthionic acid(S,S)-Nt-HistidinylalanineIsovalerylglutamic acidCurzerenone CDG(2:0/0:0/18:3(10,12,15)-OH(9))1-Methoxy-1-(2,4,5-trimethoxyphenyl)-2-propanolNeplanocin A(4As,5aR,6R,12aR)-1,10,11,12a-tetrahydroxy-6-methyl-3,12-dioxo-4a,5,5a,6-tetrahydro-4H-tetracene-2-carboxamideObtustyreneAflatoxin B2L-2,3-Dihydrodipicolinate2-DodecenalSerylhydroxyprolineSerylvalylglycylglutamic acid1-DeoxynojirimycinIsohydroxymatairesinolN-AcetylcysteinamideCurcumin IHarmalolFlavonol 3-O-D-glucoside5-Heptyltetrahydro-2-oxo-3-furancarboxylic acid(E)-2-Methyl-2-buten-1-ol O-beta-D-GlucopyranosidePhenylbutyrylglutamine2-Methylcyclohexanone3-[[(2S)-2,4-Dihydroxy-3,3-dimethylbutanoyl]amino]propanoic acidREMACEMIDE(2R,3S,5R)-5-(4,5-Dihydroimidazo[2,1-f]purin-3-yl)-2-(hydroxymethyl)oxolan-3-olDeoxynivalenolL-2-Amino-3-(1-pyrazolyl)propanoic acid(5E)-7-{4,6-Dihydroxy-2-[(1E,5E)-3-hydroxyocta-1,5-dien-1-yl]oxan-3-yl}hept-5-enoylcarnitine3-[4-(sulfooxy)phenyl]propanoic acidClobuzarit2-(2-carboxy-4-methylthiazol-5-yl)ethyl phosphateDeoxycholylasparaginePifithrinSerylvalineSorbinilAnthramycin methyl etherZearalenone5-HydroxyindoleacetaldehydeGibberellin A63CholylthreonineOxacillin5-Amino-1-(5-phospho-D-ribosyl)imidazole-4-carboxylic acidRitalinic acid1-(2-Hydroxyphenylamino)-1-deoxy-beta-D-gentiobioside 1,2-carbamateQuetiapineHydroxyethylflurazepam1,2-CyclohexanediolDidox9-Hydroxy-10,12-Octadecadienoic Acid10beta-12,13-Dinor-8-oxo-6-eremophilen-11-alGibberellin A755-Hydroxypentanoic acidFormiminoglutamic acid1,24,25-trihydroxyvitamin D3N-AcetylleucineArmillaric acidIcofungipenLeucyl-TyrosineCardenolideOsmundalactone1-Ipomeanol4-hydroxyalprazolam1-Hydroxy-2,2,6,6-tetramethyl-4-piperidinone5-Hydroxy-2-oxoindolin-3-yl sulfatePE(20:5(5Z,8Z,11Z,14Z,16E)-OH(18R)/DiMe(13,5))Imidazoleacetic acid ribotideN-Epsilon-Acetyl-L-LysineNikkomycinSotorasibLYSERGAMIDE(2R,5R)-2-[6-(Cyclopentylamino)-8-(methylamino)purin-9-yl]-5-(hydroxymethyl)oxolane-3,4-diolL-2-Aminoethyl seryl phosphateDiacetone AlcoholN-[(3s)-2-Oxotetrahydrofuran-3-Yl]butanamide2-Heptadecylfuran2H-1,2-Oxazin-3(4H)-one, 4-((3,5-bis(1,1-dimethylethyl)-4-hydroxyphenyl)methylene)dihydro-2-methyl-Beta-D-ribosylnicotinateCis-4-Carboxymethylenebut-2-en-4-olideEthylmorphine3-Piperidinecarboxylic acid, 1-(4,4-bis(3-methyl-2-thienyl)-3-butenyl)-, (S)-Hydroxyprolyl-Valine3-Hydroxydodeca-7,10-dienoylcarnitineFructosylamine7alpha-Hydroxy-3-oxo-5beta-cholan-24-oic acid1-Pentanesulfonic acidMALEAMIC ACID4-AminophenylmannosidePyridoxine 5'-phosphateN-(3-(Dimethylamino)propyl)acrylamide1,5-Dibutyl methyl hydroxycitrateLysoPE(P-18:0/0:0)2-CyanopyrimidinePhenethyl rutinoside5-(4-Methyl-5-Oxo-2H-Furan-3-Yl)Pentanoic AcidTryptophyl-GlycineHydroxybuprenorphineRamiprilat8-HydroxyondansetronCaffeic acid ester2-Hydroxyoctadecanoic acidGuanadrelMetoprololGlycyl-LysineMarbofloxacinN-Palmitoyl Threonine2'-Deoxyadenosine 5'-phosphateD-(+)-Malic acidGlycine, L-gamma-glutamyl-2-(1-methyl-4-(nitrosothio)-4-piperidinyl)glycyl-GlutarimideRetaspimycin2-Amino-4-[carbamimidoyl(methyl)amino]butanoic acid(2'E,4'Z,7'Z,8E)-Colnelenic