Controllable Preparation of Gold Nanocrystals with Different Porous Structures for SERS Sensing.

ABSTRACT: Porous Au nanocrystals (Au NCs) have been widely used in catalysis, sensing, and biomedicine due to their excellent localized surface plasma resonance effect and a large number of active sites exposed by three-dimensional internal channels. Here, we developed a ligand-induced one-step method for the controllable preparation of mesoporous, microporous, and hierarchical porous Au NCs with internal 3D connecting channels. At 25 °C, using glutathione (GTH) as both a ligand and reducing agent combined with the Au precursor to form GTH-Au(I), and under the action of the reducing agent ascorbic acid, the Au precursor is reduced in situ to form a dandelion-like microporous structure assembled by Au rods. When cetyltrimethylammonium bromide (C₁₆TAB) and GTH are used as ligands, mesoporou

SUBMITTER: Qin Y 

PROVIDER: S-EPMC10004769 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature