{"database":"MetaboLights","file_versions":[{"headers":{"Content-Type":["application/json"]},"body":{"files":{"Tabular":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/m_MTBLS15553_LC-MS_positive_reverse-phase_v2_maf.tsv","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/m_MTBLS15553_LC-MS_negative_reverse-phase_v2_maf.tsv"],"Txt":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/a_MTBLS15553_LC-MS_positive_reverse-phase.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/a_MTBLS15553_LC-MS_negative_reverse-phase.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/s_MTBLS15553.txt","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/i_Investigation.txt"],"Raw":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con1-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH5-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con3-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH3-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH1-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con5-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con6-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con5-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC1-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con6-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/Con2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC1-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH4-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH6-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH5-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC3-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC2-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC4-neg.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/CrH6-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC2-pos.raw","ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553/FILES/RAW_FILES/QC3-neg.raw"]},"type":"primary"},"statusCodeValue":200,"statusCode":"OK"}],"scores":null,"additional":{"ftp_download_link":["ftp://ftp.ebi.ac.uk/pub/databases/metabolights/studies/public/MTBLS15553"],"metabolite_identification_protocol":["Metabolites were annotated by matching accurate mass, retention time, and MS/MS fragmentation information against mzCloud, mzVault, and MassList databases. Positive and negative ion mode datasets were processed separately."],"repository":["MetaboLights"],"study_status":["Public"],"ptm_modification":[""],"instrument_platform":["Liquid Chromatography MS - negative - reverse-phase","Liquid Chromatography MS - positive - reverse-phase"],"chromatography_protocol":["Chromatographic separation was performed using a Vanquish UHPLC system equipped with a Hypersil GOLD C18 column (100 x 2.1 mm, 1.9 um; Thermo Fisher Scientific). The column temperature was maintained at 40 degrees C and the flow rate was 0.2 mL/min. For positive ion mode, mobile phase A was 0.1% formic acid in water and mobile phase B was methanol. For negative ion mode, mobile phase A was 5 mmol/L ammonium acetate in water adjusted to pH 9.0 and mobile phase B was methanol."],"publication":["Rumen-fluid metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving."],"submitter_affiliation":["North West Agriculture and Forestry University"],"submitter_name":["yuzhen Sui"],"organism_part":["rumen fluid"],"technology_type":["mass spectrometry assay"],"disease":[""],"extraction_protocol":["Approximately 100 mg of thawed and well-mixed rumen-fluid sample was extracted with 500 uL of pre-chilled 80% methanol. Samples were homogenized on ice, vortexed thoroughly, incubated on ice for 5 min, and centrifuged at 15,000 x g for 20 min at 4 degrees C. The supernatant was diluted with LC-MS-grade water to a final methanol concentration of 53%, centrifuged again under the same conditions, and used for LC-MS/MS analysis. Quality control samples were prepared by pooling equal aliquots of all sample extracts."],"organism":["Bos taurus"],"full_dataset_link":["https://www.ebi.ac.uk/metabolights/MTBLS15553"],"author":["yuzhen Sui. North West Agriculture and Forestry University. sui1632020@163.com."],"data_transformation_protocol":["Raw LC-MS/MS data were processed using Compound Discoverer software version 3.3. Data processing included retention time correction, peak detection, peak alignment, peak area integration, and relative quantification. Peak intensities