{"database":"MetaboLights","file_versions":[{"headers":{"Content-Type":["application/json"]},"body":{"files":{"Tabular":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/m_MTBLS15543_LC-MS_negative_reverse-phase_v2_maf.tsv","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/m_MTBLS15543_LC-MS_positive_reverse-phase_v2_maf.tsv"],"Txt":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/a_MTBLS15543_LC-MS_positive_reverse-phase.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/a_MTBLS15543_LC-MS_negative_reverse-phase.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/i_Investigation.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/s_MTBLS15543.txt"],"Raw":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con6-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con5-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC1-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH6-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con1-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con3-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH5-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC3-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/QC1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH6-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH5-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con5-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/Con6-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH3-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543/FILES/RAW_FILES/CrH1-neg.raw"]},"type":"primary"},"statusCode":"OK","statusCodeValue":200}],"scores":null,"additional":{"ftp_download_link":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15543"],"metabolite_identification_protocol":["Metabolites were annotated by matching accurate mass, retention time, and MS/MS fragmentation information against mzCloud, mzVault, and MassList databases. Positive and negative ion mode datasets were processed separately."],"repository":["MetaboLights"],"study_status":["Public"],"ptm_modification":[""],"instrument_platform":["Liquid Chromatography MS - negative - reverse-phase","Liquid Chromatography MS - positive - reverse-phase"],"chromatography_protocol":["Chromatographic separation was performed using a Vanquish UHPLC system equipped with a Hypersil GOLD C18 column (100 x 2.1 mm, 1.9 um; Thermo Fisher Scientific). The column temperature was maintained at 40 degrees C and the flow rate was 0.2 mL/min. For positive ion mode, mobile phase A was 0.1% formic acid in water and mobile phase B was methanol. For negative ion mode, mobile phase A was 5 mmol/L ammonium acetate in water adjusted to pH 9.0 and mobile phase B was methanol."],"publication":["Rectal-content metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving."],"submitter_name":["yuzhen Sui"],"submitter_affiliation":["North West Agriculture and Forestry University"],"organism_part":["feces"],"technology_type":["mass spectrometry assay"],"disease":[""],"extraction_protocol":["Approximately 100 mg of thawed and well-mixed rectal-content sample was extracted with 500 uL of pre-chilled 80% methanol. Samples were homogenized on ice, vortexed thoroughly, incubated on ice for 5 min, and centrifuged at 15,000 x g for 20 min at 4 degrees C. The supernatant