Controllable Deposition of Bi onto Pd for Selective Hydrogenation of Acetylene.

ABSTRACT: The rational regulation of catalyst active sites at atomic scale is a key approach to unveil the relationship between structure and catalytic performance. Herein, we reported a strategy for the controllable deposition of Bi on Pd nanocubes (Pd NCs) in the priority order from corners to edges and then to facets (Pd NCs@Bi). The spherical aberration-corrected scanning transmission electron microscopy (ac-STEM) results indicated that Bi₂O₃ with an amorphous structure covers the specific sites of Pd NCs. When only the corners and edges of the Pd NCs were covered, the supported Pd NCs@Bi catalyst exhibited an optimal trade-off between high conversion and selectivity in the hydrogenation of acetylene to ethylene under ethylene-rich conditions (99.7% C₂H₂

SUBMITTER: Kang H 

PROVIDER: S-EPMC10005703 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature