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the project’s in-house metabolite database and comparing it with the mass spectrometry data of reference standards, complete the qualitative annotation of metabolites.</p>MetaboLightsPublicLiquid Chromatography MS - negative - reverse-phaseLiquid Chromatography MS - positive - reverse-phase<p>An ultra-high-performance liquid chromatography (UHPLC) system was used, with a C18 column for component separation; the liquid-phase separation was performed using the appropriate mobile phase system and elution program.</p>Metabolomic analysis of inhibited pollen tube growth in unilateral crosses of Clematis.Zhejiang A&F Universityyichen yangpistilmass spectrometry assay<p>Grind and pulverize the frozen pistil samples, extract metabolites using a methanol-water solution, vortex thoroughly, centrifuge, and then aspirate the supernatant for subsequent instrumental analysis.</p>Clematishttps://www.ebi.ac.uk/metabolights/MTBLS15784Jian Zheng. ZheJiang Academy of Agricultural Sciences. zhengj@zaas.ac.cn.Qingdi Hu.Yaping Hu. ZheJiang Academy of Agricultural Sciences. huyp@zaas.ac.cn.<p>Perform preprocessing operations on raw mass spectrometry data, including peak alignment, peak identification, signal filtering, and data normalization.</p>TimeCultivaryicheny233@163.com<p>Pistil tissue samples from clematis were collected at various time points after pollination. Immediately after removal, the samples were rapidly frozen in liquid nitrogen and stored in a -80°C ultra-low temperature freezer for future use.</p>MetabolomicsThermo Scientific Vanquish UHPLC SystempistilMetabolomicsuntargeted analysisClematispooled sampleThermo Scientific Q-Exactive HF-Xexperimental sampleuntargeted metabolite profilingThermo Scientific Vanquish UHPLC SystempistilMetabolomicsuntargeted analysisClematispooled sampleThermo Scientific Q-Exactive HF-Xexperimental sampleuntargeted metabolite profiling<p>Using a triple quadrupole mass spectrometer, collect mass spectrometry signals of metabolites in both positive and negative ion modes.</p>TricyclohumuladiolXi-10-Hydroxyoctadecanoic acid4-HydroxynonenalPhe-IleAsp-Glu-LeuPopulinIsophthalic Acid2,10-Bisaboladiene-1,4-diol6-Hydroxy-4-methoxy-3-(3-methyl-2-butenyl)-2-(2-phenylethenyl)benzoic acid2-Decyl-3-hydroxypentanedioic acidTilirosideThr-Val-LeuSilydianinPropyl 1-(propylsulfinyl)propyl disulfideButyl dodecanoateKinetinL-Erythrulose1-Hexanol arabinosylglucosideTomelukastBafilomycin jLps(18:2)1-O-Cinnamoyl-beta-D-gentiobiose2-Hydroxy-5-methoxybenzaldehydeAuxin aTetracosanoic acidAuxin b(Z)-2-Methyl-2-butene-1,4-diol 4-O-beta-D-GlucopyranosideCitrusin FAlpha-Bisabolol oxide BAlpha-Bisabolol oxide ACitrusin BAsperuloside(2R,6x)-7-Methyl-3-methylene-1,2,6,7-octanetetrol 2-glucosideMarmesin rutinosideBuddlenol BMyricetin 3-(3'',4''-diacetylrhamnoside)Ent-17-oxo-15-kauren-19-oic acidEpicylindrospermopsin15-Oxo-11Z,13E-eicosadienoic acid3,4-Dicaffeoyl-1,5-quinolactoneN-Acetyl-D-tryptophanAsebotoxinDecursinAlbocycline9-Hydroperoxy-10E,12Z,15Z-octadecatrienoic acidAsn-IleCladospolide BPilocarpine(-)-DeoxypodophyllotoxinKoninginin GPyrroline hydroxycarboxylic acidEremopetasidioneTOFA3',5'-Cyclic GMPHovenolactoneCladospolide DAbscisic alcoholFa(18:2+2o)Asn-Ile-LeuChrysoeriol6-Deoxyerythronolide BGeir-2NepetasidePiperonylic acidLeu-Gly-LeuFahfa(16:0/2:0)Glutarate semialdehydeLysoPE(0:0/18:2(9Z,12Z))Mulberroside F6,9-Octadecadienedioic acid(+/-)-6-Hydroxy-3-oxo-alpha-ionolAucherine4-hydroxy-benzoateProline betaine2-(Formylamino)benzoic acidCinnamic AcidPalmitaldehydegamma-Glu-GlnPantothenic acid8(s)-hetre2-Propylglutaric