was diluted with LC-MS-grade water to a final methanol concentration of 53%, centrifuged again under the same conditions, and used for LC-MS/MS analysis. Quality control samples were prepared by pooling equal aliquots of all sample extracts."],"organism":["Bos taurus"],"full_dataset_link":["https://www.ebi.ac.uk/metabolights/MTBLS15543"],"author":["yuzhen Sui. North West Agriculture and Forestry University. sui1632020@163.com."],"data_transformation_protocol":["Raw LC-MS/MS data were processed using Compound Discoverer software version 3.3. Data processing included retention time correction, peak detection, peak alignment, peak area integration, and relative quantification. Peak intensities were normalized using the total peak area method. Metabolic features with a coefficient of variation greater than 30% in quality control samples were excluded from downstream analysis."],"study_factor":["Treatment"],"submitter_email":["sui1632020@163.com"],"sample_collection_protocol":["Rectal-content samples were collected aseptically from Holstein dairy cows on the day of calving using sterile rectal sampling gloves. Samples were transferred into sterile tubes, immediately frozen in liquid nitrogen, and stored at -80 degrees C until untargeted LC-MS/MS metabolomic analysis. The analyzed samples were obtained from cows in the control and high-dose chromium propionate supplementation groups."],"omics_type":["Metabolomics"],"study_design":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","rectal content","Metabolomics","LC-MS/MS","untargeted metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","Bos taurus","pooled sample","feces"],"curator_keywords":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","rectal content","Metabolomics","LC-MS/MS","untargeted metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","Bos taurus","pooled sample","feces"],"mass_spectrometry_protocol":["Mass spectrometric detection was performed using an Orbitrap Exploris 120 high-resolution mass spectrometer equipped with an electrospray ionization source. Samples were analyzed separately in positive and negative ion modes. The spray voltage was set to 3.5 kV, and full-scan MS data were acquired over an m/z range of 100-1,500. MS/MS spectra were acquired in data-dependent acquisition mode for metabolite structural annotation."],"metabolite_name":["(+/-)-Equol","LPS 16:0","Phenylacetylglutamine","FAHFA 16:0/9:0","3,3-Dimethylglutaric acid","13(S)-HOTrE","Cytidine-5'-monophosphate","Dl-3,4-Dihydroxymandelic Acid","δ-Ribono-1,4-lactone","Methandrostenolone","LPE O-14:0","mesaconic acid","3,3'-Thiopropionic acid","Prostaglandin H1","D-(-)-Quinic acid","Monensin","3,8,9-trihydroxy-10-propyl-3,4,5,8,9,10-hexahydro-2H-oxecin-2-one","Prostaglandin H2","Cer 18:1;3O/16:0","2-Anisic acid","Biotin","Citrulline","FAHFA 2:0/24:4","D-Raffinose","FAHFA 18:2/20:4","Syringic acid","N-Acetylaspartic acid","N1-(3-amino-4-chlorophenyl)-2-[2,4-di(tert-pentyl)phenoxy]acetamide","N-Acetyl-D-tryptophan","4-Hydroxybenzaldehyde","[1,1'-biphenyl]-2,2'-dicarboxylic acid","SL 17:0;O/15:0;O","FAHFA 3:0/16:0","PG 16:0_18:2","Dl-Indole-3-lactic acid","2-deoxyglucose-6-phosphate","PI-Cer 12:0;2O/21:0;O","Prostaglandin E3","Cer 18:2;2O/16:0;(2OH)","Phellamurin","Paracetamol","Mevalonic