Metabolites were annotated by matching accurate mass, retention time, and MS/MS fragmentation information against mzCloud, mzVault, and MassList databases. Positive and negative ion mode datasets were processed separately.
"],"repository":["MetaboLights"],"study_status":["Public"],"ptm_modification":[""],"instrument_platform":["Liquid Chromatography MS - negative - reverse-phase","Liquid Chromatography MS - positive - reverse-phase"],"chromatography_protocol":["Chromatographic separation was performed using a Vanquish UHPLC system equipped with a Hypersil GOLD C18 column (100 × 2.1 mm, 1.9 μm; Thermo Fisher Scientific). The column temperature was maintained at 40°C, and the flow rate was 0.2 mL/min. For positive ion mode, mobile phase A consisted of 0.1% formic acid in water, and mobile phase B was methanol. For negative ion mode, mobile phase A consisted of 5 mmol/L ammonium acetate in water, adjusted to pH 9.0, and mobile phase B was methanol. The gradient elution program was as follows: 0–1.5 min, 2% B; 1.5–4.5 min, 2%–100% B; 4.5–10.0 min, 100% B; 10.0–10.1 min, 100%–2% B; and 10.1–12.0 min, 2% B.
"],"publication":["Maternal plasma metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving."],"submitter_name":["yuzhen Sui"],"submitter_affiliation":["North West Agriculture and Forestry University"],"organism_part":["plasma"],"technology_type":["mass spectrometry assay"],"disease":[""],"extraction_protocol":["Chromatographic separation was performed using a Vanquish UHPLC system equipped with a Hypersil GOLD C18 column (100 × 2.1 mm, 1.9 μm; Thermo Fisher Scientific). The column temperature was maintained at 40°C and the flow rate was 0.2 mL/min. For positive ion mode, mobile phase A consisted of 0.1% formic acid in water and mobile phase B was methanol. For negative ion mode, mobile phase A consisted of 5 mmol/L ammonium acetate in water, adjusted to pH 9.0, and mobile phase B was methanol. The gradient elution program was as follows: 0–1.5 min, 2% B; 1.5–4.5 min, 2%–100% B; 4.5–10.0 min, 100% B; 10.0–10.1 min, 100%–2% B; and 10.1–12.0 min, 2% B.
"],"organism":["Bos taurus"],"full_dataset_link":["https://www.ebi.ac.uk/metabolights/MTBLS15538"],"author":["yuzhen Sui. North West Agriculture and Forestry University. sui1632020@163.com."],"data_transformation_protocol":["Raw LC-MS/MS data were processed using Compound Discoverer software version 3.3. Data processing included retention time correction, peak detection, peak alignment, peak area integration, and relative quantification. Peak intensities were normalized using the total peak area method. Metabolic features with a coefficient of variation greater than 30% in quality control samples were excluded from downstream analysis.
"],"study_factor":["Treatment"],"submitter_email":["sui1632020@163.com"],"sample_collection_protocol":["Maternal plasma samples were obtained from Holstein dairy cows enrolled in a prepartum chromium propionate supplementation experiment. Cows in the control group received a basal total mixed ration without supplemental chromium propionate, whereas cows in the high-dose chromium propionate group received the same ration supplemented with 20 g chromium propionate per cow per day, providing 8 mg Cr(III) per cow per day, from 21 days before expected calving until parturition. On the day of calving, blood samples were collected from the coccygeal vein into 10 mL lithium heparin vacuum tubes. Plasma was separated by centrifugation at 2,000 × g for 10 min at 4°C, aliquoted into sterile tubes, and stored at −80°C until untargeted metabolomic analysis.
"],"omics_type":["Metabolomics"],"study_design":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","Metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","periparturient period","Bos taurus","plasma","LC_MS_MS","pooled sample"],"curator_keywords":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","Metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","periparturient period","Bos taurus","plasma","LC_MS_MS","pooled sample"],"mass_spectrometry_protocol":["Mass spectrometric detection was performed using an Orbitrap Exploris 120 high-resolution mass spectrometer equipped with an electrospray ionization source. Samples were analyzed separately in positive and negative ion modes. The spray voltage was set to 3.5 kV, and full-scan MS data were acquired over an m/z range of 100–1,500. MS/MS spectra were acquired in data-dependent acquisition mode for metabolite structural annotation.
"],"metabolite_name":["2-{1-[2-(4-benzhydrylpiperazino)-2-oxoethyl]cyclopentyl}acetic acid","2-morpholino-1-phenyl-1-ethanol","Corticosterone","Prostaglandin G2","DL-Panthenol","2-[(3S)-1-(2-Methylbenzyl)-3-pyrrolidinyl]-1,3-benzoxazole","8-Aminooctanoic acid","Methyl nicotinate","PC O-32:1","PC O-32:3","1-(3,4-dimethoxyphenyl)ethan-1-one oxime","PC O-32:2","L-Histidine","PC O-32:4","LPC 16:0-SN1","PC O-32:7","2-Arachidonoyl glycerol","PC O-32:6","SM 8:1;2O/28:7","1-[(3,5-dimethylisoxazol-4-yl)sulfonyl]piperidine","L-Tyrosinemethylester","4-methylphenyl 1-ethyl-3-methyl-1H-pyrazole-5-carbothioate","N-[1-(4-methoxy-2-oxo-2H-pyran-6-yl)-2-methylbutyl]acetamide","Methyl indole-3-acetate","6-Methoxy-2-naphthoic acid","6-fluoro-3,4-dihydro-2H-pyrano[2,3-b]quinolin-5-amine","3-(5,7-dimethoxy-4-oxo-4H-chromen-2-yl)propanoic acid","Hexanoylcarnitine","HPK","FLK","Dl-Indole-3-lactic acid","L-lysine","Bis(3,5,5-trimethylhexyl) phthalate","Proline-hydroxyproline","Estradiol","PC 15:0_16:2","SM 8:1;2O/26:1","LPC 24:1-SN1","Pyridoxamine 5-phosphate","3-(propan-2-yl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione","2-hydroxy-6-[(8Z,11Z)-pentadeca-8,11,14-trien-1-yl]benzoic acid","Nor-9-carboxy-δ9-THC","SM 8:1;2O/26:2","Methyltestosterone","6-Methylquinoline","PC 42:5","FMK","Oxohongdenafil","D-(+)-Maltose","PC 42:9","5-Hydroxylysine","Fexofenadine","PC 42:8","LPC 30:3","6,8-dihydroxy-3-(10-hydroxyundecyl)-3,4-dihydro-1H-2-benzopyran-1-one","Oleamide","SM 8:1;2O/15:1","N-Acetylneuraminic acid","HRH","Pantothenic acid","10-Undecenoic acid","SL 12:2;O/16:2;O","Vindoline","3-hydroxy-2-octylpentanedioic acid","5-fluoro AB-PINACA N-(4-hydroxypentyl) metabolite","7-Ketocholesterol","L-Ornithine","WPH","(±)15-HETE","PC 14:0_15:1","N-Formylkynurenine","PC 14:0_15:0","PC O-30:3","PC O-30:4","LPE 22:6","4-[1-(dimethylamino)ethylidene]-2-phenyl-1,3-oxazol-5(4H)-one","CAR 18:2","CAR 18:1","CAR 18:0","PC 34:4_36:10","(2S)-2-(2-hydroxypropan-2-yl)-2H,3H,7H-furo[3,2-g]chromen-7-one","PC O-30:1","4-oxododecanedioic acid","PE 18:2_18:2","4-Methoxybenzaldehyde","16,16-Dimethyl prostaglandin A2","1-Phenyl-3-methyl-5-pyrazolone","4-Hydroxyquinoline","(12Z)-9,10,11-trihydroxyoctadec-12-enoic acid","5-Henicosyl-1,3-benzenediol","Androstenedione","16,16-Dimethyl prostaglandin A1","3-(2-Naphthyl)-D-Alanine","FPK","Indole","PC 17:1_18:5","LPC 24:0-SN1","DL-Arginine","FIBF-d7","10-Nitrolinoleate","4-(2,3-dihydro-1,4-benzodioxin-6-yl)butanoic acid","L-Carnitine","o-Cresol","SM 8:1;2O/28:0","PC 40:8","PC 40:5","PC 40:6","PE O-14:1_20:4","DL-Norvaline","1,3,5-Trimethylpyrazole","2-Hydroxycinnamic acid","4-morpholinobenzoic acid","Noroxycodone-d3","2-(14,15-Epoxyeicosatrienoyl) glycerol","FRH","Hydrocortisone acetate","Melatonin","4-Hydroxyretinoic Acid","Daidzin","L-Phenylalanine","5-Methylcytosine","Propionyl-L-carnitine","2,5-bis(4-hydroxy-3-methoxyphenyl)-3,4-dimethyloxolan-3-ol","Oleanolic acid","PC O-36:5","PC O-36:4","PC O-36:9","Ecgonine","PC(16:0/16:0)","L-(-)-Methionine","PC O-36:1","PC 16:0_17:1","Tetrahydrocortisone","gamma-Glutamylmethionine","12-oxo Phytodienoic Acid","CAR 16:1","Threonine","SM 36:1;2O","LPC O-21:1","3-(2-naphthyl)-5-(trifluoromethyl)-1H-pyrazole","1-(2'-fluoro[1,1'-biphenyl]-4-yl)propan-1-one","DL-Tryptophan","LPC 22:5-SN1","cis-7-Hexadecenoic Acid","6-benzyl-4-oxo-1,4-dihydropyridine-3-carboxamide","DGDG O-8:0_2:0","PC O-14:0","4-Methoxycinnamic Acid","Acetanilide","ethyl 3-oxo-3-(1H-pyrazol-5-ylamino)propanoate","1,4-dihydroxyheptadec-16-en-2-yl acetate","N'-[(2,4-dihydroxyphenyl)methylene]-4-methylbenzenesulfonohydrazide","PC 18:1_19:2","6-(3-hydroxybutan-2-yl)-5-(hydroxymethyl)-4-methoxy-2H-pyran-2-one","Docosanamide","2-Thiocytidine","4-(3,4-dihydro-2H-1,5-benzodioxepin-7-yl)-2-methyl-1,3-thiazole","SM 8:1;2O/19:0","Prostaglandin K2","Tauroursodeoxycholic acid","Pipecolic acid","Perillartine","Indole-3-acrylic acid","PC O-34:7","PC O-34:6","PC O-34:9","PC O-34:8","LPC 42:12-SN2","PC O-34:1","Indole-3-carboxaldehyde","PC O-34:3","PC O-34:4","11-Ketoetiocholanolone","4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylamino)-4-oxobutanoic acid","Asp-Phe","2-methyl-2,3,4,5-tetrahydro-1,5-benzoxazepin-4-one","Bisphenol A","PC 19:1_19:1","Ingenol-3-angelate","L-Glutamate","Cafestol","PE 17:0_17:1","1H-indene-3-carboxamide","2-(2-methyl-1H-indol-3-yl)acetonitrile","QNK","3,6-dibenzyl-1,2-dihydro-1,2,4,5-tetraazine","LPC 22:6-SN2","LPC 22:6-SN1","L-Adrenaline","SM 32:2;2O","PC O-12:0","3-[4-methyl-1-(2-methylpropanoyl)-3-oxocyclohexyl]butanoic acid","(2E,4E)-N-[2-(4-hydroxyphenyl)ethyl]dodeca-2,4-dienamide","Prostaglandin J2","Cholecalciferol","Thymine","16α-Hydroxydehydroepiandrosterone","15-Deoxy-Δ12,14-prostaglandin A1","1-Methyluric acid","Stercobilin","Diethyl maleate","Oleoyl-L-alpha-lysophosphatidic acid","1-Methyladenosine","4-Hydroxyisoleucine","2-[3-methyl-2-(methylimino)-4-oxo-1,3-thiazolan-5-yl]acetic acid","Taurodeoxycholic Acid (sodium salt)","Coenzyme Q2","1-(4-methyl-2-morpholino-1,3-thiazol-5-yl)ethan-1-one","Guanidineacetic acid","3-Hydroxy-3-methylbutanoic acid","SPB 18:1;2O","PC 20:5_22:6","Oxolamine","LSD-d3","5,8-dihydroxy-10-methyl-5,8,9,10-tetrahydro-2H-oxecin-2-one","5-Hydroxyindole-3-acetic acid","CAR 12:1","PC O-29:1","PC O-29:0","N6-Succinyl Adenosine","SM 8:1;2O/31:0","7-Methylguanosine","R-1 Methanandamide phosphate","6β-Oxycodol N-oxide","PE O-14:1_18:1","Stearoyl Ethanolamide","2,3-dihydroxypropyl 12-methyltridecanoate","PC 38:0","PC 38:6","Dibenzoyl Thiamine","PC 38:4","PC 38:5","Alternariol","PC O-18:0","LPC 20:2-SN1","PC O-18:1","PC O-18:2","cis,cis-Muconic acid","PC O-18:3","Octanedioic acid","LPC 38:6","Cer 8:0;3O/15:1;(2OH)","5-hydroxy-6,7-dimethoxy-2-phenyl-4H-chromen-4-one","LPC O-15:0","2-Oxindole","N1-(1-benzyl-4-piperidyl)-4-chlorobenzene-1-sulfonamide","N-Tetradecanamide","SM 8:0;2O/25:0","LPC 22:3-SN1","N-Methyldioctylamine","Pyrogallol","8,15-Dihete","Testosterone","Levothyroxine","Dibutyl sebacate","N1-[4-hydroxy-6-(methoxymethyl)pyrimidin-2-yl]acetamide","4-Aminobutyric acid","Isohomovanillic acid","Cuminaldehyde","(2,6-dimethylmorpholino)(1-methyl-5-nitro-1H-pyrazol-4-yl)methanone","L-Kynurenine","PC 18:4_18:4","Creatine","4-(4-nitrophenylazo)aniline","PC O-38:4","4-oxo-5-phenylpentanoic acid","PC O-38:7","PC O-38:6","PC O-38:9","PC O-38:8","Cytosine","16-Heptadecyne-1,2,4-triol","PC 19:2_18:5","(S)-Leucic acid","PC 19:2_18:3","PC 19:2_18:4","SM 30:1;2O","N2,N2-Dimethylguanosine","CAR 10:1","N-acetyl-L-ornithine","ethyl 3-[(4-chlorophenethyl)amino]-2-cyanoacrylate","2-[(3S)-1-Benzyl-3-pyrrolidinyl]-1-methyl-1H-benzimidazole","PC 36:2","PC 34:3_36:10","SM 9:1;2O/28:7","α-Hydroxyhippuric acid","SM 8:1;2O/20:0","Nicotinuric Acid","2-(4-methoxyphenyl)-3-(1H-pyrazol-4-yl)acrylonitrile","LPC O-13:1","PC O-16:0","LPC 20:3-SN1","PC O-16:1","3-(methylsulfonyl)-2H-chromen-2-one","LPC 23:0-SN1","KKK","Ergosta-5,7,9(11),22-Tetraen-3-beta-Ol","(11E,15Z)-9,10,13-trihydroxyoctadeca-11,15-dienoic acid","LPC 22:4-SN1","L-(+)-Citrulline","D-Panthenol","L-beta-Imidazolelactic acid","Vitamin A","Sodium cholate","Delta-Tridecalactone","Stearamide","Sphingosine (d18:1)","Asp-Phe methyl ester","PC