were normalized using the total peak area method. Metabolic features with a coefficient of variation greater than 30% in quality control samples were excluded from downstream analysis."],"study_factor":["Treatment"],"submitter_email":["sui1632020@163.com"],"sample_collection_protocol":["Rumen-fluid samples were collected from Holstein dairy cows on the day of calving using an oral stomach tube. The initial portion of rumen fluid was discarded to minimize saliva contamination, and representative rumen-fluid samples were transferred into sterile tubes. Samples were immediately frozen in liquid nitrogen and stored at -80 degrees C until untargeted LC-MS/MS metabolomic analysis. The analyzed samples were obtained from cows in the control and high-dose chromium propionate supplementation groups."],"omics_type":["Metabolomics"],"study_design":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","Metabolomics","LC-MS/MS","untargeted metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","rumen fluid","Bos taurus","pooled sample"],"curator_keywords":["Orbitrap Exploris 120 mass spectrometer, Thermo Fisher Scientific","Metabolomics","LC-MS/MS","untargeted metabolomics","untargeted analysis","Vanquish UHPLC system, Thermo Fisher Scientific","rumen fluid","Bos taurus","pooled sample"],"mass_spectrometry_protocol":["Mass spectrometric detection was performed using an Orbitrap Exploris 120 high-resolution mass spectrometer equipped with an electrospray ionization source. Samples were analyzed separately in positive and negative ion modes. The spray voltage was set to 3.5 kV, and full-scan MS data were acquired over an m/z range of 100-1,500. MS/MS spectra were acquired in data-dependent acquisition mode for metabolite structural annotation."],"metabolite_name":["Corticosterone","6-methyl-2-(4-methylphenyl)pyrimidin-4-yl 4-methylbenzene-1-sulfonate","2,4-dichlorobenzaldehyde 1-methyl-1-(6-methylpyridazin-3-yl)hydrazone","DL-Panthenol","Monolaurin","2-(benzylamino)-6-methyl-5-(2-methyl-1,3-thiazol-4-yl)nicotinonitrile","13(S)-HOTrE","N-Acetyldopamine","U-47700-d6","Imidazolelactic acid","WLH","Lysopa 16:0","2-[(3S)-1-(2-Thienylmethyl)-3-pyrrolidinyl]-1,3-benzoxazole","8-Aminooctanoic acid","Methyl nicotinate","WLK","1-(3,4-dimethoxyphenyl)ethan-1-one oxime","Isobutyryl carnitine","LPC 16:0-SN1","2-Arachidonoyl glycerol","1-[(3,5-dimethylisoxazol-4-yl)sulfonyl]piperidine","4-[4-(1-phenyl-1H-1,2,4-triazol-5-yl)-1,3-thiazol-2-yl]pyridine","3-(cyclopropylmethyl)-2-mercaptoquinazolin-4(3H)-one","L-Tyrosinemethylester","Monensin","D-Sphingosine","Apocynin","2,3-Dinor-TXB2","4-methylphenyl 1-ethyl-3-methyl-1H-pyrazole-5-carbothioate","Alloxan","N-[1-(4-methoxy-2-oxo-2H-pyran-6-yl)-2-methylbutyl]acetamide","Methyl indole-3-acetate","6-Methoxy-2-naphthoic acid","N-Methylisoleucine","Neopterin","5-(benzyloxy)-2-(hydroxymethyl)-1,4-dihydropyridin-4-one","4-Hydroxybenzaldehyde","HPK","7-(2-aminophenyl)heptanoic acid","L-lysine","Pilocarpine","N6-Me-dA","Jasmone","20-Carboxy-Leukotriene B4","N6-Acetyl-L-lysine","2'-O-Methylguanosine","3-(propan-2-yl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione","2-hydroxy-6-[(8Z,11Z)-pentadeca-8,11,14-trien-1-yl]benzoic acid","Glutathione","2-oxa-4-azatetracyclo[6.3.1.1~6,10~.0~1,5~]tridecan-3-one","FMH","6-Methylquinoline","D-(+)-Maltose","(+/-)12(13)-DiHOME","Maltopentaose","Fexofenadine","6,8-dihydroxy-3-(10-hydroxyundecyl)-3,4-dihydro-1H-2-benzopyran-1-one","1-(4-hydroxyphenyl)propane-1,2-diol","Loxoprofen","PI-Cer 36:3;3O","Isophorone","4-Methyl-5-thiazoleethanol","Oleamide","N6-Methyladenine","1,4-Dihydro-1-Methyl-4-Oxo-3-Pyridinecarboxamide","Lidocaine N-oxide","Pantothenic acid","10-Undecenoic acid","Vindoline","PE 14:0_14:0","PE 14:0_14:1","4-(cyclohexylmethyl)-6-(2-thienyl)-2,3-dihydropyridazin-3-one hydrate","Viramune","3-hydroxy-2-octylpentanedioic acid","Xanthurenic acid","Irganox 259","L-Ornithine","D-Glucosamine 6-phosphate","5,6-dimethyl-4-oxo-4H-pyran-2-carboxylic acid","5-chloro-6-(trifluoromethyl)-1,3-dihydro-2H-benzimidazole-2-thione","N-Formylkynurenine","2-[1-(5-chlorobenzo[b]furan-2-yl)ethylidene]hydrazine-1-carbothioamide","Oxaceprol","DKK","(2S)-2-(2-hydroxypropan-2-yl)-2H,3H,7H-furo[3,2-g]chromen-7-one","4-oxododecanedioic acid","2-{[4-(tert-butyl)-4H-1,2,4-triazol-3-yl]thio}-3-nitropyridine","3-(3,4,5-trimethoxyphenyl)propanoic