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f.scanftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_NEG/Dog_OviductFluid_Control_02_NEG.wiff.scanftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_POS/Dog_OviductFluid_QC03_POS.wiffftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_NEG/Dog_OviductFluid_FA_02_NEG.wiffftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_NEG/Dog_OviductFluid_Control_01_NEG.wiffftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_POS/Dog_OviductFluid_Control_02_POS.wiffftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493/FILES/RAW_FILES/OviductFluid_POS/Dog_OviductFluid_FA_01_POS.wiff.scanprimaryOK200ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15493<p>Metabolite features were annotated using experimental mass-to-charge ratio (m/z), retention time, and available mass-spectral annotation information. Compound annotations were cross-referenced against public metabolite databases, including HMDB and KEGG where database identifiers were available. Additional spectral-library or compound-matching information was retained where available in the processed datasets. Metabolite name, m/z, retention time, database identifier, molecular formula, and sample abundance information were compiled into polarity-specific metabolite assignment files.</p>MetaboLightsPublicLiquid Chromatography MS - positive - reversed-phase-chromatographyLiquid Chromatography MS - negative - reversed-phase-chromatographyLiquid Chromatography MS - negative - reverse-phase<p>Metabolite separation was performed by reversed-phase liquid chromatography prior to mass spectrometric detection. Separate LC-MS/MS assays were performed for ovary, oviduct fluid, and serum samples in positive and negative ionization modes. Chromatography instrument, column model, column type, and other assay-specific chromatography information are recorded in the corresponding assay metadata files.</p>Untargeted LC-MS/MS metabolomics of ovary, oviduct fluid, and serum from dogs supplemented with folic acid.xiamen universitySite Luoovaryoviductblood serumsolventmass spectrometry assay<p>Samples were prepared for untargeted LC-MS/MS metabolomic analysis using the laboratory sample-preparation workflow established for each biological matrix. Ovary, oviduct fluid, and serum samples were processed separately, and pooled quality-control samples were prepared from representative study samples for monitoring analytical reproducibility. The resulting extracts were subjected to LC-MS/MS analysis in positive and negative ionization modes.</p>blank sampleCanis lupus familiarishttps://www.ebi.ac.uk/metabolights/MTBLS15493ZHAO Baobao. Northwest A&F University. 2023060371@nwafu.edu.cn.<p>Raw LC-MS/MS data were processed to generate polarity-specific metabolomic feature tables. Detected features were organized using experimental mass-to-charge ratio (m/z), chromatographic retention time, and sample abundance values. Features from individual biological samples and pooled quality-control samples were aligned and compiled into processed metabolite tables. Positive- and negative-ion datasets were handled separately and subsequently formatted as MetaboLights metabolite assignment files.</p>Treatmentlstxmu@gmail.com<p>Canine ovary, oviduct fluid, and serum samples were collected from control and folic acid-supplemented groups. Biological samples were assigned to the corresponding control or folic acid treatment group prior to LC-MS/MS analysis. Pooled quality-control samples were included for analytical quality assessment, and blank samples were included where applicable. Sample identifiers, tissue types, treatment groups, and sample types are provided in the study sample metadata.</p>Metabolomicsultra-performance liquid chromatography-mass spectrometrypooled quality control sampleMetabolomicsoviductWaters ACQUITY UPLC H-Class Systemuntargeted analysissolvent blankexperimental sampleblank sampleovaryCanis lupus familiarisblood serumTripleTOF 6600mass spectrometrysolventQ Exactive HFQ Exactiveultra-performance liquid chromatography-mass spectrometrypooled quality control sampleMetabolomicsoviductWaters ACQUITY UPLC H-Class Systemuntargeted analysissolvent blankexperimental sampleovaryblank sampleCanis lupus familiarisblood serumTripleTOF 6600mass spectrometrysolventQ Exactive HFQ Exactive<p>Untargeted mass spectrometry was performed in both positive and negative ionization modes. Ovary samples were analyzed using a Thermo Scientific Q Exactive HF mass spectrometer, oviduct fluid samples were analyzed using an AB SCIEX TripleTOF 6600 mass spectrometer, and serum samples were analyzed using a Thermo Scientific Q Exactive mass spectrometer. Electrospray ionization was used where documented in the assay metadata. Mass spectral acquisition ranges, ionization polarity, mass analyzer, ion source, and instrument-specific information are provided in the corresponding assay metadata files.