acid2,5-diamino-6-(5-phospho-D-ribosylamino)pyrimidin-4(3H)-oneVindoline12-Hydroxyheptadeca-5,8,10-trienoic acidDgmg(18:3)Daucic acid16-hydroxy hexadecanoic acidCurcumin diglucosideVal-Asp-SerTrans-Traumatic acidD-(-)-Citramalic acid1-Methyl-3-(1-methylethyl)-1,2-cyclopentanedicarboxylic acidPe(o-16:3/4:0)Phe-Gln-LeuGly-Ile-LeuSuccinyladenosineLpi(18:2)1-palmitoyl lysophosphatidic acidEseramineOleandrose2,3-Butanediol glucosideD-Arabinose 5-phosphateTrp-Gly-LeuPhthalic acidAlpha-guaiaconic acid3-Furoic acidGlyceric AcidN-L-gamma-Glutamyl-L-leucine1-(4,7-dimethylpyrazolo[5,1-c][1,2,4]triazin-3-yl)ethan-1-one3-Dehydroquinic acidOxidized glutathioneLeu-Ala-LeuCabbage identification factor 22'-hydroxypyridoxolLpi(18:3)11R-hydroxy-dodecanoic acidCis-9-Octadecenedioic acidDihydrophaseic acidCryptomeridiolP-mentha-1,3,5-triene-3,9,10-triolSer-Ala-LeuLeucanthosideAngoroside CIsopentyl gentiobiosideCorchoionoside CVal-Asn-LeuGlucosyl (E)-2,6-Dimethyl-2,5-heptadienoate6,7-Dihydroxydihydrolinalool 7-O-beta-glucopyranosideIsocitric acidPhe-Val-LysAsp-Glu15-Hydroxypentadecanoic acidTridecanoic acidAvocadene 2-acetate8,8a-Deoxyoleandolide4'-O-Methylkanzonol WLoliolideVanoxerineCer(18:1_3O/16:0)Adenosine monophosphateGroPInsAla-Ala-Ile4-(beta-D-glucosyloxy)-3-hydroxy-benzoic acid2-Hydroxycinnamic acidLinoleic acid(-)-Pinoresinol 4-O-beta-D-glucopyranosideSalaquinone AGlu-Glu-LeuArg-Asn9-Oxo-10E,12Z,15Z-octadecatrienoic acidAscorbic acidL-PhenylalanineCandesartanLathyrol3-Methyl-1,1-cyclohexanediacetic acid4,7-dioxooctanoic acid(+)-PinoresinolMethylsuccinic acidAla-Leu3,4-Dimethyl-5-pentyl-2-furanundecanoic acidFahfa(16:0/10:0)Traumatic acidTetradecanedioic acidTubaic acidErythritolEnt-7-oxo-8(14),15-pimaradien-19-oic acidVaccenic acidThr-Leu-LeuEcgonineSilux1-O-Galloyl-beta-D-glucoseHexylresorcinolDMH-13-(1-Carboxyvinyloxy)benzoic acidGibberellin A4Terephthalic acidGibberellin A54-Tert-AmylphenolL-IditolZeatinVal-Glu-LeuCrithmumdiol(E)-4-Oxo-2-nonenoic acid(1R,2R,3S,1'R)-Nepetalinic acidCnidioside AVal-Asn-His(gamma-Glutamyl-gamma-glutamyl)-S-methylcysteineUmbelliferone2,3-Dihydroxypropyl dihydrogen phosphateAsn-Thr-IleBenzoic acid+2o,o-hexDelta-ValerolactoneBetanidinbeta-Glutamic AcidAsp-Trp6-O-(6-Deoxy-alpha-L-mannopyranosyl)-beta-D-glucopyranoseNCGC00347612-02_C20H30O4_17-Hydroxy-15,16-epoxykauran-18-oic acid9-arabinofuranosyladenineGlu-Val-Leu(-)-11-hydroxy-9,10-dihydrojasmonic acid 11-beta-D-glucoside12,13-Epoxy-9-hydroxy-10-octadecenoate4-Nitrophenyl butyrateSalicylic acid beta-D-glucosideAlpha-Ketosuberic acid5-Phenyl-1,3-oxazinane-2,4-dioneRhododendrol2-Hydroxyoctanoic acidGlu-ValVanillic acid+o-sulfonatehexBeta-D-Glucopyranosyl-11-hydroxyjasmonic acidUridine 5'-monophosphateCitric acid(4E,7E,10E,13E)-Hexadeca-4,7,10,13-tetraenoic acidXi-2,2,6-Trimethyl-1,4-cyclohexanedione8(R)-Hydroperoxylinoleic acidDG(PGF2alpha/0:0/15:0)Protogenkwanin 4'-glucosideHis-Gly-LysD-(+)-TryptophanD-Linalool 3-(6''-malonylglucoside)Rhodioloside DMG(6 keto-PGF1alpha/0:0/0:0)Maleamic acid(9Z,12Z)-15-Hydroxyoctadeca-9,12-dienoic acid2-(1-Pentenyl)furanDL-3-Phenyllactic acidAziridyl benzoquinonePalatinoseManoyl oxideGalangin3-Oxo-2-(2Z-Pentenyl)cyclopentyl propionic acidPhe-ValErysothiopine(E)-7-[4-Hydroxy-2-[(E)-3-hydroxyoct-1-enyl]-6-oxooxan-3-yl]hept-5-enoic acid3'-Hydroxyacetophenone(22R,23R)-22,23-dihydroxy-campest-4-en-3-oneWoorenoside XIVignatic acid AIle-Val8-Oxohexadecanoic acidEsculetinLeucinic AcidAsp-Phe6-HydroxycoumarinCis-Coutaric acidL-2-Amino-4-methylenepentanedioic acid2-Octoxy-6-[(3,4,5-trihydroxyoxan-2-yl)oxymethyl]oxane-3,4,5-triolPro-Thr(4R,5S,7R,11x)-11,12-Dihydroxy-1(10)-spirovetiven-2-one 12-glucosideDehydroascorbic acidGeranic