acid","2'-O-Methylguanosine","(+/-)14(15)-DiHETE","4-Ethylphenol","2'-O-Methyladenosine","2,2-Bis(hydroxymethyl)propionic acid","PG 5:0_18:0","LPE O-13:1","PE O-18:5_20:0","H-Trp-NH2","Corey Lactone Diol","SL 17:0;O/14:0","all-cis-4,7,10,13,16-Docosapentaenoic acid","PE-Cer 12:0;2O/20:0","6-Ketoprostaglandin F1α","Lysopc 20:0","Tetrahydrocorticosterone","(+/-)12(13)-DiHOME","5-Hydroxytryptophol","(±)10(11)-EpDPA","Glycitein","Pseudouridine","1-methyl-N-(4-piperidinophenyl)-1H-imidazole-4-sulfonamide","Isophorone","2-cyano-3-(3,4-dimethoxyphenyl)acrylic acid","PG 27:0_18:1","trans-10-Heptadecenoic acid","2-[(carboxymethyl)(methyl)amino]-5-methoxybenzoic acid","N-Acetylneuraminic acid","Estriol 17-sulfate","4-Pyridoxic acid","Diethyloxalpropionate","9-(3-O-Methylpentofuranosyl)-1,9-dihydro-6H-purin-6-one","Guanosine","1,3-dipyridin-3-ylpropane-1,3-dione","N-Acetyl-L-methionine","Prostaglandin F1α","12(S)-HETE","Prostaglandin F1β","4-Acetamidobutyric Acid","5'-S-Methyl-5'-thioadenosine","LPA 16:0","N-Acetyl-DL-norvaline","MGDG 22:0_18:1","FAHFA 10:0/16:0","LPE 22:1","Saccharin","Chenodeoxycholic Acid","LPE 22:2","2-Hydroxy-2-methylbutanedioic acid","19-Nortestosterone","Ethyl chrysanthemumate","Hexadecanedioic acid","20-hydroxy Leukotriene B4","NAGly 15:0/17:0","11(Z),14(Z)-Eicosadienoic Acid","SL 17:0;O/15:0","Prostaglandin D3","FAHFA 20:0/22:2","LPE 11:0","Ethyl-β-D-glucuronide","8Z,11Z,14Z-Eicosatrienoic acid","trans-Petroselinic Acid","Uridine","2-Phenylglycine","Ornithine","Asaraldehyde","DL-β-Leucine","Sulfaquinoxaline","Homogentisic Acid","Prostaglandin E1 Ethanolamide","LPC 20:3","Malonic acid","LPC 20:4","FAHFA 4:0/18:0","trans-2-Butene-1,4-dicarboxylic Acid","LPS 15:0","4,7-dimethylpyrazolo[5,1-c][1,2,4]triazine-3-carbonitrile","Dulcitol","7-(1-pyrrolidinyl)pyrimido[4,5-d]pyrimidin-4-amine","ethyl 3-cyano-2-hydroxy-6-phenylisonicotinate","LPC 20:1","LPC 20:2","LPA 15:0","1-(3-phenylpropanoyl)-4-piperidinecarboxylic acid","PG 4:0_14:0","Ascorbyl stearate","D-Ribose-1-phosphate","DL-3,4-Dihydroxyphenyl glycol","LPG 4:0","α,α-Trehalose","PG 5:0_16:0","FAHFA 19:0/6:0","1-benzyl-3-(2-methylphenyl)-3,7-dihydro-1H-purine-2,6-dione","NAGly 15:0/16:0","FAHFA 2:0/23:0","Adenosine","Glycoursodeoxycholic acid","3-[2-(1,3,5-trimethyl-1H-pyrazol-4-yl)hydrazono]pentane-2,4-dione","3-methyl-5-oxo-5-(4-toluidino)pentanoic acid","Lysope 18:1","2-Hydroxyestradiol","Uric acid","O1-(4-chlorobenzoyl)-4-nitrobenzene-1-carbohydroximamide","LNAPE 18:2/N-18:2","Linoleic acid","2-Aminopimelic acid","3-Hydroxy-3-methylglutaric acid","23-Norcholic acid","LPE 12:0","Fumaric acid","Acetylcarnitine","Argininosuccinic acid","1,5-Anhydro-D-glucitol","3-Hydroxybutyric acid","2-Isopropylmalate","Phenylpyruvic acid","Benzoic acid","nor-6β-Oxycodol","8-iso-15-keto Prostaglandin F2α","4-Hydroxyretinoic Acid","Ascorbic acid","N-Oleoyl Dopamine","2-Hydroxy-2-methyl-3-buten-1-yl beta-D-glucopyranoside","Ala-Leu","Methylsuccinic acid","3-methyl-4-[2-(2-methylphenyl)hydrazono]-4,5-dihydro-1H-pyrazol-5-one","Traumatic acid","Tetradecanedioic acid","Docosahexaenoic acid","Oleanolic acid","LPE 20:1","LPE 20:2","LPG O-18:2","LPE O-18:0","LPE 20:3","LPG O-18:1","LPE O-18:1","LPE 20:4","LPE O-18:2","FAHFA 12:0/14:0","LPC 18:2","LPC 18:3","4-(acetylamino)phenyl 3-chlorobenzoate","9-[(2-hydroxyethoxy)methyl]-1,9-dihydro-6H-purin-6-one","LPI 16:0","Folinic acid","12-oxo Phytodienoic Acid","Cer 18:0;3O/16:0;(2OH)","LPC 18:0","2-Isopropylmalic acid","LPC 18:1","Gibberellin A4","Methyl-beta-galactopyranoside","19(R)-Hydroxy prostaglandin F1α","LPA 18:2","5-Dehydroquinic acid","11-dehydro Thromboxane B2","Metanephrine","DL-Tryptophan","Suberic acid","Phenobarbital-d5","Butylparaben","N-Acetyl-L-glutamine","LPC 19:1","PG 4:0_16:0","N-Acetylphenylalanine","PG 4:0_16:1","4-Methoxycinnamic Acid","Taurolithocholic acid","11(E)-Eicosenoic Acid","Xanthosine","Pyridoxine","D-Threose","(±)-Abscisic acid","Citric acid","LPE 10:0","Glycolithocholic acid","Cer 17:0;2O/2:0","LPG 20:3","2-Thiocytidine","13Z,16Z-Docosadienoic Acid","3-(2-thienylmethyl)-2-thioxotetrahydro-4H-imidazol-4-one","15-Deoxy-Δ12,14-prostaglandin D2","Cer 18:0;2O/15:0;(3OH)","Glycocholic acid","(±)8(9)-DiHET","LPE O-16:1","FAHFA 12:0/16:0","4-phenylbenzo[4,5]imidazo[1,2-a]pyrimidin-2-amine","2'-Deoxyuridine","DGMG (18:2)","Levodopa","Stachyose","5-Aminopentanoate","LNAPE 18:2/N-2:0","Chenodeoxycholic acid-3-beta-D-glucuronide","Jasmonic acid","Tretinoin","ST 24:1;O4;T/18:1","N-Acetyl-DL-glutamic acid","2-Hydroxycaproic acid","N-(2,6-Dimethylphenyl)-N-(methoxyacetyl) alanine","Milbemectin A4","Cer 17:0;2O/17:0;(3OH)","1-Palmitoyl-Sn-Glycero-3-Phosphocholine","Milbemectin A3","Benzyl cinnamate","MGDG O-20:0_18:2","Cytidine","Hydroquinone","Bisphenol A","5(S)-HpEPE","15(R),19(R)-Hydroxy prostaglandin F1α","Taurochenodeoxycholic acid","Guanosine-3',5'-cyclic monophosphate","23-Nordeoxycholic acid","Genistein","Monobenzyl phthalate","Acetildenafil","LPE O-15:1","10-Hydroxydecanoic acid","Lactobionic acid","FAHFA 11:0/13:0","PG 4:0_18:2","PG 4:0_18:1","Taurolithocholic acid 3-sulfate","LPG 11:0","LPE O-15:0","LPI 13:0","4-Hydroxy-3- methoxyphenylglycol sulfate","Cer 18:1;3O/15:0","Glycochenodeoxycholic acid","Stearic Acid","Stercobilin","1-(2,4-dihydroxyphenyl)-2-(3,5-dimethoxyphenyl)propan-1-one","D-Ribose","Ethyl myristate","dUMP","Cer 18:0;2O/17:0;(3OH)","Taurine","Docosanoic Acid","Gamma-Glu-Leu","Naringenin","12-epi Leukotriene B4","Allantoin","Hydrocinnamic acid","Arachidic acid","7-Hydroxy-3,4-dihydrocarbostyril","DL-4-Hydroxyphenyllactic acid","PG O-21:1_18:2","LPG 9:0","N1-[4-(cyanomethyl)phenyl]-4-chlorobenzamide","FAHFA 16:0/18:2","Dihydrofolic acid","N-Acetylsphingosine","8(S),15(S)-DiHETE","(±)9(10)-DiHOME","17α-Hydroxypregnenolone","Kynurenic acid","2-[(3S)-1-(Cyclohexylmethyl)-3-pyrrolidinyl]-5-fluoro-1H-benzimidazole","LPG O-14:1","alpha-Ketoglutaric acid","LPG O-14:0","DL-Malic acid","ST 24:2;O4","N-Acetyl-Asp-Glu","Taurochenodeoxycholic Acid (sodium salt)","2'-Deoxyinosine","Methionine","5-Hydroxyindole-3-acetic acid","Muramic acid","Porphobilinogen","Tyrosol","4-Oxoproline","L-Arabinitol","PG O-20:0_18:1","Cer 19:0;2O/18:0;(3OH)","Docosatrienoic Acid","D-α-Hydroxyglutaric acid","1-Methylguanosine","Lysops 22:5","(±)12(13)-DiHOME","Undecanoic acid","AICA ribonucleotide","4-(4-cyclohexylphenyl)-4-oxobut-2-enoic acid","Calcitriol","6-bromo-3-(2-phenylethanhydrazonoyl)-2H-chromen-2-one","L-Glutathione oxidized","Octanedioic acid","Gentisic acid","6-Deoxy-D-glucose","PG 3:0_16:1","LPG 13:0","PG 3:0_16:0","LPG 13:1","PG 2:0_14:0","3-Methyladipic acid","Lithocholic Acid","Geranylgeranyl pyrophosphate","Benzyl 