O-40:6","N4-Acetylcytidine","PC O-40:4","PC O-40:9","SM 8:1;2O/35:0","Luteolin-3',7-Diglucoside","PC O-40:7","PC O-40:8","SM 8:0;2O/18:0","CE 18:2","Quinoline-4-carboxylic acid","7-{[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy}-2H-chromen-2-one","25-hydroxycholecalciferol","Skatole","SM 8:1;2O/22:0","5-[(10Z)-14-(3,5-dihydroxyphenyl)tetradec-10-en-1-yl]benzene-1,3-diol","2-phenyl-2,4,6,7-tetrahydrothiino[4,3-c]pyrazol-3-ol","PC 18:0_18:1","Choline Glycerophosphate","SM 8:1;2O/22:2","All-Trans-13,14-Dihydroretinol","LPC 34:3","3,4-dihydro-4-oxo-2H-1,3-benzoxazine-2-spiro-4'-(1'-ethylpiperidine)","Diflorasone","Di(2-ethylhexyl) phthalate","Decanoylcarnitine","Choline","beta-Estradiol 17-Acetate","L-Methionine sulfone","2-methyl-6-{[(5-phenyl-2-thienyl)carbonyl]amino}benzoic acid","SDMA","(5E)-7-methylidene-10-oxo-4-(propan-2-yl)undec-5-enoic acid","Octadecanamine","L-Hydroxyproline","3,4-Methylenedioxyethamphetamine","PC 42:9_44:12","PC 15:1_15:1","L-Isoleucine","Bicyclo Prostaglandin E2","PC 19:0_19:1","SM 33:1;2O","SM 8:1;2O/26:6","PC 18:2_19:2","PE O-13:1_20:4","Palmitoylcarnitine","Indole-3-pyruvic acid","Undecanedioic acid","Glycyl-L-leucine","N1-[3,5-di(trifluoromethyl)phenyl]-3-(3-thienyl)acrylamide","2-{(3S)-1-[4-(Trifluoromethyl)benzyl]-3-pyrrolidinyl}-1H-benzimidazole","SM 9:1;2O/24:6","Diosgenin","2,3-Dinor-11β-prostaglandin F2α","PC O-42:10","PC O-42:11","SM 43:1;2O","INK","L-Argininosuccinate","Bitertanol","3-(3-morpholinopropyl)-2-(2-pyridinyl)-2,3-dihydro-4(1H)-quinazolinone","SM 8:1;2O/24:3","SM 8:1;2O/24:2","5,7-dimethyl-4-oxo-4H-chromene-3-carbonitrile","SM 8:1;2O/24:1","LPC O-17:2","SM 8:1;2O/24:0","H-Gly-Pro-OH","LPC O-17:0","Furanyl fentanyl 3-furancarboxamide isomer-d5","D-(+)-Proline","SM 8:0;2O/27:0","DL-Glutamine","indoline-2-carboxylic acid","Phosphocholine","pentane-1,2,3,4,5-pentol","5-Methyl-dl-tryptophan","5-(hydroxymethyl)-4-methoxy-2,5-dihydrofuran-2-one","Estrone","SM 8:1;2O/13:1","ethyl 3-oxo-5,6-diphenyl-2,3-dihydropyridazine-4-carboxylate","SM 8:1;2O/13:0","LPC 20:1-SN1","2-Methoxyestradiol (2-MeOE2)","LPC 40:8","LPC 40:7","5,7-dihydroxy-3-(4-hydroxyphenyl)-4H-chromen-4-one","LPC 42:10","Leu-Pro","PC O-20:0","L-(-)-alpha-Amino-epsilon-Caprolactam","Limonin","SM 9:1;2O/30:6","SM 9:1;2O/30:7","SM 9:1;2O/30:8","Quinoline","Feruloyl Putrescine","SM 39:1;2O","All trans-Retinal","2-Anisic acid","Biotin","D-Raffinose","LPC 20:5-SN1","3-Hydroxyanthranilic acid","Tributyl citrate","2-phenyl-4H-furo[2,3-h]chromen-4-one","9-HOTrE","PC 16:1_16:2","PC 14:0_14:0","(+/-)11(12)-DiHET","Oleic acid","PC O-33:2","PC O-33:1","PC O-33:3","H-Trp-NH2","Lysopc 20:4","PC 17:2_17:2","4-Methylaminoantipyrine","Lysopc 20:0","gamma-Nonanolactone","11-Oxoetiocholanolone","PC O-40:11","PI 38:4","PC O-40:10","PI 38:3","LPC 18:1-SN1","PC O-22:4","4-Pyridoxic acid","PC O-22:5","LPC 22:0-SN1","Azaspiracid-1","Octyl hydrogen phthalate","5-[4-(phenylsulfonyl)phenyl]-1H-pyrazole","2,4-dihydroxyheptadec-16-en-1-yl acetate","LPC 42:9","N-Acetyl-L-methionine","13,14-dihydro-15-keto Prostaglandin A2","5'-S-Methyl-5'-thioadenosine","DL-Lysine","17alpha-Hydroxyprogesterone","PC 42:6_44:12","1,7-bis(4-hydroxyphenyl)-5-methoxyheptan-3-one","PC 34:6_34:7","SM 8:1;2O/29:0","SM 9:1;2O/32:1","GQH","Biliverdin","PC 41:5","2-(4,4-diphenyl-1-piperidinobuta-1,3-dienyl)phenyl acetate","LPC 20:4-SN1","Palmitoyl sphingomyelin","PC O-42:9","TKK","1-Methylguanine","2-hydroxy-3,6-diphenylcyclohexyl acetate","PC O-42:8","SM 8:1;2O/18:0","ENH","SPB 16:1;2O","Hydroxyprogesterone caproate","7-(1-pyrrolidinyl)pyrimido[4,5-d]pyrimidin-4-amine","Proline","ethyl 3-cyano-2-hydroxy-6-phenylisonicotinate","U-44069","Acipimox","LPC 20:0","TLH","1-Caffeoylquinic Acid","PC O-31:2","(2E)-6-hydroxy-2-methyl-6-(4-methylphenyl)hept-2-enoic acid","PC O-31:1","PC O-31:3","PC O-31:6","PC 16:2_16:2","1,2-dihydroxyheptadec-16-yn-4-yl acetate","LPC 18:0-SN1","CAR 17:0","Indole-3-acetic acid","3-methyl-5-oxo-5-(4-toluidino)pentanoic acid","PC O-31:0","L-Methionine Methyl Ester","N1-(2-amino-2-oxoethyl)-2-(isopropylthio)acetamide","(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-(propan-2-yloxy)oxane-3,4,5-triol","PC O-20:4","PC O-20:3","PI 36:2","prop-2-ynyl 3-({[amino(imino)methyl]thio}methyl)benzoate hydrochloride","PC O-20:5","PI 36:1","LPC 19:0-SN1","4-(1H-pyrazol-1-yl)-N,N-bis(2-pyridinylmethyl)benzenesulfonamide","PC 17:1_17:2","gamma-Glutamyltyrosine","N-(5-acetamidopentyl)acetamide","2-Arachidonyl Glycerol ether","Phlorizin","methyl 3,4,5-trihydroxycyclohex-1-ene-1-carboxylate","LPC 26:0-SN1","PC 18:2_20:3","Taurocholic acid","Folinic acid","Ergosterol peroxide","Norfentanyl","8,8-dimethyl-2-phenyl-4H,8H-pyrano[2,3-h]chromen-4-one","Avocadyne 1-acetate","Propionylcarnitine","4-decyl-3-hydroxy-5-oxooxolane-2,3-dicarboxylic acid","p-Mentha-1,3,8-triene","3-amino-2-phenyl-2H-pyrazolo[4,3-c]pyridine-4,6-diol","PI 34:1","Obscurolide A1","5-Methylcytidine","PC O-37:5","PC O-37:7","benzaldehyde 1-(2,4-dinitrophenyl)hydrazone","β-Cortolone","Dehydroepiandrosterone (DHEA)","(±)13-HpODE","N-Acetyl-aspartic acid","Creatinine","AKK","Acetyl-L-carnitine","CAR 15:1","CAR 15:0","PC 19:1_18:2","LPC O-22:0","Glycolithocholic acid","Valine","2-Amino-1,3,4-octadecanetriol","SM 32:1;2O","N-[2-chloro-6-(trifluoromethoxy)phenyl]-2,2-dimethylpropanamide","Capsaicin","Linoleoyl ethanolamide","LysoPE 18:2","Cortisol","Bilirubin","SM 8:0;2O/30:0","mesityl(piperidin-4-yl)methanone hydrochloride","PE O-15:1_20:4","PE O-15:1_20:5","PC 15:0_15:0","Betaine","N-Methylhydantoin","7-hydroxy-5-methoxy-2-phenyl-3,4-dihydro-2H-1-benzopyran-4-one","Prunin","AL 8810 Methyl ester","2-(methylsulfanyl)-4-quinazolinamine","4-{3-[(3,4-dihydroxyphenyl)methyl]-2-methylbutyl}benzene-1,2-diol","L-Leucyl-L-Alanine","Cytidine","PC 18:1_18:1","PC 18:1_18:2","Isoquinoline","octadec-9-ynoic acid","P-Aminohippuric