acid","4-Methoxybenzaldehyde","1-Phenyl-3-methyl-5-pyrazolone","(12Z)-9,10,11-trihydroxyoctadec-12-enoic acid","UMP","3-hydroxy-3-(2-pyridylmethyl)indolin-2-one","Retrorsine","2-Phenylglycine","1-allyl-9,9,9a-trimethyl-9,9a-dihydro-1H-imidazo[1,2-a]indol-2(3H)-one","16,16-Dimethyl prostaglandin A1","3-(2-Naphthyl)-D-Alanine","DLK","Homogentisic Acid","PE 15:0_15:0","Indole","N-(5-Aminopentyl)acetamide","Norsufentanil","DL-Arginine","10-Nitrolinoleate","4-(2,3-dihydro-1,4-benzodioxin-6-yl)butanoic acid","L-Carnitine","FQH","o-Cresol","Adenosine","18-β-Glycyrrhetinic acid","Gly-Tyr-Ala","Pyridoxine O-Glucoside","1-Methyl-2-[(3S)-1-(2-methylbenzyl)-3-pyrrolidinyl]-1H-benzimidazole","1,3,5-Trimethylpyrazole","2-Hydroxycinnamic acid","DL-Norvaline","4-morpholinobenzoic acid","Ala-trp","2-(14,15-Epoxyeicosatrienoyl) glycerol","D-Erythrose 4-phosphate","2-[5-(2-hydroxypropyl)oxolan-2-yl]propanoic acid","Citral","4-Hydroxyretinoic Acid","L-Phenylalanine","PE 16:0_16:0","5-Methylcytosine","PE 16:0_16:1","Ala-Leu","Propionyl-L-carnitine","Isoproterenol","Oleanolic acid","Ecgonine","(+)-Evodiamine","PC 16:0_17:2","Thromoboxane B1","gamma-Glutamylleucine","gamma-Glutamylmethionine","PI-Cer 37:3;3O","Methyl EudesMate","2-ethyl-2-(3-methoxyphenyl)cyclohexanone oxime","7-Aminoclonazepam-d4","1,1-Dimethyl-2-oxopropyl N-[2-(2-pyridyl)ethyl]carbamate","4-[(4-phenethyl-1,4-diazepan-1-yl)sulfonyl]-2,1,3-benzoxadiazole","11-dehydro Thromboxane B2","5-acetyl-2,6-dimethyl-1,2,3,4-tetrahydropyridin-4-one","3-(2-naphthyl)-5-(trifluoromethyl)-1H-pyrazole","DPK","DL-Tryptophan","cis-7-Hexadecenoic Acid","Debromohymenialdisine","MGDG O-8:0_22:4","Guanine","2-Naphthol","NAOrn 14:0/16:0","L-Threonic acid-1,4-lactone","DGDG O-8:0_2:0","Epinastine","4-Methoxycinnamic Acid","3-benzyl-4-hydroxy-5-(4-hydroxyphenyl)-2,5-dihydrofuran-2-one","ethyl 3-oxo-3-(1H-pyrazol-5-ylamino)propanoate","Lysopg 18:1","1,4-dihydroxyheptadec-16-en-2-yl acetate","7-Methylguanine","6-Pentyl-2H-pyran-2-one","6-(3-hydroxybutan-2-yl)-5-(hydroxymethyl)-4-methoxy-2H-pyran-2-one","1-Methyladenine","Levalbuterol","(3beta,9xi)-3-(beta-D-Glucopyranosyloxy)-14-hydroxycard-20(22)-enolide","3-(4-hydroxy-3-methoxyphenyl)propanoic acid","9-Aminoacridine","Prostaglandin K2","1-(7-methoxy-2-oxo-2H-chromen-8-yl)-3-methyl-2-oxobutyl acetate","Adenosine 3'5'-cyclic monophosphate","Pipecolic acid","SPK","Indole-3-acrylic acid","4-(4-methoxyphenyl)-2-(2-thienyl)pyrimidine","Methyl cinnamate","5,5-dimethyl-3-morpholinocyclohex-2-en-1-one","15-epi Prostaglandin A1","2-morpholinophenyl 2-thiophenecarboxylate","Adrenosterone","4-(3,4-dihydro-2H-1,5-benzodioxepin-7-ylamino)-4-oxobutanoic acid","1-Palmitoyl-Sn-Glycero-3-Phosphocholine","SQH","Asp-Phe","Bisphenol M","2-methyl-2,3,4,5-tetrahydro-1,5-benzoxazepin-4-one","Hydroquinone","(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-(2-phenylethoxy)oxane-3,4,5-triol","1-adamantyl(1,4-thiazinan-4-yl)methanone","5(S)-HpEPE","2-{[(4,5-dimethoxy-2-nitrophenethyl)imino]methyl}phenol","N-P-Coumaroyl Spermidine","Monobutyl phthalate","L-Glutamate","2'-Deoxyadenosine-5'-monophosphate","Ecgonine methyl ester","Guanosine-3',5'-cyclic monophosphate","N3,N4-Dimethyl-L-arginine","PE 17:0_17:1","J147","1H-indene-3-carboxamide","1,4-dihydroxy-1,4-dimethyl-7-(propan-2-ylidene)-decahydroazulen-6-one","QNK","LPC 22:6-SN1","L-Adrenaline","N-(2-morpholinophenyl)-2-furamide","cis-Aconitic acid","3-[4-methyl-1-(2-methylpropanoyl)-3-oxocyclohexyl]butanoic acid","3-(dimethylamino)-1-[4-(phenylsulfonyl)phenyl]prop-2-en-1-one","Thymine","16α-Hydroxydehydroepiandrosterone","Physostigmine","4-styrylpyridine","1-Methyladenosine","(4E)-1,7-bis(3,4-dihydroxyphenyl)hept-4-en-3-one","4-Hydroxyisoleucine","Maltol","Sinomenine","3,4,10,11-tetramethoxy-7,8,12b,13-tetrahydro-5H-6-azatetraphene","3-(2-methylpropyl)-octahydropyrrolo[1,2-a]pyrazine-1,4-dione","ethyl 1-(3-nitro-2-thienyl)piperidine-4-carboxylate","Coenzyme Q2","Gamma-Glu-Leu","4-[4-(aminocarbonyl)piperidino]-4-oxobut-2-enoic acid","3-Hydroxy-3-methylbutanoic acid","N-Acetylsphingosine","o-Toluic Acid","L-Threonine","PC 17:0_17:1","Testosterone undecanoate","Nervonic ceramide","Andrographolide","3-(5-phenyl-1,3-oxazol-2-yl)-4-(trifluoromethyl)pyridine","LSD-d3","alpha-Ketoglutaric acid","5-phenyl-2,3-dihydro-1H-1,4-benzodiazepin-2-one","Trigonelline","5,8-dihydroxy-10-methyl-5,8,9,10-tetrahydro-2H-oxecin-2-one","5-Hydroxyindole-3-acetic