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Carbon-Coated CuNb₁₃O₃₃ as A New Anode Material for Lithium Storage.

ABSTRACT: Niobates are very promising anode materials for Li⁺-storage rooted in their good safety and high capacities. However, the exploration of niobate anode materials is still insufficient. In this work, we explore ~1 wt% carbon-coated CuNb₁₃O₃₃ microparticles (C-CuNb₁₃O₃₃) with a stable shear ReO₃ structure as a new anode material to store Li⁺. C-CuNb₁₃O₃₃ delivers a safe operation potential (~1.54 V), high reversible capacity of 244 mAh g^-1, and high initial-cycle Coulombic efficiency of 90.4% at 0.1C. Its fast Li⁺ transport is systematically confirmed through galvanostatic intermittent titration technique and cyclic voltammetry, which reveal an ultra-high average Li⁺ diffusion coefficient (~5 × 10^-11 cm² s^-1), significantly contributing to its excellent rate capability with capacity retention of 69.4%/59.9% at 10C/20C relative to 0.5C. An in-situ XRD test is performed to analyze crystal-structural evolutions of C-CuNb₁₃O₃₃ during lithiation/delithiation, demonstrating its intercalation-type Li⁺-storage mechanism with small unit-cell-volume variations, which results in its capacity retention of 86.2%/92.3% at 10C/20C after 3000 cycles. These comprehensively good electrochemical properties indicate that C-CuNb₁₃O₃₃ is a practical anode material for high-performance energy-storage applications.

SUBMITTER: Gao J

PROVIDER: S-EPMC10004636 | biostudies-literature | 2023 Feb

REPOSITORIES: biostudies-literature

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Carbon-Coated CuNb13O33 as A New Anode Material for Lithium Storage.

Gao Jiazhe J Li Songjie S Wang Wenze W Ou Yinjun Y Gao Shangfu S Liu Xuehua X Lin Chunfu C

Materials (Basel, Switzerland) 20230222 5

Niobates are very promising anode materials for Li+-storage rooted in their good safety and high capacities. However, the exploration of niobate anode materials is still insufficient. In this work, we explore ~1 wt% carbon-coated CuNb13O33 microparticles (C-CuNb13O33) with a stable shear ReO3 structure as a new anode material to store Li+. C-CuNb13O33 delivers a safe operation potential (~1.54 V), ...[more]

PMID: 36902934

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Project description:Bagasse-derived carbon electrodes were developed by doping with nitrogen functional groups and compositing with high-capacity MnO2 nanoparticles (MnO2/NBGC). The bagasse-derived biochar was N-doped by refluxing in urea, followed by the deposition of MnO2 nanoparticles onto its porous surface via the hydrothermal reduction of KMnO4. Different initial KMnO4 loading concentrations (i.e. 5, 10, 40, and 100 mM) were applied to optimize the composite morphology and the corresponding electrochemical performance. Material characterization confirmed that the carbon composite has a mesoporous structure along with the dispersion of MnO2 nano-particles on the N-containing carbon surface. It was found that the 5-MnO2/NBGC sample exhibited the highest electrochemical performance with a reversible capacity of 760 mA h g-1 at a current density of 186 mA g-1. It delivered reversible capacities of 488 and 390 mA h g-1 in cycle tests at 372 and 744 mA g-1, respectively, for 150 cycles and presented good reversibility with nearly 100% coulombic efficiency. In addition, it could exert high capacities up to 388 and 301 mA h g-1 even under high current densities of 1860 and 3720 mA g-1, respectively. Moreover, most of the prepared composite products showed high rate capability with great reversibility up to more than 90% after testing at a high current density of 3720 mA g-1. The great electrochemical performance of the MnO2/NBGC nanocomposite electrode can be attributed to the synergistic impact of the hierarchical architecture of the MnO2 nanocrystals deposited on porous carbon and the capacitive effect of the N-containing defects within the carbon material. The nanostructure of the MnO2 particles deposited on porous carbon limits its large volume change during cycling and promotes good adhesion of MnO2 nanoparticles with the substrate. Meanwhile, the capacitive effect of the exposed N-functional groups enables fast ionic conduction and reduces interfacial resistance at the electrode interface.

Dataset Information

Carbon-Coated CuNb₁₃O₃₃ as A New Anode Material for Lithium Storage.

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Carbon-Coated CuNb<sub>13</sub>O<sub>33</sub> as A New Anode Material for Lithium Storage.

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