</p>Benzoic acidTaurineCYCLOATENaringeninp-Cresol sulfateZinniolFumaric acid (not validated)flecainideCer(d18:1/23:0)(+)-Aspidospermidine3-(Methylthio)acryloyl-CoA; Methylthioacryloyl-CoA; 3-(Methylsulfanyl)acryloyl-CoAPC(16:0/18:2)Trifluoroacetic acidFluorenoneOxidized Photinus luciferinAPRINDINEPC(18:2/18:1)O-carbamyl-dl-serine3,5,3'-triiodothyropyruvic acidPE(18:1/20:4)ThreonineAconinePC(15:0/22:6)3-O-MethylquercetinN-EthylglycinePC(16:0/16:1)Arsenic acidPE(18:1/22:6)DICHLOROMETHANEPC(14:0/14:0)Propynoic acidGlutamic acidMetaphosphoric acidGlutathioselenol; GSSeHSemilepidinoside A3-Hydroxypyridine sulfate1,3-Diarachidin1-Hydroxy-3-methoxy-7-primeverosyloxyxanthoneedaravoneN1-(5-Phospho-a-D-ribosyl)-5,6-dimethylbenzimidazole1,7-di-O-phosphonohept-2-uloseN-AcetylornithinePE(P-16:0/20:3)GDP-4-amino-4,6-dideoxy-alpha-D-mannose; GDP-alpha-D-perosaminePE(22:5/22:6)9-mercapto-11,17-dioxoandrosta-3,5-dien-3-yl acetateNCIOpen2_008042Pyroglutamic acidCE(DiMe(9,5))PC(15:0/16:0)FENSULFOTHIONU 6796AlanineIsonicotinoyl-NADP adduct; INH-NADP adductPhenylalanine4'-ChloroacetanilideLPA(12:0)Amaranthin5-Amino-4-chloro-2-(5-hydroxymuconoyl)-3(2H)-pyridazinone; 5-Amino-4-chloro-2-(2-hydroxymuconoyl)-3(2H)-pyridazinonePC(14:0/16:1(9Z))PC(14:0/18:3(9Z,12Z,15Z))XanthineCaffeic acidArsonoacetic acidGinkgolide BCefazolin(Z)-5-Hexadecenoic acid2-(4-Chloro-3,5-dimethylphenoxy)-N-(2-phenyl-2H-benzotriazol-5-yl)-acetamideketaminePE(16:0/18:3(9Z,12Z,15Z))PC(15:0/16:1)SolasonineMK826Pantothenic acidPE(20:3/22:6)PS(22:6/22:6)1,2,3,6-TetragalloylglucoseTripoxyrollin2-(Methylthio)benzothiazolePerfluorododecanoic acidDiflunisal(3-hydroxy-2-octadeca-9,12-dienoyloxypropyl) octadeca-9,12-dienoateDiallyl tetrasulfideSCHEMBL4364428Cer(d18:1/24:1)3-(4-hydroxy-3,5-diiodophenyl)-2-oxopropanoic acidShikimic aciddITPPC(16:1/16:1)AcalyphinTHIOACETAMIDE1,6-DINITROPYRENETolytoxinIDPfentanylPC(14:0/18:2)Phenyl vinyl sulfidePelargonidin 3-O-3'',6''-O-dimalonylglucosideTheacitrin APC(14:0/16:0)Octaethylene glycolHydriodic acidPE(P-18:1/22:4)Pelargonidin 3-glucosideTyrosineIsoplumbaginNeobetanin2-amino-4-oxo-4-phosphonooxybutanoic acidMethcillinCer(d18:1/22:0)2-Amino-5-chloromuconate 6-semialdehydeUridine, trisodium saltCHEBI:821951,2,4,5-Tetrathianethiotepa4-Hydroxyquinoline2-Hydroxy-2-methylbutyric acidhypotaurinePeroxynitrous acidSuccinic acidHypoxanthineOxypurinolPC(14:0/16:1)N-(2R-Hydroxytricosanoyl)-2S-amino-1,3S,4R-octadecanetriolJamaicamide CRugulosinmollicellin FCHEMBL291413-DeazauridinePC(14:0/20:4)Cer(d18:1/25:0)SULFURIC ACIDbusulfanAzelaic acidlysylhistidineemedastinePE(P-18:0/18:2)IprobenfosSCHEMBL10001351CAIR; 4-Carboxy-AIRPE(20:5/22:6)Fasciculic acid CPE(P-18:1/22:6)ThiamineCHLOROPRENE4-Keto-anhydrotetracycline; 4-Ketoanhydrotetracycline; 4-Keto-ATC; 4-Dedimethylamino-4-oxo-anhydrotetracycline; 4-De(dimethylamino)-4-oxoanhydrotetracycline; (4aR,12aS)-3,10,11,12a-Tetrahydroxy-6-methyl-1,4,12-trioxo-4a,5-dihydrotetracene-2-carboxamideCilastatinNithiazideUric acidFLAMPROPMangiferin 6'-gallatePE(P-16:0/20:0)3-(2,2-Dichlorovinyl)-2,2-dimethylcyclopropane carboxylic acidPS(18:0/20:4(8Z,11Z,14Z,17Z))pentamidinePerfluorohexanesulfonic acidPE(22:6/16:0)PE(O-16:1(1Z)/22:6(4Z,7Z,10Z,13Z,16Z,19Z))9-fluoro-11,17-dihydroxy-10,13,17-trimethyl-1,2,6,7,8,11,12,14,15,16-decahydrocyclopenta[a]phenanthren-3-one2,3-Dimercaptosuccinic acid5-hydroxy-2-oxo-4-ureido-2,5-dihydro-1H-imidazole-5-carboxylic acid3-Bromo-5-chloro-2,6-dihydroxybenzoic acid2-ureidoglycineLactic acidArchaeolLumichrome1,2-Dipalmitoyl-rac-glycero-3-phosphoethanolamineGlutaminefalseUntargeted LC-MS/MS metabolomics of ovary, oviduct fluid, and serum from dogs supplemented with folic acidThis dataset contains untargeted metabolomic profiles of canine ovary, oviduct fluid, and serum samples collected from control and folic acid (FA)-supplemented groups. LC-MS/MS metabolomics was performed in both positive and negative ionization modes to characterize metabolic alterations associated with folic acid supplementation and to investigate systemic and reproductive-tract metabolic responses. Raw mass spectrometry data, including biological samples, pooled quality-control samples, and blank samples where applicable, are provided to support data reproducibility and downstream metabolomic analyses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