acid","(1E)-5-hydroxy-1,7-diphenylhept-1-en-3-one","N6-Succinyl Adenosine","diethyl 2-[(4-benzhydrylpiperidino)methylidene]malonate","L-5-Hydroxytryptophan","3-Methoxyflavone","R-1 Methanandamide phosphate","6β-Oxycodol N-oxide","Cryptotanshinone","Stearoyl Ethanolamide","2,3-dihydroxypropyl 12-methyltridecanoate","1-(3-ethyl-2,4-dihydroxy-6-methoxyphenyl)butan-1-one","DGDG O-8:0_22:1","Cystine","Ip7G","Octopamine","6-methoxy-4-(trifluoromethyl)nicotinamide","N-(2-hydroxyphenyl)acetamide","2-(3,4-dihydroxyphenyl)acetamide","Dopamine","Thymidine 3,5-cyclic monophosphate","N-Methyldioctylamine","3-Hydroxylidocaine","2-Methylpentanedioic acid","Psoralidin","Dibutyl sebacate","ethyl 3-amino-4-(methylamino)benzoate","6-methyl-4-(morpholinomethyl)-2H-chromen-2-one","Uracil","Eicosapentaenoic acid","2-{2-[(1-methyl-1H-pyrazol-5-yl)amino]-2-oxoethoxy}acetic acid","Tryptamine","Cuminaldehyde","(2,6-dimethylmorpholino)(1-methyl-5-nitro-1H-pyrazol-4-yl)methanone","L-Kynurenine","Creatine","N-Acetylcytidine","3-ethoxy-5-(trifluoromethyl)pyridine-2-carboximidamide","4-oxo-5-phenylpentanoic acid","Octopine","16-Heptadecyne-1,2,4-triol","Cytosine","2-{[methyl(2,3,4,5,6-pentahydroxyhexyl)amino]methylidene}malononitrile","3-Succinoylpyridine","Cer 18:1;3O/24:0;(2OH)","Prostaglandin E2-1-glyceryl ester","N-acetyl-L-ornithine","methyl 2-[(2-acetyl-3-oxo-1-butenyl)amino]acetate","4-methyl-6-phenyl-5,6-dihydro-2H-pyran-2-one","N1-piperidinocarbonyl-4-methylbenzene-1-sulfonamide","ethyl 4-(6-bromo-2-methyl-4-oxo-3,4-dihydroquinazolin-3-yl)benzoate","3-ethyl-4-hydroxy-1-methyl-1,2-dihydroquinolin-2-one","3-Hydroxypicolinic acid","2,6-Dihydroxypurine","2-cyano-2-(2,3-dihydro-1H-inden-1-yliden)acetamide","Homovanillic acid","Triptolide","Nicotinuric Acid","SL 11:1;O/16:1;O","2-(acetyloxy)-3-amino-1-[1,2-di(acetyloxy)ethyl]-3-oxopropyl acetate","L-Glutamic acid","Catechin","TG 18:2_18:2_18:2","4-fluoro-N-[4-(4-methylpiperazino)phenyl]benzenesulfonamide","KKK","PE 31:1","Ginsenoside Rb1","4-oxo-4-[(1-phenylethyl)amino]but-2-enoic acid","D-(-)-Salicin","cis-Resveratrol","Ergosta-5,7,9(11),22-Tetraen-3-beta-Ol","2-methoxy-5-(1H-1,2,4-triazol-5-yl)-4-(trifluoromethyl)pyridine","α-Linolenoyl ethanolamide","(11E,15Z)-9,10,13-trihydroxyoctadeca-11,15-dienoic acid","TG 18:1_18:2_18:2","L-(+)-Citrulline","Desthiobiotin","1-(4-bromophenyl)-2-phenylethan-1-one","D-Panthenol","L-beta-Imidazolelactic acid","Vitamin A","Histidine","Sodium cholate","Delta-Tridecalactone","Tyramine","CYM-5442","(6E)-7-(2H-1,3-benzodioxol-5-yl)-1-(piperidin-1-yl)hept-6-en-1-one","KMH","Sphingosine (d18:1)","NAOrn 16:0/16:0","Sedanolide","Gly-Val","5,6-dimethoxy-2-(2-methoxyphenyl)-4H-chromen-4-one","(3-Methoxy-4-hydroxyphenyl)ethylene glycol sulfate","N-(9-oxodecyl)acetamide","LPE 17:0","3-(3-Methoxyphenyl)propionic acid","Azetidine-2-carboxylic acid","Cyclohexylsulfamate","Ethylmalonate","PC 34:2","KNK","7-{[(2E)-3,7-dimethylocta-2,6-dien-1-yl]oxy}-2H-chromen-2-one","Thr-Leu","25-hydroxycholecalciferol","Glycerol-3-phosphate","5-[(10Z)-14-(3,5-dihydroxyphenyl)tetradec-10-en-1-yl]benzene-1,3-diol","Choline Glycerophosphate","LPC O-19:0","Luteolin","Cystamine","4-(tert-butyl)phenyl 3,5-dimethylisoxazole-4-carboxylate","All-Trans-13,14-Dihydroretinol","gamma-Glutamylglutamine","5-Aminovaleric acid","Xanthine","Diflorasone","D-Glucosamine","Choline","TG 16:0_16:0_18:2","PE 17:1_17:1","KPH","N-Butylbenzenesulfonamide","N,N-dimethyl-9H-purin-6-amine","(5E)-7-methylidene-10-oxo-4-(propan-2-yl)undec-5-enoic acid","L-Hydroxyproline","Nicotinic acid","ILK","L-Alanyl-L-proline","2-Amino-6-methylmercaptopurine","4-[(4-chlorophenyl)thio]-1-methyl-1H-pyrazolo[3,4-d]pyrimidine","3,4-dihydro-2H,6H-[1,3]thiazino[2,3-b]quinazolin-6-one","3'-O-Methyluridine","SPB 19:0;2O","Carvone","7-Methylxanthine","KQH","IMH","2-hexyl-5-(4-nonylphenyl)pyrimidine","3-Methylindole","Indole-3-pyruvic acid","2-Amino-1,3-octadecanediol","Glycyl-L-leucine","Oxymatrine","ABL 127","2,3-Dinor-11β-prostaglandin F2α","2'-Deoxyadenosine","Lipoic acid","Methyl alpha-D-glucopyranoside","INK","Thromboxane B2","4-oxo-4,5,6,7-tetrahydrobenzo[b]furan-3-carboxylic acid","3-Oxo-7alpha,12alpha-hydroxy-5beta-cholanoic acid","5-Methyl-2'-deoxycytidine","Dihydrothymine","Kanosamine","2'-O-Methylcytidine","H-Gly-Pro-OH","2-(2-hydroxy-3-methylbutanamido)-4-methylpentanoic acid","D-(+)-Proline","5-Methoxyindole-3-Carbaldehyde","3-Acetoxyurs-12-en-23-oic