acidCoriandrone CLumiflavin5(S)-HpEPE7-Hydroxy-4-methyl-2H-chromen-2-oneBenzofuranDehydrodiferulic dilactone7,8,17-trihydroxy-4,9,11,13,15,19-docosahexaenoic acidMonobutyl phthalateCis-p-Coumaric acid 4-[apiosyl-(1->2)-glucoside](3R)-3,15-dihydroxypentadecanoic acid6''-AcetylliquiritinMacluraxanthoneHaloperidol(-)-11-Hydroxy-9,15,16-trioxooctadecanoic acid2-Oxooctadecanoic acid3-Carboxy-4-methyl-5-propyl-2-furanpropionic acidN-(2-methyl-4-oxooxetan-3-yl)acetamide(E)-Methyl-4-hydroxycinnamate(9Z,12Z,14E)-16-Hydroxy-9,12,14-octadecatrienoic acidRosiridoside BRosiridoside CCyclopentylacetic acidOleoylglycerone phosphateAlismorientol A2-Hydroxyethyl gardenamide AGlycyrrhizaisoflavone BAceneuramic acidQuinalizarinPyridin-3-ylmethyl {4-[(2-amino-4-fluorophenyl)carbamoyl]benzyl}carbamate3-(3,5-Di-tert-butyl-4-hydroxyphenyl)propanoic acidAustocystin B9,10-DihomeDocosanedioic acidCytidine 3'-monophosphateBetaenone EGlycerol 3-PhosphateTheaspirone AGly-Ala-LeuSer-Ile-IleGoshonoside F2Ala-Ser-IleCyclohexanecarboxamide5'-((Z)-Feruloyl) 3-(2'-methylarabinosylxylose)11-Oxooctadecanoic acidSoraphen OMethylisocitric acidPhaseolic acidGly-Glu-LeuDL-4-Hydroxyphenyllactic acidArachidic acidPhomopsichalasinSenecioic acidQuercetin 3-galactosideD-Saccharic acid 1,4-lactone(1R,2R,4S)-p-Menthane-1,2,8-triol 8-glucoside1-(5-Phosphoribosyl)imidazole-4-acetateTridecanedioic acidAndrographolideFenoksan8-Hydroxypinoresinol 4-glucoside11-Hydroxy-2-undecenoic acid(-)-Pinellic acidMedicocarpinBidenlignaside BN-Nonanoylglycine2-(2-ethyl-6-methyl-n-(2-sulfoacetyl)anilino)propanoic acid3-(4-Hydroxyphenyl)-beta-alanineMgdg(18:3/18:3)4-OxoprolineVal-Leu-Ile2,3,6,8-Tetrahydroxy-1-methylxanthoneFormononetin 7-O-glucuronideTrans-10-Heptadecenoic acidCer(14:0_2O/20:1_(3OH))Citbrasine3-Hydroxy-1,2-dihydropyridin-2-oneIsorhamnetin 3-galactosideLippioside I3-Hydroxydodecanoic acidEthyl pentyl ketoneAustadiolDodec-3-enedioic acidPaeonoside2-Hydroxycampholonic acid17-Hydroxyheptadecanoic acidPhaeofuran BCalcitriolCis-MelilotosideSinapoyl aldehydeDimethoxaneGeranyl-PPTianshic acid methylester9-OxoOTrETrans-Ferulic acidRumphellolide CPhe-Ser-Leu2-Hydroxydocosanoic acid1-Heptadecene-4,6-diyne-3,9-diol3,4-Dihydroxystyrene2-hydroxypentadecanoic acid(+/-)-9-HpODEFahfa(16:0/7:0)Mgmg(16:3)Adouetine XCanavaninosuccinateMethyl-2-hydroxyisobutyric acid16,17-Dihydro-16alpha,17-dihydroxygibberellin A7 17-glucosideChalepin acetateNeohesperidose6,7-Dihydro-4-(hydroxymethyl)-2-(p-hydroxyphenethyl)-7-methyl-5H-2-pyrindiniumKaempferol 3-(6''-ethylglucuronide)11-Hydroxyaclacinomycin XAmaranthinPiperonyl butoxideBruceoside A4-Oxononanoic acidDomesticoside2-(3,4-Dihydroxyphenyl)-4,6-dihydroxy-2-methoxybenzofuran-3-oneAla-Ala-LeuMevastatin6,18,19-Trihydroxytrachyloban-2-oneVismiaguianin ACaffeic acid hexosideAminohydroxybutyric acidBaohuoside IITricin 7-[rhamnosyl-(1->2)-galacturonide]Trp-TrpN-CaffeoylputrescineAsn-PheLeu-Ala-GlyButyl acrylateGlu-Leu-Leu(3Z,5E)-4-Hydroxy-6-(4-Hydroxyphenyl)Hexa-3,5-Dien-2-OneS-FuranopetasitinHydroxyanthecotulide9-Oxo-nonanoic acidEhletianol CPro-Ala8,11-eicosadiynoic acidDihydrojasmonic acidAsp-AspKuwanon DDaucolBis(4-chlorophenyl)acetic acid3-Furancarboxylic acid[5,6beta,16-Trihydroxygrayanotox-10(20)-en-3beta-yl]beta-D-glucopyranosideXanthoxin6-Oxooctadecanoic acidDG(PGD1/i-13:0/0:0)Rosmic acidRivenprost10,16-Dihydroxy-hexadecanoatePaliperidoneMulberrofuran AKaempferol 3-robinobiosideFalcarinone2-Methyl-1-hydroxypropyl-ThPP2-MethoxyestriolSophoraflavonoloside11,15-Epoxy-3(20)-phytene-1,2-diolBeta-AlanopineGlycyrolGibboside3'-KetolactoseDidymic acid7alpha,8-dihydroxy-5beta,8betaH,9betaH,10alpha-Labdan-15-oic acid2,5-Dihydro-4-hydroxy-5-oxo-3-phenyl-2-furanpropanoic acid6-Oxocativic acidNigerloxinAla-Tyr-Ile-AspRhamnetin 3-sophorosideAla-Glu-Ile6-Hydroxymethylherniarin(S)-Pterosin PCalystegin B2(6R)-Folinic acidUndecylenic acid4-Formyl-2-hydroxybenzoic acid3-Hydroxy-5Z-octenyl acetatePyrrolostatinAsn-Ile-Ile2-Phenylethyl 6-O-pentopyranosylhexopyranosideSer-Val-PheLinocinnamarin7-O-Demethyl-2,3-dihydro-albocycline5-Hydroxy-3-methyl-2,5-dihydrofuran-2-oneThreonic acidN-alpha-Acetyl-L-citrulline2,3-dihydro-1-benzofuran-2-carboxylic acid6-O-p-Coumaroyl-D-glucoseCinchonidine1,6-Anhydro-beta-D-glucose1,3-Diferuloylglycerol20-Carboxyarachidonic acidXanthoangelol CPentadecanedioic acidTuberonic acid glucosideNorepinephrine1,2,3-Propanetricarboxylic acid(R)-Methylphosphonofluoridic acid 1,2,2-trimethylpropyl esterOleandolideAsp-LeuMollicellin CMetipranololMjdbissn00000009N-Acetyl-L-phenylalanineMgmg(18:3)LysoPE(18:2w6/0:0)10-Oxooctadecanoic acidMollicellin IMjdbissn00000003Myristoylglycine(+/-)-Camphoric acidMjdbissn00000001DG(PGJ2/a-15:0/0:0)4,5-DihydrovomifoliolCaohuoside DRaltitrexedCaramboxin9-O-Acetylneuraminic acidAla-Gly-LeuTropic acidSer-Phe3,8,9-Trihydroxy-6H-benzo[c]chromen-6-oneGenistein 7-O-(2-p-coumaroylglucoside)Apigenin 7-[rhamnosyl-(1->2)-galacturonide]Cis-Aconitic AcidNecatorinePindone5alpha-Androstane-3beta,7alpha,17beta-triolDeoxyadenosineAmethopterinPA(5-iso PGF2VI/i-16:0)QuercetinValtrateDendronobiloside BA-L-Arabinofuranosyl-(1->2)-[a-D-mannopyranosyl-(1->6)]-D-mannose1-(4-hydroxyphenyl)butane-2,3-diolSer-Val-IleRobustaside A3-O-Galloylshikimic acidFulvic acid3-hydroxysuberic acidCorchorifatty acid B2-DecarboxybetaninNorfenefrine(R)-1-O-b-D-glucopyranosyl-1,3-octanediol1-Aminocyclopropanecarboxylic acid3-Glyceryl-8-hydroxy-6-methoxyisocoumarin2-hydroxynonanoic acid6-Ethyl-2,4-dihydroxy-3-methylbenzaldehydeRustosideP-hydroxybenzoyl glucoseEthionamide11-Hydroxyundecanoic acid(1S,2R,4R,8S)-p-Menthane-2,8,9-triol 2-glucosideGinsenoyne IKaempferol 3-rhamnosyl-(1->3)(4'''-acetylrhamnosyl)(1->6)-glucosideApiin3-Hydroxyoctanoic acidNigellic acid12-hydroxyoctadecanoic acidTeniposideGinsenoyne D(2S)-2-Butanol O-[b-D-Apiofuranosyl-(1->6)-b-D-glucopyranoside]Eugenitol4-(2-Amino-1-hydroxyethyl)benzene-1,2-diol(-)-VermiculineHydroxyphenyllactic acidFrangulanineVal-Val-LeuGamma-Glutamyltyramine4-Oxododecanedioic acidPurpurogallin16(S)-HetePropylparabenFahfa(18:3/19:1)Glu-Thr-IleTricetin2-n-Propyl-4-oxopentanoic acidAsp-Ala-Leu6-Oxabicyclo[3.1.0]hexane-2-undecanoic acid methyl ester(10E,15Z)-9,12,13-Trihydroxyoctadeca-10,15-dienoic acidSebacic acid monomethyl esterAlpha-D-Mannose 1-phosphateCibaric acidLiriodendrinFurfuryl isovalerate(-)-Blastmycinolactol(x)-2-Heptanol glucosideTrans-4-hydroxycyclohexanecarboxylic acidCerberalignan DUWM6(+)-Plumosol4,7,7,11-Tetramethyl-12-oxabicyclo[9.1.0]dodec-4-ene-3,6-diolGln-Glu-IlePeperomin C5,7-Dihydroxy-4H-chromen-4-one12,13-EpOMEGluconic acid7-MethylxanthineGarcimangosone C1-Octen-3-ol-3-o-beta-D-xylopyranosyl(1->6)-beta-D-glucopyranosideAcacetinLicoriconeAsp-Phe-Leu2-Furoic acidViguileninUndecanedioic acidSwertiamarinLicoriphenoneCalenduloside E(-)-ArctigeninVisnaginSer-LeuIndole-3-butyric acid(-)-PestalotinPentalenolactone OSedoheptuloseTrp-His-His12-Sulfooxy-9,10-dihydrojasmonic acidButyl 3-hydroxy-2-methylidenebutanoate3-Methyl-4-pentenoic acidGeranyl beta-D-glucopyranosidePalmitic Acid ethyl esterAnsamitocin P-3Val-Ile-GluArtemidinolFa(9:0)Citramalic acidCis-zeatin-9-N-glucoside(S)-Bitalin A 12-glucoside1,2,5,8-Tetrahydroxyanthracene-9,10-dioneLeu-Ser4-Hydroxybenzoic acid glucosideTrp-Ser-ProLaurylsulfuric acidPanaxynolEverlastoside DArtemoin A2-Hydroxyhexanedioic acidJioglutin