acidGibberellin A34-cataboliteSulfate2',3'-Didehydro-2',3'-dideoxyguanosineValylglutamic acidAcetylshikoninXanthohumolPG(16:0/0:0)[U]Methyl 7-epi-12-hydroxyjasmonate glucosideGlycyl-TryptophanCitramalic AcidPhenidone3,5-dihydroxy-4-(sulfooxy)benzoic acid5-Hydroxyvalproic acidCoagulin R 3-glucosidePhenylalanylleucineAnabasineEsmololUndeca-2,4,6-trienoylcarnitineGamma-Glutamyl-S-(1-propenyl)cysteine sulfoxide20-Hydroxy-leukotriene E4N-Stearoyl Isoleucine4-Hydroxyvalproic acid4-Methoxybenzyl glucoside6-Ethylchenodeoxycholic acidO6-BenzylguanineL-GalactoseAlpha-(Dimethylaminomethyl)-2-(3-ethyl-5-methyl-4-isoxazolyl)-1H-indole-3-methanolHomopisatin(8R,9S,10R,13S,14S,17R)-13-Ethyl-17-ethynyl-3-nitroso-2,3,6,7,8,9,10,11,12,14,15,16-dodecahydro-1H-cyclopenta[a]phenanthren-17-olSotalol5-(4-Carboxybutylperoxy)pentanoic acidMyo-Inositol3,4-Dihydroxy-2-hydroxymethyl-1-pyrrolidinepropanamide4,5Dimethyl-3-(2-oxo-2-phenyl-ethyl)-thiazolePenciclovirPhaseic acid15-KeteThienamycinDL-m-TyrosineZeranolEstrone glucuronidePiperoxanNeotigogeninValylisoleucine4-Hydroxy-3-methoxybenzenemethanol20-Hydroxy-6Z,15Z-eicosadienoic acidBergamottinN-Acetyl-2-hydroxybenzamide3(4->5)-Abeo-4,11:4,12-diepoxy-3-eudesmanol(1S)-(-)-Camphanic AcidGibberellin A40VelleinN-(Hydroxymethyl)acrylamideEuxanthoneCitric Acid(2S)-3-Hydroxy-1-[(2S)-pyrrolidine-2-carbonyl]pyrrolidine-2-carboxylic acidUrate radicalAsparaginyl-PhenylalanineMibefradilBisphenol A bis(2-hydroxyethyl)ether5-(Methoxycarbonyl)thiophene-2-carboxylic acidValylleucine(all-Z)-8,11,14-HeptadecatrienalGibberellin A51(1alpha,4alpha,5beta,6alpha,11betaH)-1,4-Epoxy-5-hydroxy-10(14)-germacren-12,6-olideN(6)-L-Homocysteinyl-L-lysineAplysiatoxin, 17-debromo-5(6)-Epoxy Prostaglandin E1Cyperolone4-Bis(2-hydroxyethyl)amino-L-phenylalanineIslatravirGibberellin A8-catabolite4'-Methylliquiritigenin 7-rhamnosideGibberellin A20Gibberellin A19LysoPA(8:0/0:0)5(S)-Hydroperoxyeicosatetraenoic acid7-Hydroxy-6-methyl-8-ribityl lumazineGibberellin A34DecarbamoylneosaxitoxinElatoside GEchothiophateGibberellin A29InosineL-Serine(S)-a-Amino-2,5-dihydro-5-oxo-4-isoxazolepropanoic acid N2-glucosideN-Stearoyl LeucineAdenosine 5'-Monophosphate6-Hydroxy-3,4-dihydro-2(1H)-quinolinoneLysoPE(20:0/0:0)Cholesterol glutamate2-Hydroxyquinoline-3-carboxylic acidBL IV(3S)-3-hydroxycyclocitralN,N-dihydroxy-L-tyrosineChromafenozide1-nonadecanoyl-glycero-3-phosphateGlucose pyruvate lactate5-Aminovaleric AcidOleoyl glycineThreonylisoleucineO-Desmethylvenlafaxine glucuronideHydroxypropionylcarnitineTryptophyl-IsoleucineVanylglycolThymine dimerL-Alanyl-l-ValineS-Farnesyl cysteine2-Hydroxystearic acid5-(Hydroxymethyl)pyrrolidin-2-one(2R,3S)-2,3-dimethylmalateLobetyolinMethyl-[12]-gingerdiolPirinixil3-hydroxypentadecanoic acidIsobutyl 4-hydroxybenzoate5H-Indazole-5,5-dicarboxylicacid, 1,2,3,4,6,7-hexahydro-3-oxo-2-(6-Hydroxy-4-oxo-2-sulfanylidene-1H-pyrimidin-5-yl)propanedialDimethyl phthalateAjugol3-Hexenoic acidSalbutamol 4-O-sulfatePicrocrocinTyrosyl-IsoleucineGlucosamine 6-phosphateShikimic