acid","4-(3,4-dimethoxyphenyl)-3-methyl-1H-pyrazol-5-amine","5-Methyl-dl-tryptophan","5-(hydroxymethyl)-4-methoxy-2,5-dihydrofuran-2-one","acetoacetate","o-Veratraldehyde","D-2-Aminoadipic acid","Estrone","Isoeugenyl acetate","5,7-dihydroxy-3-(4-hydroxyphenyl)-4H-chromen-4-one","(+/-)-Equol","1-morpholino-3-(4-nitrophenoxy)propan-2-ol","PE 15:0_16:1","GLK","Riboflavin","1,3-bis(4-methoxybenzyl)-2-phenylhexahydropyrimidine","L-(-)-alpha-Amino-epsilon-Caprolactam","2-Methoxyresorcinol","8-Isoprostaglandin F1α","Eicosapentaenoic acid ethyl ester","Folic acid","CDP","4-(anilinomethylidene)-3-methyl-4,5-dihydroisoxazol-5-one","Lysope 14:0","N-Desmethyltramadol","D-(+)-Camphor","Feruloyl Putrescine","GMK","3-amino-4-(propylamino)cyclobut-3-ene-1,2-dione","(+)-ar-Turmerone","All trans-Retinal","Flunitrazepam-d3","2-ethyl-1H-perimidine","PE O-16:1_18:2","6-methoxy-2,3,4,9-tetrahydro-1H-beta-carbolin-1-one","Ursolic acid","Tributyl citrate","N4-phenethylmorpholine-4-carbothioamide","2-phenyl-4H-furo[2,3-h]chromen-4-one","2-deoxyglucose-6-phosphate","L-Asparagine","Paracetamol","N-{5-[(dimethylamino)sulfonyl]-2-methylphenyl}cyclohexanecarboxamide","VLH","Guanosine monophosphate","VLK","2-[(3S)-1-(2-Chlorobenzyl)-3-pyrrolidinyl]-5-methyl-1,3,4-oxadiazole","Estriol","2'-O-Methyladenosine","2-[(3S)-1-Benzyl-3-pyrrolidinyl]-1,3-benzothiazole","N'-[4-(tert-butyl)phenyl]-N-cyclohexyl-N-methylurea","H-Trp-NH2","Cytidine 5'-monophosphate (hydrate)","5-Hydroxytryptophol","Glycitein","gamma-Nonanolactone","11-Oxoetiocholanolone","Isoferulic acid","N-benzyl-2-(6-methoxy-2-naphthyl)propanamide","O-7460","3-methyl-4-nitrobenzene-1-carbohydrazide","5-amino-2-(dimethylamino)benzoic acid","Octyl hydrogen phthalate","2,4-dihydroxyheptadec-16-en-1-yl acetate","ELK","13,14-dihydro-15-keto Prostaglandin A2","4-Acetamidobutyric Acid","N1-(2-pyridyl)-2-(3,5-difluorophenyl)acetamide","DL-Lysine","Lysope 16:0","1,7-bis(4-hydroxyphenyl)-5-methoxyheptan-3-one","违-L-Glutamyl-L-glutamic acid","7-(3,4-dihydroxyphenyl)-5-hydroxy-1-(4-hydroxyphenyl)heptan-3-one","Triacanthine","3-phenyl-2-(3-pyridyl)-1,3-thiazolan-4-one","Boc-beta-cyano-L-alanine","DG O-22:4_14:0","3,4-dihydroxy-4-(4-methoxyphenyl)-1,2,3,4-tetrahydroquinolin-2-one","LPC 20:4-SN1","Alanyltyrosine","Palmitoyl sphingomyelin","Fenvalerate","Fumonisin B1","Fumonisin B2","TKK","1-Methylguanine","2-hydroxy-3,6-diphenylcyclohexyl acetate","2,4-dichloro-N-{2-[(2-furylmethyl)amino]-1-methyl-2-oxoethyl}benzamide","1-{4-[2-nitro-4-(trifluoromethyl)phenyl]piperazino}ethan-1-one","5-Aminosalicylic Acid","Hydroxyprogesterone caproate","7-(1-pyrrolidinyl)pyrimido[4,5-d]pyrimidin-4-amine","Proline","N1-(5-methylisoxazol-3-yl)-2-morpholinoacetamide","1-(3-phenylpropanoyl)-4-piperidinecarboxylic acid","2-{[5-(trifluoromethyl)-2-pyridyl]thio}acetic acid","(2E)-6-hydroxy-2-methyl-6-(4-methylphenyl)hept-2-enoic acid","1,2-dihydroxyheptadec-16-yn-4-yl acetate","LPC 18:0-SN1","Glycoursodeoxycholic acid","Indole-3-acetic acid","3-methyl-5-oxo-5-(4-toluidino)pentanoic acid","2-(2,6-dimethoxyphenyl)-5,6-dimethoxy-4H-chromen-4-one","2-[(3S)-1-(4-Fluorobenzyl)-3-pyrrolidinyl]-5-methyl-1H-benzimidazole","L-Methionine Methyl Ester","N1-isopropyl-2-(1H-2-pyrrolylcarbonyl)-1-hydrazinecarboxamide","L-Tyrosine","(2R,3S,4S,5R,6R)-2-(hydroxymethyl)-6-(propan-2-yloxy)oxane-3,4,5-triol","Aflatoxin B1","Adipamide","EPH","EPK","3-hydroxy-3-methylpentanedioic acid","4-methoxy-6-(prop-2-en-1-yl)-2H-1,3-benzodioxole","Sitagliptin","5-Phenylvaleric Acid","gamma-Glutamyltyrosine","PC 17:1_17:1","4-hydroxy-3-(3-methylbut-2-en-1-yl)benzoic acid","N-(5-acetamidopentyl)acetamide","2-Arachidonyl Glycerol ether","methyl 3,4,5-trihydroxycyclohex-1-ene-1-carboxylate","Spermidine","EQH","Folinic acid","Aflatoxin M1","4-phenoxyphenyl 4-hydroxypiperidine-1-carboxylate","TG 16:0_18:2_18:2","Avocadyne 1-acetate","Urocanic acid","Albendazole sulfone","N1-(2-piperidinophenyl)-3,4,5-trimethoxybenzamide","Phenyl[(3S)-3-(5-propyl-1,3,4-oxadiazol-2-yl)-1-pyrrolidinyl]methanone","Methylhippuric acid","p-Mentha-1,3,8-triene","Metanephrine","3-amino-2-phenyl-2H-pyrazolo[4,3-c]pyridine-4,6-diol","Obscurolide A1","PE 16:0_17:1","PE 16:0_17:2","Pyridoxal 5'-phosphate","5-(tert-butyl)-2-methyl-N-(4-nitrophenyl)-3-furamide","Piperine","3,5-di(2-furylmethylidene)tetrahydro-2H-pyran-4-one","2-acetamido-3-(4-methoxyphenyl)propanoic