EPA(PGF2alpha/16:0)[1S-(1a,2a,3b,4b)]-1-methyl-4-(1-methylethyl)-1,2,3-CyclohexanetriolN-AcetoxymethylflindersineFeruloylcholine6-HydroxydopamineChemanox 22Asp-Ile-Leu2-Linoleoyl-1-palmitoyl-sn-glycero-3-phosphoethanolamineB-D-Xylopyranosyl-(1->4)-a-L-rhamnopyranosyl-(1->2)-L-arabinose5,7-dihydroxy-4-methylcoumarinIsoglycycoumarin13-Hydroxy-9-methoxy-10-oxo-11-octadecenoic acid10-Hydroxy-8-nor-2-fenchanone glucosideMuricatacinPG(TXB2/a-13:0)PaclobutrazolEthyl 3-hydroxyoctanoate O-[glucosyl-(1->6)-glucoside]SinapateAvocadyne 4-acetateL-(-)-3-Phenyllactic acid9S-Hydroxy-10E,12Z,15Z-octadecatrienoic acid(-)-Glyceollin ID-Glucuronic Acid3-Isopropylmalic acidLipoxin B4Deoxyribose(3b,6b,8b,12a)-8,12-Epoxy-7(11)-eremophilene-6-angeloyloxy-8,12-dimethoxy-3-olMethyl (2E)-3-(2,5-dihydroxyphenyl)prop-2-enoate1-O-FeruloylglucoseSer-Thr-Leu6-CaffeoylsucroseConiferyl alcoholL-alpha-hydroxyisovaleric acidGlu-LeuCladinose(7'R,8'R)-4,7'-Epoxy-3',5-dimethoxy-4',9,9'-lignanetriol 9'-glucosideTrans-p-Menthane-7,8-diol 7-glucosideAsp-Gln-LeuAscorbalamic acidCaffeic Acid11-Oxohexadecanoic acidHeptanoic acid2,4-Dihydroxy-3,6-dimethylbenzoic acidPyrrolidine-3-carboxylic acid5-oxodecanoic acid3-Hydroxy-3-(methoxycarbonyl)pentanedioic acidDimethyl 2,4-bis(4-hydroxyphenyl)cyclobutane-1,3-dicarboxylateLipoxin A5Xi-7-Hydroxyhexadecanedioic acid5-O-Methylembelin7a-Epialexaflorine4-Anisic acidMedica 16(+)-Camphanic acid1-Methylxanthine2-Methoxy-4-vinylphenolBuflomedil3-(2-Hydroxyphenyl)propionic acidOctadecanedioic acidValinopineCalanolide ASyringic acid1,2,2-Trimethylcyclopentane-1,3-dicarboxylic acid2-Amino-5-phosphonopentanoic acidAsp-Phe-IleQuercetin 3-[p-coumaroyl-(->6)-glucosyl-(1->2)-glucosyl-(1->2)-glucoside]EthotoinMesaconic acid6''-O-MalonyldaidzinThiochromeAucubin(Z)-3,5-Hexadienyl butyrate(2E)-21-hydroxyhenicos-2-enoic acidUreidopropionic acidL-Asparagine2-Benzylidenesuccinic acidOxyphenbutazoneGlutaric acidZapoterin2-HydroxycineolScortechinone PDL-Benzylsuccinic acid2-({4-[4-(benzyloxy)phenyl]-4h-1,2,4-triazol-3-yl}thio)-n-phenylacetamideKaempferol 3-beta-D-galactosideCotinine-N-oxidePanaxytriolBeta-D-SedoheptulopyranoseIsolicoflavonolVal-PheSer-SerPseudouridine2-Methylglutaric acidRotenone(-)-Senkyunolide JOsmanthuside ASachaloside I2-Hydroxypalmitic acidFeruloyl lactate3-epi-6-deoxocathasteroneVal-Gly-IleGrevilloside FPrelunularic acid19-Hydroxycinnzeylanol 19-glucosideSativic acidPraziquantelGuanosineDiacylglycerolDihydrodehydrodiconiferyl alcohol7-Keto-8-aminopelargonic acidKaempferol-3-glucoside-3''-rhamnosideAlpha-(1,2-Dihydroxyethyl)-1,2,3,4-tetrahydro-7-hydroxy-9-methoxy-3,4-dioxocyclopenta[c][1]benzopyran-6-acetaldehydeFurocoumarinic acid glucosidePinoresinolPa(18:2/18:3)Dodecyl Hydrogen SulfateHexane-1,5-diol 1-O-beta-D-glucopyranoside3-MethylxanthineAvenestergenin B22-methylcitric acidKaempferol 3-sophorotriosideHexadecanedioic acid2D-5-O-Methyl-2,3,5/4,6-pentahydroxycyclohexanone1,3-Dihydroxypropan-2-yl phosphate(1R*,2R*,4R*,8S*)-p-Menthane-1,2,8,9-tetrol 9-glucosideEriojaposide A(2R,3Z)-Phycocyanobilin(Z)-N-Feruloyl-5-hydroxyanthranilic acid(R)-8-Acetoxycarvotanacetone3-Hydroxybenzoic Acid3,5-Pyridinedicarboxylic acid, 1,4-dihydro-2,4,6-trimethyl-, diethyl ester9S-Hydroperoxy-10E,12Z-octadecadienoic acid2-Hydroxypentanoic AcidNorviburtinalUridine2-[[2-(3,5-Dihydroxy-4-isopropyl-phenyl)-2-guanidino-acetyl]amino]acetic acidGlu-PheEicosanedioic acid4-Methoxyphenylacetic AcidPentadecanalQuercetin-3'-glucuronideMalonic acidCapsiateDIMP1-Octen-3-yl glucosideGeranylcitronellolIsoketocamphoric acidD-tartaric acid1-O,6-O-Bis(4-Hydroxy-Trans-cinnamoyl)-Beta-D-GlucopyranoseIsoeugenolEpicatechin gallateOnonin3-Hydroxymethylglutaric acid9,13-Dihydroxy-4-Megastigmen-3-One 9-GlucosideKetodeoxyoctonic acidMacrosphelide KObacunoneBeraprostFa(16:1)Epicatechin 3-O-(4-methylgallate)6''-O-AcetylholocalinSer-Glu-LeuHyp-Val5,8,11-Eicosatrienoic acid, 14,15-dihydroxy-, (5Z,8Z,11Z)-Aromadendrin6,8-Dimethyl-4-hydroxycoumarin2,2-Dimethylglutaric acidHynapene AFumaric acidNornicotineFumagillolAdipamideSakuraninTyvelosePhorbol 12-myristate 13-acetateProstratinSulfo jasmonate12(13)-Epoxy-9Z-octadecenoic acid2-O-Methyl-L-fucoseN-acetyl-l-methionineTalaroconvolutin BAcoric acidD-Ribulose 5-phosphate11-Hydroxy-9-tridecenoic acidC-veratroylglycolAsp-Leu-Ile5-Hydroxy-2-(3-hydroxy-2-methoxycarbonyl-5-methylphenoxy)-3-methoxybenzoic acidIsoguanosineDrupaninStrictosidine2-Oxo-4-phenylbutanoic acidGly-Ile-Ile3,12-dihydroxydodecanoic acidChromonePEtOH(18:2/16:3)2-AcetylpyridineGlycosmisic AcidTsibulin 221-hydroxy-heneicosanoic acid4'-O-Methyl-(-)-epicatechin 3'-O-glucuronideHarmalolAla-Ile-AspAsparagoside A5-Heptyltetrahydro-2-oxo-3-furancarboxylic acidTridec-2-enedioic acid5,7-DihydroxycoumarinFolinic acid(2Z)-3-[2-(beta-D-Glucopyranosyloxy)phenyl]acrylic acidSorbitan laurate2-Isopropylmalic acidTriethylene glycol diglycidyl etherLariciresinol 4-O-glucosideZeanoside B5-MethylthioriboseAvocadyne 1-acetateFa(18:3+3o)2-Methoxyhexadecanoic acidFlavokawain AFa(16:0)Acetone cyanohydrinPe(34:2)2-(3-methylbutoxy)-6-[(3,4,5-trihydroxyoxan-2-yl)oxymethyl]oxane-3,4,5-triolPA(PGF2alpha/P-16:0)FormacidineSecoeremopetasitolide AN-alpha-Benzoyl-L-arginineMethyldehydrograviphaneSuberic acidKenposide A9(s)-hodeAsn-Val-LeuSmgdg(o-16:2/7:0)Fahfa(16:0/11:0)Monnieriside gCorrin2,6-Dihydroxybenzoic acidNiazimininCompactin diol lactoneCaiophoraeninPA(PGF1alpha/8:0)2-Hydroxyheptanoic acidRhodomollein XIIICasegravol isovalerate15-hedeScyllo-InositolO(6)-Methyl-2'-deoxyguanosine18:3-18:3-dgdgAmoenin(6E)-8-hydroxygeraniol2,5-Diaziridinyl-3,6-bis(2-hydroxyethylamino)-1,4-benzoquinoneVerbasoside5-Aminopentanoic acidSer-Leu-Leu(E)-10-Hydroxy-8-decenoic acid13-hotreCanavalioside4-(6-methyl-4-oxoheptan-2-yl)cyclohexene-1-carboxylic acid4-HydroxystyreneTrans-p-Coumaroyl beta-D-glucopyranoside12,13-trans-Epoxy-9-oxo-10E,15Z-octadecadienoic acidCyanidin 3-sambubiosideSterebin GSterebin DHeliangin9-Oxo-10(E),12(E)-octadecadienoic acidSterebin BB-D-fructosyl-a-D-(6-O-(E))-feruloylglucosideCis-10-Hydroxylinalyl oxide 7-glucosideLeu-LeuMagnesium protoporphyrin[6]-Gingerdiol 5-O-beta-D-glucopyranosidePG(PGF2alpha/20:4(5Z,8Z,11Z,14Z))Aspergillide CEucomic acidFa(18:2+3o)Quercetin-3-o-deoxyhexosyl(1-2)pentoside5-Oxooctadecanoic acidTerconazoleGly-Phe-Leu-GlyPro-Tyr-GlnCedrinSecologanosideKankanoside EPhe-Thr-AsnAla-Val-Leu1-Deoxy-D-xylulose3-hydroxycinnamic acidCaffeic acid 3-glucosideGlu-AsnGlyasperin F1-(4-Hydroxy-3-methoxyphenyl)-3-decanoneFoliasalacioside DNitrosobenzene5-(4-sulfophenyl)undecaneN-palmitoyl glycine3-(2-Heptenyloxy)-2-hydroxypropyl undecanoateHemsleyanosideDjalonenolIle-Val-IleFahfa(16:0/3:0)Piperonyl sulfoxideIndolapril10-methylhexadecanoic acidKetotifen-N-glucuronideVal-LeuN(6)-methyl-AMP3-beta-Hydroxy-4-beta-methyl-5-alpha-cholest-7-ene-4-alpha-carboxylateSulindacLicoricidin2,2-Bis(4-hydroxyphenyl)-propanoic acidPhenolphthalin(1R,2R,4S,5S,6R,7S)4,5-Epoxygermacra-9Z-en-1,2,6-triol6-Hydroxyluteolin 6-xyloside7-Ethoxycoumarin2-Oxoheptanedioic acid4-Methyl-5-oxo-2-pentyl-2,5-dihydro-3-furancarboxylic acidGuanosine 5'-monophosphate3-Phenyl-beta-alanine6''-Malonylgenistin4-hydroxy-2',3,4',6'-tetramethoxychalconePinonic acidGly-Tyr-Lys5-(3-Pyridyl)-2-hydroxytetrahydrofuranPA(6 keto-PGF1alpha/22:4(7Z,10Z,13Z,16Z))L-Ribonic acidGlu-Pro3-Hydroxyoctadecanoic