Acid","N-Benzylformamide","7-methyl-3-nitroimidazo[1,2-a]pyridine","1-Methylhistidine","3-[3,5-bis(trifluoromethyl)phenyl]-N'-hydroxyprop-2-enimidamide","CAR 24:0","PC 16:0_18:5","PC O-35:5","DL-5-Methoxytryptophan","PC O-35:2","PC O-35:4","2-Thio-acetyl MAGE","4-acetyl-4-(ethoxycarbonyl)heptanedioic acid","DL-2-(acetylamino)-3-phenylpropanoic acid","1-Palmitoylglycerol","CAR 13:0","Testosterone glucuronide","Monoolein","PC 20:3_20:3","dUMP","N-(6-methoxypyridin-3-yl)thiophene-2-carboxamide","Progesterone","APK","3-(3,4-dihydroxyphenyl)propanoic acid","Prolylleucine","Genistin","PC 39:5","DL-Dipalmitoylphosphatidylcholine","L-arginine","PC 39:4","5-(6-hydroxy-6-methyloctyl)-2,5-dihydrofuran-2-one","PC O-17:1","5-Hydroxytryptophan","Kynurenic acid","LPC O-14:0","PC O-17:0","3-Indoleacrylic acid","Methyl 3-indolyacetate","1-Aminocyclohexanecarboxylic acid","Muscone","Palmitoylethanolamide","Taurochenodeoxycholic Acid (sodium salt)","Methionine","N-lactoyl-phenylalanine","LPC 19:2-SN1","MAG (18:3)","NKK","N-[(dimethylamino)methylene]-4-methylbenzenesulfonamide","DL-α-Aminocaprylic acid","2'-Deoxycytidine","Styrene","Rosmarinic acid","2,6-Di-tert-butyl-1,4-benzoquinone","CAR 22:0","LPC 17:1-SN1","11-Deoxy prostaglandin F1α","SM 42:1;2O","1-Stearoylglycerol","NAOrn 15:0/16:0","6-Deoxy-D-glucose","3-Methylcrotonylglycine","3-Methyladipic acid","PC 17:0_18:4","(1E,4Z,6E)-5-hydroxy-1,7-bis(4-hydroxyphenyl)hepta-1,4,6-trien-3-one","PC 17:0_18:2","Glu-Gln","PC 19:0_20:5","Salsolinol","Serotonin","Kojic acid","2-(2-acetyl-3,5-dihydroxyphenyl)acetic acid","Ferulic acid","Leucylproline","L-Homocitrulline","LPC 15:0-SN1","5α-Dihydrotestosterone glucuronide","(S)-Nicotine","8-Hydroxyquinoline","PC 20:2_21:2","α-Aspartylphenylalanine","Cannabidivarin","PC 37:2","Dehydrocholic acid","PC 37:5","LPC 19:1-SN1","PC 16:3_18:5","2-Hydroxyphenylalanine","LPC 18:4-SN1","Methanandamide","PC O-15:0","(S)-AL 8810","PC O-15:1","Fisetin","2-[(butylamino)(imino)methyl]-1-oxohydrazinium-1-olate","LysoPC 10:0","DL-Carnitine","1-[2-(2,5-dimethyl-1H-pyrrol-1-yl)-4-nitrophenyl]-1H-imidazole","Homoarginine","3-Ureidopropionic acid","SM 8:0;2O/22:0","L-aspartic Acid","Dehydroepiandrosterone","1,2-Dipalmitoylphosphatidylglycerol","1-(4-Methoxyphenyl)-2-propanone","LPC 17:0-SN1","Hypoxanthine","1-(2-furyl)pentane-1,4-dione","SM 14:3;2O/22:6","Palmitoyl ethanolamide","D-glutamine","4-[2-(2-oxo-1-imidazolidinyl)ethyl]-1lambda~6~,4-thiazinane-1,1-dione","Heptadecanoic Acid","N-(cyclopropylmethyl)-N'-phenylurea","2-{4-[(4-methylphenyl)sulfonyl]piperazino}-1-morpholino-1-ethanone","LLK","PC O-39:8","N6,N6,N6-Trimethyl-L-lysine","Methyl palmitate","2-Hydroxybutyric acid","5-Methyluridine","PC 18:5_18:5","11β-Hydroxyandrosterone","Palmitoleic Acid","(2E)-3-(3,4-dimethoxyphenyl)prop-2-enoic acid","O1-(2,6-dichlorobenzyl)-4-methoxybenzene-1-carbohydroximamide","D-Ala-D-Ala","Cortisone","Gly-Phe","PC O-28:1","PC