acid","Acetophenone","Ritalinic acid","dimethyl 2-(3-nitro-2-pyridyl)malonate","Docosahexaenoic Acid","Creatinine","Acetyl-L-carnitine","Cer 17:0;2O/16:0","Pyridoxine","RMH","3-hydroxy-3,4-bis[(4-hydroxy-3-methoxyphenyl)methyl]oxolan-2-one","RMK","Sulforidazine","trans-3-Indoleacrylic acid","Glycolithocholic acid","2-Amino-1,3,4-octadecanetriol","tetranor-12(R)-HETE","Linoleoyl ethanolamide","Tiglic acid","9-Oxo-10(E),12(E)-octadecadienoic acid","RNH","Betaine","N-Methylhydantoin","AL 8810 Methyl ester","6-Acetylmorphine","4-{3-[(3,4-dihydroxyphenyl)methyl]-2-methylbutyl}benzene-1,2-diol","L-Leucyl-L-Alanine","Enrofloxacin","Cytidine","PC 18:1_18:1","Indole-3-lactic acid","Clinafloxacin","Isoquinoline","2-(4-aminophenoxy)isophthalonitrile","octadec-9-ynoic acid","P-Aminohippuric Acid","ANH","ANK","Prostaglandin F2α-1-glyceryl ester","Dithranol","Cer 18:0;2O/16:0","7-methyl-3-nitroimidazo[1,2-a]pyridine","RPK","PLH","PLK","10-Hydroxydecanoic acid","N-[4-(aminosulfonyl)phenyl]-2-chloro-6-fluorobenzamide","4-Methylvaleric Acid","Deoxycorticosterone 21-glucoside","3-hydroxy-1,5-diphenylpentan-1-one","2-Thio-acetyl MAGE","Cadaverine","1-(3-methoxy-2-nitrostyryl)pyrrolidine","4-acetyl-4-(ethoxycarbonyl)heptanedioic acid","7-Ketolithocholic acid","DL-2-(acetylamino)-3-phenylpropanoic acid","Cer 18:1;3O/23:0;(2OH)","RQH","5'-Deoxy-5'-(Methylthio)Adenosine","Vitamin E Acetate","2-[(3S)-1-Cyclobutyl-3-pyrrolidinyl]-5-fluoro-1H-benzimidazole","6-(4-phenylpiperazino)hexanoic acid hydrochloride","1-(4-methoxyphenyl)propane-1,2-diol","dUMP","APK","3-(3,4-dihydroxyphenyl)propanoic acid","Prolylleucine","Prothionamide","5-(6-hydroxy-6-methyloctyl)-2,5-dihydrofuran-2-one","4-(3-methoxy-5,6-dihydrobenzo[c]acridin-7-yl)morpholine","ethyl 5-methoxy-2-methyl-1-phenyl-1H-indole-3-carboxylate","4-Guanidinobutyric acid","5-Hydroxytryptophan","Kynurenic acid","3-Indoleacrylic acid","Methylmalonate","Methyl 3-indolyacetate","Methionine","NKK","Isopropyl myristate","2'-Deoxycytidine","Styrene","4-oxo-4-(5,6,7,8-tetrahydronaphthalen-1-ylamino)but-2-enoic acid","Carbadox","2,6-Di-tert-butyl-1,4-benzoquinone","PPK","11-Deoxy prostaglandin F1α","5-[(1-benzothiophen-3-ylmethyl)sulfanyl]-1-methyl-4-nitro-1H-imidazole","L-Glutathione oxidized","3-Methoxytyramine","L-Norleucine","1-Stearoylglycerol","NAOrn 15:0/16:0","3-Methylcrotonylglycine","4-Butylresorcinol","Dihydromethysticin","N-allyl-2-(2-methyl-1-benzofuran-3-yl)acetamide","Salsolinol","Nitrofurantoin","Serotonin","Dihydrozeatin","Kojic acid","N-Stearoyl taurine","trans-4-Phenyl-4-piperidinocyclohexanol","DL-m-Tyrosine","Ferulic acid","2-(Formylamino)Benzoic Acid","3-{[(3S)-3-(1,3-Benzothiazol-2-yl)-1-pyrrolidinyl]methyl}benzonitrile","Leucylproline","AKB48 N-(4-fluorobenzyl) analog","ethyl 2,3-dioxo-1,2,3,4-tetrahydroquinoline-4-carboxylate","Kinetin 9-riboside","Gamma-Aminobutyric acid","2-Hydroxyacetophenone","8-Hydroxyquinoline","dUTP","Maltotetraose","NNK","2-(cyclopropylcarbonyl)-3-(methylthio)-3-morpholinoacrylonitrile","Harmine","Phytosphingosine","Arachidonoyl amide","2-Hydroxyphenylalanine","6-amino-1-(2-methylphenyl)-1,2,3,4-tetrahydropyrimidine-2,4-dione","Cortodoxone","2-(3,4-dihydroxyphenyl)-3,5,7-trihydroxy-6-methyl-4H-chromen-4-one","Fisetin","LysoPC 10:0","Homoarginine","Ergocalciferol","Coumarin","7-(2-hydroxypropan-2-yl)-1,4a-dimethyl-decahydronaphthalen-1-ol","Spermine","Stanozolol","Hypoxanthine","1-(2-furyl)pentane-1,4-dione","2'-O-Methyl-5-methylcytidine","Palmitoyl ethanolamide","2-Phenylpropionic acid","Cer 18:0;3O/24:0;(2OH)","D-glutamine","4-[2-(2-oxo-1-imidazolidinyl)ethyl]-1lambda~6~,4-thiazinane-1,1-dione","3-Acetyl-11-keto-β-boswellic acid","N-Acetyl-DL-phenylalanine","15-OxoEDE","N-[2-(1,5-dimethyl-4-nitro-1H-pyrazol-3-yl)vinyl]-N,N-dimethylamine","2-[(3S)-1-(2-Methylbenzyl)-3-pyrrolidinyl]-1,3-benzothiazole","N8-Acetylspermidine","N1-(2,3-dihydro-1,4-benzodioxin-6-yl)acetamide","N6,N6,N6-Trimethyl-L-lysine","4-(3-methoxyphenyl)-4-methyl-2,6-dioxopiperidine-3,5-dicarbonitrile","5-Hydroxyindole","N1,N1-diethyl-4-[2-(4-bromophenyl)diaz-1-enyl]aniline","Palmitoleic Acid","Adenine","(2E)-3-(3,4-dimethoxyphenyl)prop-2-enoic acid","O-Arachidonoyl ethanolamine","D-Ala-D-Ala","Glu-Val-Phe","Gly-Phe","3-(2-chlorophenyl)-3-(2,4-difluoroanilino)acrylonitrile","D-Proline","N1-(1H-indol-4-yl)cyclohexane-1-carboxamide","Inosine","Purine","Dl-3-Hydroxynorvaline","Methylimidazoleacetic