acidCis-3-Hexenyl acetateLysoPE(0:0/18:0)NaringeninIle-Asp3,4-Dihydroxyphenylacetic acidGlucaric acid(1beta,2beta,5beta)-p-Menth-3-ene-1,2,5-triol9-(2,3-Dihydroxypropoxy)-9-oxononanoic acidDihydrofolic acidCurcumin 4'-O-beta-D-gentiobiosyl 4''-O-beta-D-glucosideMG(5-iso PGF2VI/0:0/0:0)Fusarin C13-hydroxyoctadecanoic acidAndrosin1-palmitoyl-sn--glycero-3-phospho-D-myo-inositolDL-Malic acidChaenorrhinosideCofarylosideGlu-Ile-IleThr-Ala-IleGly-LeuGibberellin A12Citreoviridin C2-(acetylamino)hexanoic acidGlu-Arg-LeuPorphobilinogenDeacetylnomilin2-OxosuberateSachaloside VII(2S,4R)-p-Mentha-1(7),5-dien-2-ol acetateEugeninOleuropeinRengyoside BFormycin bDodec-7-enoic acidAsp-Val-IleTyr-MetPhloionolic acid(E)-2-Tridecene-4,6,8-triyn-1-olIsoeugenitol(7S)-HydropreneRicinoleic acid3-O-beta-D-Galactopyranosyl-L-arabinoseIdebenone3-hydroxy-5,5,8a-trimethyl-3,4,4a,6,7,8-hexahydronaphthalene-2-carboxylic acid3-Hydroxy-2,6,6-trimethyl-1-cyclohexene-1-carboxylic acidGly-Val-Leu(-)-RiboflavinD-MannoseAlpha-EudesmolAustalide LNeoarctin AAlpha-D-Galactose 1-phosphateCis-9,10-Epoxystearic acidLariciresinolIle-ProMethyl pheophorbide b3-Methyladipic acidPentadecanoic acidSyringetin-3-O-glucoside3,5-dihydroxydecanoic acidShikimateDiaportinol3-Aminopentanedioic AcidSer-Ser-IleNifuradeneL-Arabinopyranose2,3-DihydroxypropanamideKaempferolGalactinolFerulic acidDehydrocarissone10-FormyltetrahydrofolatePrehumuloneNorathyriolPretyrosineHexyl 6-O-pentopyranosylhexopyranosideS-JaponinN-AcetylnorvalineNeocarthamin4-Hydroxy-3-methoxybenzenemethanol1-[(2R,3S,5R)-3,4-Dihydroxy-5-(hydroxymethyl)oxolan-2-yl]pyrimidine-2,4-dioneAsn-Leu-Leu2-HydroxyacetophenoneGibberellin A20 13-glucosideIsovitexinTanegoside AKievitone hydrateMaltotetraoseAdb-fubinacaPsilocybinN-Acetyl-DL-valineGlu-Asp-Lys3-(3,4-Dihydroxyphenyl)-2-hydroxypropanoic acidAleuritic acidGinkgotoxinErythrocentaurinL-Glutamic AcidXi-Linalool 3-[rhamnosyl-(1->6)-glucoside]Lansiumarin C6-Ketomyristic acidPeperinic acid7-Oxo-11-dodecenoic acidTrp-Ser-Ile(E)-2-(Methoxycarbonylmethyl)butenedioate5,6-epoxy,18R-HEPEDimethylmalonic acidLpc(16:0)Quercetin 3-xylosyl-(1->6)-glucoside13-hpotreDihydrocitrinone9-hydroxyoctadecanoic acid3-Hydroxy-4-methoxybenzaldehydeMyristic acidMyricetin 3-robinobioside6-MethylprednisoneSuccinic acid(+)-LariciresinolViridamineCytidine-3',5'-cyclicmonophosphate2,4-dinitrophenol(+)-Syringaresinol O-beta-D-glucosideN-Docosahexaenoyl GlycineLeu-Phe9-Oxohexadecanoic acidKanokoside C5-Oxohexanoic acidGlu-Val-AlaTrachelogenin6alpha-Hydroxygeniposide_ Deacetylasperulosidic acid methyl esterTanakineSpinasaponin AThr-Ile15-Methoxyisodauc-3-ene-1beta,5alpha-diol3-Hydroxyphenylacetic AcidButyl (S)-3-hydroxybutyrate glucosideArabinoseAtractyloside AAcorusdiolKaempferol 3-sophoroside 7-glucoside3-O-Caffeoyl-4-O-methylquinic acidBeta-D-Galactosyl-(1->4)-L-rhamnoseCicaprost3-(4-Hydroxyphenyl)-3-oxopropanoic acidOxaloglutarate8-(3-Octyl-2-oxiranyl)octanoic acid2'-(E)-Feruloyl-3-(arabinosylxylose)Hydroxymyricanone(+)-Neomethynolide7,15-Dihydroxyabieta-8,11,13-trien-18-oic acid(-)-WikstromolAdenineSilvestrolOctadeca-9-ene-1,18-dioic-acidPA(5-iso PGF2VI/16:0)Gly-Phe3-hydroxyheptadecanoic acidArg-Lys(4R,5S,7R,11S)-11,12-Dihydroxy-1(10)-spirovetiven-2-one 11-glucoside(3R)-3,19-dihydroxynonadecanoic acidMangostanolN-Pyruvoyl-5-methoxy-3-hydroxyanthranilateIcariside B5(R)-PrunasinFahfa(18:2/18:1)Sec-o-GlucosylhamaudolL-SerineLactupicrinKanzonol MLinalool oxide IIIUridine monophosphate (UMP)Cis-Pinonic acid2-(Carboxymethyl)benzoic acidDihydroxyacetone3,4-Dimethyl-5-pentyl-2-furanheptanoic acidLeu-IlePutaminoxin E9,10-Dihydroxystearate(3S)-3-hydroxycyclocitralLucidenic acid