O-28:3","D-Proline","SM 8:1;2O/32:0","SM 8:1;2O/32:3","D-Phenylalanine","Methylimidazoleacetic acid","LPC 15:1-SN1","LPC 18:3-SN1","Ouabain","LNH","Tetranor-12(S)-HETE","Panthenol","isoleucine","Pregnenolone","1,7-bis(4-hydroxyphenyl)heptan-3-one","SM 9:1;2O/34:1","SM 8:1;2O/23:0","PC 13:0_13:0","LPC O-18:3","LPC O-18:0","Trifolin","LPC O-18:1","2-(cyclopropylcarbonyl)-3-(4-fluoroanilino)acrylonitrile","SM 8:0;2O/28:0","5-trans prostaglandin F2β","Lysine Butyrate","Abametapir","Sebacic acid","LPC 16:2-SN1","3-Methoxy prostaglandin F1α","N-Phenylacetylglutamine","Methyldopa","Linustatin","Nicotinamide","11(Z),14(Z),17(Z)-Eicosatrienoic acid","PC 21:2_20:3","Ohmefentanyl","15-Deoxy-Δ12,14-prostaglandin J2-2-glycerol ester","LPC 22:0","N-Acetylornithine","Oleoyl ethanolamide","N-(4-butyl-2-methylphenyl)-N'-[4-(4-methylpiperazino)phenyl]urea","Pyridoxamine","L-Pyroglutamic acid","9-Oxo-ODE","Biochanin A","11β-Prostaglandin F2α","Androsterone","Deoxyguanosine","SM 38:1;2O","SM 8:1;2O/34:7","PE O-15:1_18:2","Acetylcholine","SM 8:1;2O/34:8","PE O-15:1_18:3","5-OxoETE","N-Lauroylsarcosine","LPC 18:2-SN1","Thymidine","(±)8-HEPE","PC O-19:0","D-Fructose 6-phosphate","PC O-19:1","3-phenyl-5-(trifluoromethyl)-4,5-dihydro-1H-pyrazol-5-ol","α-Lapachone","LPC O-16:1","Proscillaridin A","1-[3-nitro-4-(2-pyridylthio)phenyl]ethan-1-one","1-[5-(2-phenyleth-1-ynyl)-2-thienyl]ethan-1-one oxime","N-Arachidonoyl-L-serine","HKK","PC 20:4_20:5","N-Methyllysine","DL-Stachydrine","Linolelaidic Acid (C18:2N6T)","(+/-)5(6)-EET Ethanolamide","3'-Adenosine monophosphate (3'-AMP)","2-(2-amino-3-methylbutanamido)-3-phenylpropanoic acid","Ethyl oleate","cis-gondoic acid","13,14-dihydro-15-keto-tetranor Prostaglandin E2","SM 33:2;2O","Phe-Phe","5-ethoxy-2-[(2,3,4,5,6-pentafluorobenzyl)thio]-1H-benzo[d]imidazole","Mag (18:1)","Methionine sulfoxide","Senecionine","p-Hydroxybenzaldehyde","LPC 17:2-SN1","1,3-Dimethyluracil","Palmitic Acid","1-(4-benzylpiperazino)-2-(pyridin-2-ylamino)propan-1-one","LPC 14:1-SN1","16(R)-HETE","PC 18:2_18:2","4-Aminobiphenyl","Deoxycytidine","WKK","LPE 16:0","SM 8:1;2O/36:1"],"additional_accession":[]},"is_claimable":false,"name":"Maternal plasma metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving","description":"This study contains untargeted LC-MS/MS metabolomic profiles of maternal plasma collected on the day of calving from Holstein dairy cows in the control and high-dose chromium propionate supplementation groups. Cows received either a basal total mixed ration without supplemental chromium propionate or the same ration supplemented with high-dose chromium propionate from 21 days before expected calving until parturition. Plasma samples were collected at calving and analyzed to characterize maternal metabolic responses associated with prepartum chromium propionate supplementation during the periparturient 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