acid","LNH","Tetranor-12(S)-HETE","Arachidonic acid","Kuromanin","isoleucine","1,7-bis(4-hydroxyphenyl)heptan-3-one","N-Acetylmethionine","Phenylpropiolic acid","(2R)-2-[(2R,5S)-5-[(2S)-2-hydroxybutyl]oxolan-2-yl]propanoic acid","Caffeine","3,3,5-trimethyl-3H,11H-pyrano[3,2-a]carbazole","2-(cyclopropylcarbonyl)-3-(4-fluoroanilino)acrylonitrile","2-(3,5-dimethyl-1H-pyrazol-4-yl)-5-methoxybenzoic acid","4-methoxy-9-(2-methylbut-3-en-2-yl)-7H-furo[3,2-g]chromen-7-one","4-Hydroxybenzoic acid","5-trans prostaglandin F2β","Maltotriose","Valproic acid","Abametapir","2-piperidinobenzoic acid","4-Phenyl-3-buten-2-one","3-Methoxy prostaglandin F1α","3-methoxy-2-phenyl-4H-furo[2,3-h]chromen-4-one","Methyldopa","N-Acetylhistamine","Nicotinamide","2,4-Dimethylbenzaldehyde","Methyl dihydrojasmonate","3-Methyl-2-oxobutanoic acid","13-HPODE","Maslinic acid","4-Methyl-2-Oxopentanoic Acid","N-[2-(4-methoxyphenoxy)ethyl]-2-furamide","6-Hydroxymelatonin","N-(4-butyl-2-methylphenyl)-N'-[4-(4-methylpiperazino)phenyl]urea","Oleoyl ethanolamide","Apigenin","6,6-dimethyl-4-piperidino-5,6-dihydro-2H-thiine-2-thione","Pyroglutamic acid","4-methyl-5-oxo-2-pentyl-2,5-dihydrofuran-3-carboxylic acid","Pyridoxamine","L-Pyroglutamic acid","Biochanin A","N-METHYL (-)EPHEDRINE","2-phenylthiomorpholin-3-one","N1-(3-pyridyl)-4-[(dipropylamino)sulfonyl]benzamide","3-[(4-hydroxyphenyl)methyl]-octahydropyrrolo[1,2-a]pyrazine-1,4-dione","Acetylcholine","5-OxoETE","Choline bitartrate","2-(3,4-dimethoxyphenyl)ethanamine","LPC 18:2-SN1","Diphenylamine","4-(2-methoxyphenyl)-1-(3-phenyl-1,2,4-thiadiazol-5-yl)piperidine","D-Fructose 6-phosphate","Diosmetin","4-(benzoylamino)-3-hydroxybutanoic acid","8-(1,2-dihydroxy-3-methylbut-3-en-1-yl)-7-methoxy-2H-chromen-2-one","α-Lapachone","Tryptophanol","Nicotinamide N-oxide","N,N-Dimethylarginine","Ne-(1-Carboxymethyl)-L-lysine","[4-(1H-1,2,4-triazol-1-yl)phenyl]methanol","HKK","lipoamide","DL-Stachydrine","Linolelaidic Acid (C18:2N6T)","(+/-)5(6)-EET Ethanolamide","T-2 Triol","3'-Adenosine monophosphate (3'-AMP)","Histamine","4-(methylthio)-6-phenyl-2-(3-pyridyl)pyrimidine-5-carbonitrile","2-(2-amino-3-methylbutanamido)-3-phenylpropanoic acid","cis-gondoic acid","(5-L-Glutamyl)-L-Amino Acid","Phe-Phe","Methionine sulfoxide","N-α-L-Acetyl-arginine","Gly-Tyr","Senecionine","Phosphoethanolamine","p-Hydroxybenzaldehyde","1,3-Dimethyluracil","1-(4-benzylpiperazino)-2-(pyridin-2-ylamino)propan-1-one","16(R)-HETE","Epinephrine","(1R,2R)-trans-N-Boc-1,2-cyclohexanediamine","N-Acetyl-L-leucine","15-Deoxy-δ12,14-prostaglandin J2-2-glycerol ester","PC 18:2_18:2","NAOrn 16:0/17:0","2,5-Furandicarboxylic acid","N1-Acetylspermine","Psoralen","2'-Deoxyguanosine","Deoxycytidine","Valylproline","WKK","PE O-15:1_16:0","N'-{6-[(5-chloro-3-pyridyl)oxy]-3-pyridyl}-N,N-dimethyliminoformamide","Daidzein","LPE 16:0","7α-Hydroxytestosterone"],"additional_accession":[]},"is_claimable":false,"name":"Rumen-fluid metabolomic profiling of periparturient dairy cows supplemented with high-dose chromium propionate before calving","description":"This study contains untargeted LC-MS/MS metabolomic profiles of rumen-fluid samples collected on the day of calving from Holstein dairy cows in the control and high-dose chromium propionate supplementation groups. Cows received either a basal total mixed ration without supplemental chromium propionate or the same ration supplemented with 20 g chromium propionate per cow per day, providing 8 mg Cr(III) per cow per day, from 21 days before expected calving until parturition. Rumen-fluid samples were collected at calving and analyzed to characterize ruminal metabolic responses associated with prepartum chromium propionate supplementation during the periparturient period.","dates":{"publication":"2026-09-26","submission":"2026-09-04"},"accession":"MTBLS15553","cross_references":{"KEGG":["Com_2_neg","Com_37_neg","Com_82_neg","Com_145_neg","Com_181_neg","Com_202_neg","Com_221_neg","Com_235_neg","Com_260_neg","Com_301_neg","Com_327_neg","Com_371_neg","Com_495_neg","Com_506_neg","Com_600_neg","Com_608_neg","Com_666_neg","Com_784_neg","Com_800_neg","Com_876_neg","Com_899_neg","Com_1032_neg","Com_1063_neg","Com_1471_neg","Com_1580_neg","Com_1684_neg","Com_2009_neg","Com_2088_neg","Com_2128_neg","Com_2358_neg","Com_2469_neg","Com_2850_neg","Com_3826_neg","Com_3956_neg","Com_4216_neg","Com_5358_neg","Com_9400_neg","Com_