AcidN-Hydroxylorcaserin2-OxoarginineMarasmalQUINACAINOL(10E,15Z)-9,12,13-Trihydroxyoctadeca-10,15-dienoylcarnitine4-AndrostenediolN-Acetyl-L-Glutamic Acid4,6-O-Ethylidene-alpha-D-glucose3,4-Dichloroisocoumarin(+/-)10-HDoHEExo,exo-1,8-Epoxy-p-menthane-2,6-diolGabapentin enacarbilTilisolol(+/-)-PelletierineHMDB02417984-AzidobenzenesulfonamideDihydrocaffeic acid 3-sulfateIndoximodLabetalolGluconic Acid4-Hydroxypropranolol glucuronide2-[(E)-2-(3-Nitrophenyl)vinyl]quinoline11-EpicortisolDocebenoneHomodolicholide2-Polyprenyl-3-methyl-5-hydroxy-6-methoxy-1,4-benzoquinoneAeglinAB-ChminacaGlaucamine3-hydroxytridecanoic acidMukurozidiolBufalinTrans-p-Menthane-1,7,8-triol 8-glucoside(R)-2-Hydroxystearic AcidNicotinic AcidIsoleucyl-ValineByssochlamic acid2-(Arabinosylamino)-3-(glucosylamino)propanenitrileP-Hydroxyhippuryl-his-leu-OHXanthurenic acid 8-O-sulfateCincassiol BPhysangulide1,2,3,4-Tetrahydroisoquinolin-1-yl formateThreonylphenylalanineGlycyl-MethionineMilbemycin beta12-Methoxy-N-(1-phenethylpiperidin-4-yl)-N-phenylacetamideSalicyluric acid10-Oxo-11-octadecen-13-olideIsolithocholic Acid3',4'-DihydrodiolAcebutolol1-[2,3-Dimethyl-2-(2-methylbut-3-en-2-yl)furan-3-yl]-3,5-dihydroxy-4-methoxyhexan-2-oneMethyl 5-hydroxyoxindole-3-acetate2-Hydroxymyristic Acid4-NonylphenolfalseGut microbiota-derived 3-indoleacrylic acid mediates ferulic acid protection against aflatoxin B1 hepatotoxicity via AhR-ferroptosis inhibition Aflatoxin B1 (AFB1)-induced hepatic inflammation poses severe global health burdens with limited interventions. Here, we demonstrated that ferulic acid (FA), a cereal-derived polyphenol, alleviated AFB1 hepatotoxicity by remodeling gut microbiota and activating microbial tryptophan metabolism. FA enriched Peptostreptococcus anaerobius (P. anaerobius), enhancing its conversion of tryptophan to 3-indoleacrylic acid (IA) via transcriptional upregulation of key enzymes (Aromatic amino acid aminotransferase, Phenylacetate dehydrogenase, Pylacetate dehydratase (fldBC)). The recombinant fldBC enzyme catalyzed the production of IA from indole-3-lactic acid in vitro. P. anaerobius attenuated AFB1-induced hepatic inflammation and ferroptosis in mice was attributable to bacterial production of IA. Mechanistically, IA competitively inhibited AFB1 binding to the aryl hydrocarbon receptor (AhR), thereby suppressing AhR-driven ferroptosis, evidenced by rescued GPX4/xCT expression and reduced iron overload. Crucially, integrated single-cell RNA sequencing and flow cytometry revealed that IA mitigated AFB1-induced hepatitis by polarizing Kupffer cells toward an M2-reparative phenotype. In summary, FA modulates gut microbiota composition and tryptophan metabolism, particularly by increasing the relative abundance of P. anaerobius and enhancing IA production, thereby inhibiting AFB1-induced AhR activation, ferroptosis, and macrophage polarization, ultimately alleviating hepatic inflammation. Our findings establish a gut microbiota-IA-AhR-ferroptosis axis as a therapeutic target for mycotoxin-induced liver 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