6-O-beta-D-glucopyranosyl-beta-D-glucopyranoside","Pentadecanoic acid","LPG O-15:1","LPG O-15:0","N'-(4-methoxybenzoyl)-2-[(1-naphthylmethyl)thio]acetohydrazide","LPC 15:0","FAHFA 18:0/20:2","4,6-dimethyl-2-(methylamino)-5-nitronicotinonitrile","Thymidine 5'-monophosphate","dCMP","Glucose-6-phosphate","Pyrogallol","LPS 20:2","β-Estradiol-17β-glucuronide","O-Desmethylnaproxen","Lauric Acid","Kinetin 9-riboside","LysoPE 18:0","Eicosapentaenoic acid","Lysopc 17:0","(±)9-HpODE","α-Aspartylphenylalanine","Glucuronic acid-3,6-lactone","2-Hydroxyphenylalanine","IDP","PG 2:0_15:0","LPG 14:0","Cer 18:0;3O/14:0","LPG O-16:0","delta9-THC-d9","β-Estradiol","LPC 16:0","Glycerol 1-hexadecanoate","LPI 18:3","Glucosamine 6-sulfate","LPI 18:2","LPI 18:1","Lauric acid ethyl ester","N-acetyl-D-glucosamine","methyl 2-[(2-acetyl-3-oxo-1-butenyl)amino]acetate","17-AAG","Hypoxanthine","LPE 19:1","Prostaglandin A1 ethyl ester","4-(2-((4-Methoxyphenyl)amino)oxazol-5-yl)benzonitrile","Adipic acid","Gluconolactone","Isorhapontigenin","Adrenic acid","2-Phenylpropionic acid","Lysopc 14:0","4-[2-(2-oxo-1-imidazolidinyl)ethyl]-1lambda~6~,4-thiazinane-1,1-dione","3-Hydroxypicolinic acid","LPG O-17:2","Fenbendazole sulfoxide","N-[4-(2,6-dimethylmorpholino)phenyl]-N'-(2-thienylmethyl)thiourea","LPG O-17:1","LPG 15:1","FAHFA 18:2/18:1","L-(-)-Glyceric acid","PG 2:0_16:0","LPG 15:0","2-Hydroxybutyric acid","N1-(3-chlorobenzyl)-N2-(5-methylisoxazol-3-yl)ethanediamide","FAHFA 18:1/20:3","LPG O-17:0","PG 3:0_18:2","PG 3:0_18:1","PG 3:0_18:0","4-Hydroxytamoxifen","2-[({4-[3,5-di(tert-butyl)-1H-pyrazol-1-yl]phenyl}imino)methyl]phenol","5-Hydroxyindole-2-carboxylic acid","LPC 17:1","LPC 17:2","ADGGA 12:0_12:0_18:2","LPC 17:0","4,5-diphenyl-2,3-dihydro-1H-pyrazolo[3,4-c]pyridazin-3-one","Gly-Phe","Verbascose","3-Nitro-L-Tyrosine","11(Z)-Eicosenoic acid","Cer 18:0;2O/14:0;(3OH)","Dl-3-Hydroxynorvaline","N-Acetyl-D-galactosamine 4-sulfate","4-(2-((4-Cyanophenyl)amino)oxazol-5-yl)benzonitrile","Uridine monophosphate (UMP)","ST 27:1;O;S","Corchorifatty acid F","Oxoadipic Acid","16-(Hexopyranosyloxy)-7-hydroxy-8,9-epoxypimaran-18-oic acid","Cholic acid","Arachidonic acid","isoleucine","2'-Deoxyinosine 5'-monophosphate","19(R)-Hydroxy-prostaglandin E2","2,3-dinor Prostaglandin E1","3-(3-Hydroxyphenyl)propionic acid","3,4,5-trihydroxycyclohex-1-ene-1-carboxylic acid","D-(+)-Mannose","16-Hydroxyhexadecanoic acid","LPG 16:1","LPG 16:0","LPG 16:2","3,5-Dihydroxybenzoic acid","Phenylpropiolic acid","10-Formylpteroic acid","Delta-Tridecalactone","13-Hpotre(R)","Esculin","Nervonic acid","Sphingosine (d18:1)","4-Hydroxybenzoic acid","MGMG (18:2)","Soyasaponin I","Nonanoic acid","12-Hydroxydodecanoic acid","SL 17:0;O/17:0;O","Valproic acid","Cmp_257","Abametapir","Sebacic acid","3-Methoxyphenylacetic acid","Asp-Phe methyl ester","LPE 17:1","Nicotinamide","Formononetin","3',5,7-Trihydroxy-4'-methoxyflavanone","3-Methyl-2-oxobutanoic acid","N-Glycolylneuraminic acid","3-Indoxyl sulphate","15(R)-Prostaglandin D2","4-Methyl-2-Oxopentanoic Acid","2-Hydroxyvaleric acid","Royal jelly acid","FAHFA 2:0/18:1","FAHFA 2:0/18:0","13,14-dihydro-15-keto-tetranor Prostaglandin F1β","Oxytetracycline","PG 5:0_14:0","D-Glucarate","Glycerol-3-phosphate","LPG 17:0","MGDG 16:0_18:3","LPG 17:2","2-{2-oxo-2-[(2-oxo-3-azepanyl)amino]ethoxy}acetic acid","LPG 