48_neg","Com_10_neg","Com_1532_neg","Com_39_neg","Com_342_neg","Com_331_neg","Com_234_neg","Com_540_neg","Com_184_neg","Com_376_neg","Com_765_neg","Com_868_neg","Com_1291_neg","Com_2679_neg","Com_207_neg","Com_168_neg","Com_9_neg","Com_23_neg","Com_31_neg","Com_47_neg","Com_60_neg","Com_61_neg","Com_66_neg","Com_76_neg","Com_83_neg","Com_94_neg","Com_95_neg","Com_110_neg","Com_118_neg","Com_120_neg","Com_122_neg","Com_141_neg","Com_149_neg","Com_154_neg","Com_157_neg","Com_163_neg","Com_179_neg","Com_187_neg","Com_211_neg","Com_213_neg","Com_222_neg","Com_225_neg","Com_232_neg","Com_243_neg","Com_291_neg","Com_321_neg","Com_344_neg","Com_345_neg","Com_351_neg","Com_361_neg","Com_363_neg","Com_366_neg","Com_391_neg","Com_393_neg","Com_406_neg","Com_439_neg","Com_453_neg","Com_467_neg","Com_473_neg","Com_484_neg","Com_546_neg","Com_572_neg","Com_573_neg","Com_587_neg","Com_622_neg","Com_641_neg","Com_689_neg","Com_716_neg","Com_728_neg","Com_733_neg","Com_746_neg","Com_768_neg","Com_796_neg","Com_844_neg","Com_859_neg","Com_880_neg","Com_933_neg","Com_978_neg","Com_1007_neg","Com_1015_neg","Com_1019_neg","Com_1023_neg","Com_1035_neg","Com_1041_neg","Com_1080_neg","Com_1100_neg","Com_1135_neg","Com_1164_neg","Com_1194_neg","Com_1203_neg","Com_1206_neg","Com_1212_neg","Com_1218_neg","Com_1274_neg","Com_1310_neg","Com_1312_neg","Com_1344_neg","Com_1364_neg","Com_1373_neg","Com_1412_neg","Com_1417_neg","Com_1425_neg","Com_1432_neg","Com_1480_neg","Com_1491_neg","Com_1529_neg","Com_1594_neg","Com_1722_neg","Com_1730_neg","Com_1736_neg","Com_1750_neg","Com_1751_neg","Com_1767_neg","Com_1788_neg","Com_1806_neg","Com_1886_neg","Com_1893_neg","Com_1903_neg","Com_1983_neg","Com_1995_neg","Com_2034_neg","Com_2060_neg","Com_2105_neg","Com_2126_neg","Com_2139_neg","Com_2250_neg","Com_2291_neg","Com_2297_neg","Com_2311_neg","Com_2313_neg","Com_2321_neg","Com_2418_neg","Com_2425_neg","Com_2447_neg","Com_2525_neg","Com_2570_neg","Com_2589_neg","Com_2639_neg","Com_2692_neg","Com_2719_neg","Com_2728_neg","Com_2764_neg","Com_2800_neg","Com_2847_neg","Com_2867_neg","Com_2975_neg","Com_2995_neg","Com_3002_neg","Com_3027_neg","Com_3043_neg","Com_3080_neg","Com_3392_neg","Com_3460_neg","Com_3839_neg","Com_3843_neg","Com_3854_neg","Com_3857_neg","Com_3862_neg","Com_3878_neg","Com_3922_neg","Com_3965_neg","Com_3969_neg","Com_3992_neg","Com_4118_neg","Com_4132_neg","Com_4142_neg","Com_4205_neg","Com_4211_neg","Com_4226_neg","Com_4259_neg","Com_4385_neg","Com_4433_neg","Com_4470_neg","Com_4581_neg","Com_4611_neg","Com_4616_neg","Com_4665_neg","Com_4723_neg","Com_4838_neg","Com_4839_neg","Com_4900_neg","Com_4929_neg","Com_4946_neg","Com_5007_neg","Com_5042_neg","Com_5111_neg","Com_5115_neg","Com_5208_neg","Com_5235_neg","Com_5237_neg","Com_5309_neg","Com_5417_neg","Com_5453_neg","Com_5496_neg","Com_5519_neg","Com_5535_neg","Com_5608_neg","Com_5700_neg","Com_5867_neg","Com_5980_neg","Com_5985_neg","Com_6107_neg","Com_6145_neg","Com_6286_neg","Com_6327_neg","Com_6361_neg","Com_6525_neg","Com_6569_neg","Com_6575_neg","Com_6617_neg","Com_6658_neg","Com_6727_neg","Com_6764_neg","Com_6894_neg","Com_6930_neg","Com_6931_neg","Com_6963_neg","Com_6992_neg","Com_6999_neg","Com_7016_neg","Com_7209_neg","Com_7379_neg","Com_7593_neg","Com_7615_neg","Com_7625_neg","Com_7626_neg","Com_8096_neg","Com_8115_neg","Com_8171_neg","Com_8246_neg","Com_8277_neg","Com_8391_neg","Com_8455_neg","Com_8459_neg","Com_8610_neg","Com_8704_neg","Com_8782_neg","Com_8833_neg","Com_8834_neg","Com_8890_neg","Com_9118_neg","Com_9205_neg","Com_9300_neg","Com_9309_neg","Com_9401_neg","Com_446_neg","Com_457_neg","Com_2364_neg","Com_218_neg","Com_103_neg","Com_627_neg","Com_787_neg","Com_336_neg","Com_86_neg","Com_3753_neg","Com_1476_neg","Com_962_neg","Com_2952_neg","Com_4862_neg","Com_3471_neg","Com_339_neg","Com_5475_neg","Com_678_neg","Com_2123_neg","Com_5180_neg","Com_1067_neg","Com_651_neg","Com_887_neg","Com_1914_neg","Com_4239_neg","Com_774_neg","Com_8300_neg","Com_1185_neg","Com_708_neg","Com_36_neg","Com_387_neg","Com_683_neg","Com_6005_neg","Com_199_neg","Com_1961_neg","Com_124_neg","Com_3591_neg","Com_2077_neg","Com_115_neg","Com_7692_neg","Com_1708_neg","Com_2054_neg","Com_885_neg","Com_5571_neg","Com_1656_neg","Com_721_neg","Com_3929_neg","Com_2818_neg","Com_3_neg","Com_3368_neg","Com_1371_neg","Com_509_neg","Com_8306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