M9-Oxo-11-(3-pentyl-2-oxiranyl)-10E-undecenoic acidAla-GlyN-Acetyl-L-prolineValsartan acid3',4',5-Trihydroxy-3,7-dimethoxyflavone 5-glucoside3-O-Caffeoyl-1-O-methylquinic acidAlpha-Licanic acidTrans-2-OctenalEthylmalonic acid15-hete(-)-Abscisic acid4-O-Methyl episappanolGamma-Linolenic acid3-Methyglutaric AcidDihydroxy-valerateValproic acidArbutinNarirutinSebacic acid12-methylhexadecanoic acidAla-Gln-Leu3-Dehydroshikimic acid19-hydroxy-nonadecanoic acidChloriolide5-DeoxykievitoneArctinone3-[(2,4-Dihydroxy-3,3-dimethylbutanoyl)amino]prop-2-enoic acidAvocadene 4-acetateAsperulosidic acid2,6,10,14-Tetramethyl-6,10,15-hexadecatriene-2,3,8,14-tetrol 8-acetateIsoniazid pyruvateHymenoside M13S-Hydroxy-9Z,11E,15Z-octadecatrienoic acidTetranor-12(R)-HETEApigeninOctadec-9-enedioic acidAstragalinDL-2-hydroxy stearic acidDL-beta-Hydroxypalmitic acidLpe(18:3)SobrepinBeta-Cyano-L-alaninePicrocrocin4',7-Di-O-methylcatechinDG(6 keto-PGF1alpha/0:0/a-15:0)Asp-Ile6-Deoxylamioside2-OxoarginineDodecanedioic acidFoetisulfide AUstiloxin DLappaol CTerniflorinDisperse Blue 1S-AdenosylmethionineTrans-fertaric acidN-acetylsphingosine3,4-Dihydro-2H-1-benzopyran-2-oneLesquerolic acidGingerol5-Hexyl-2-furanoctanoic acidAllixin8-hydroxy-3-methoxycarbonyl-2-methylidenenonanoic acid9,12,13-TodeaCyclopassifloic acid D6''-O-Acetylglycitin1-Palmitoyl-2-hydroxy-sn-glycero-3-phosphoethanolamine5-OxoETEEurystatin DIcariside F21,4-Cyclohexanedicarboxylic AcidFahfa(2:0/16:0)3-tert-butyladipic acid3,5-Dihydroxy-6,7-megastigmadien-9-one8-methyl Nonanoic acid4-Allyl-2,6-dimethoxyphenolLeu-GluAlbocycline M-6RubschisandrinThymidine(-)-Aspidospermine5,9-Epidioxy-3-hydroxyergost-7-en-6-oneSwerilactone LFraxiresinol 4'-O-beta-D-glucopyranosideAlpha-Zearalanol3-Hydroxysebacic acidPantetheineMethylmalonic acidCrocusatin GMalic acidDG(PGD1/a-13:0/0:0)4-IsopentylphenolIpomeatetrahydrofuran4-Methylbenzoic acid1-AcetylprolineLinalool oxide (cis-pyran)4-(Hexopyranosyloxy)-3-methoxybenzoic acid11b,13-DihydrolactucopicrinPandangolide 16-C-Methylkaempferol 3-glucoside2',6'-Diacetyl-3,6-diferuloylsucrose6-HydroxykaempferolArmexifolinAlbidosideL-Aspartic AcidTrans-2-Hydroxycinnamic acidMaltoseErythronolactoneLpc(18:2)2,2'-(3-methylcyclohexane-1,1-diyl)diacetic acidQuercetagetinAbafunginJamesoniellide D4-Hydroxy-8-methoxy-2H-furo[2,3-h]-1-benzopyran-2-oneElenolideTraumatinGln-Val-IleNonadecanoic acidCoronaric acidCelebixanthoneThr-Asp-IleAllantoic acidElaidic acidSer-Val-Gly-Glu12-hydroxyjasmonic acidEpicatechin2-Hexylfuran6-Acetoxy-7-hydroxymyrcene-7-O-beta-D-glucopyranoside-2'-O-acetateAzelaic acid6',7'-DihydroxybergamottinDG(PGE2/a-13:0/0:0)TripdiolideMirabegronQuercetin 7-glucosideN-Acetyl-L-leucineHT-2 ToxinAvocadeneD-Tagatose2-(N-Hydroxyamino)-3-phenylpropanoic acidLpg(16:1)Curcumin IISalazinic acidHydroxytyrosol9-Peroxy-5,6E-dehydro-6,7-dihydrogeranyl acetatePEtOH(16:3/18:3)Asn-Asp-Tyr2''-(6''-p-Coumaroylglucosyl)quercitrin4-Methylumbelliferone glucuronide2-Methylpropyl 3-hydroxy-2-methylidenebutanoateLevuglandin D2Manumycin A8-O-Acetyl shanzhiside methyl ester5'-HydroxycotinineNorvalinePicroside I5,7-Megastigmadien-9-ol glucosidefalseMetabolomic analysis of inhibited pollen tube growth in unilateral crosses of Clematis<p>This study utilized broad-target metabolomics to analyze the metabolic changes underlying the inhibition of pollen tube growth in Clematis one-way hybrid crosses with low compatibility. It identified differentially accumulated metabolites and elucidated the key metabolic pathways involved in one-way hybridization barriers, thereby providing a metabolic basis for interspecific hybrid breeding in Clematis.</p>2026-09-232026-09-23MTBLS15784