17:1","N'-(4-chlorophenyl)-4-ethylbenzohydrazide","PG 2:0_18:1","(±)13-HODE","(+/-)9,10-dihydroxy-12Z-octadecenoic acid","2-(trifluoromethyl)-10H-phenothiazine","15(R)-Prostaglandin E2","Ascorbyl palmitate","Dodecanedioic acid","N-METHYL (-)EPHEDRINE","LPE 9:0","β-Muricholic acid","Propylparaben","Sorbitan monooleate","Quinic acid","ST 24:1;O4;T","beta-Estradiol 17-Acetate","LPE 18:0","LPE 18:1","19(R)-hydroxy Prostaglandin A2","LPE 18:2","LPE 18:3","Adenosine 5'-monophosphate","N-Lauroylsarcosine","L-Hydroxyproline","LPS 18:1","Thymidine","ST 24:1;O4","(±)11(12)-DiHET","3-Hydroxysebacic acid","LPG 18:2","Methylmalonic acid","LPG 18:1","Bicyclo Prostaglandin E2","LPG 18:0","LPS 18:2","N-Tigloylglycine","Nicotinamide N-oxide","13,14-dihydro-15-keto-tetranor Prostaglandin D2","(±)14(15)-DiHETE","Inositol","AKB48 N-(4-hydroxypentyl) metabolite","2-Hydroxy-3-methylbutanoic acid","2-Furoic acid","Homo-Gamma-Linolenic Acid (C20:3)","3-Methylindole","Erythronolactone","Undecanedioic acid","11-Deoxy prostaglandin F2β","Tetracycline","MGDG O-11:0_3:0","FAHFA 18:1/19:2","1a,1b-Dihomo prostaglandin F2α","Salvinorin B","Salvinorin A","L-Aspartic acid","Lysopc 18:3","Nonadecanoic acid","LPE 15:0","1a,1b-Dihomo prostaglandin E1","(R)-3-Hydroxy myristic acid","Lipoic acid","15-keto Prostaglandin A1","20-Hydroxy-(5Z,8Z,11Z,14Z)-eicosatetraenoic acid","Methyl alpha-D-glucopyranoside","Thromboxane B3","Orotic Acid","N-[2-(6-amino-9H-purin-9-yl)ethyl]-N-(2-furylmethyl)amine","Elaidic acid","Estra-1(10),2,4,16-tetraen-3-ol","3-Oxo-7alpha,12alpha-hydroxy-5beta-cholanoic acid","LPG 19:1","Cynaropicrin","Azelaic acid","2-(Dimethylamino)Guanosine","Δ17-6-keto prostaglandin F1α","1,3-Dimethyluracil","Palmitic Acid","PG O-21:1_20:4","Perillic acid","(±)11-HETE","2-Hydroxymyristic acid","Dimetghyl 4-Hydroxyisophthalate","Imidazoleacetic acid","2-Hydroxy-4-methylthiobutanoic acid","PC 18:2_18:2","Guanosine monophosphate (GMP)","3-(3-bromo-4-hydroxy-5-methoxyphenyl)-2-cyanoacrylamide","1-(1,8-dihydroxy-3,6-dimethyl-2-naphthyl)ethan-1-one","Deoxycholic acid","5-Methyl-dl-tryptophan","MGDG O-11:0_4:0","JWH 250 N-pentanoic acid metabolite","lithocholic acid 3-sulfate","Glycodeoxycholic acid","o-Veratraldehyde","Estrone","(±)9(10)-EpOME","Biopterin","δ-Gluconic acid δ-lactone","15-Deoxy-δ12,14 -Prostaglandin J2","Mestranol","13,14-Dihydro-15-keto Prostaglandin E2","LPE 16:1","13,14-Dihydro-15-keto Prostaglandin E1"],"additional_accession":[]},"is_claimable":false,"name":"Rectal-content metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving","description":"This study contains untargeted LC-MS/MS metabolomic profiles of rectal-content samples collected on the day of calving from Holstein dairy cows in the control and high-dose chromium propionate supplementation groups. Cows received either a basal total mixed ration without supplemental chromium propionate or the same ration supplemented with 20 g chromium propionate per cow per day, providing 8 mg Cr(III) per cow per day, from 21 days before expected calving until parturition. Rectal-content samples were collected aseptically at calving and analyzed to characterize hindgut metabolic responses associated with prepartum chromium propionate supplementation during the periparturient 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