Hybrid Donnan dialysis-electrodialysis for efficient ammonia recovery from anaerobic digester effluent.

ABSTRACT: Ammonia recovery from wastewater is crucial, yet technology of low carbon emission and high ammonia perm-selectivity against complex stream compositions is urgently needed. Herein, a membrane-based hybrid process of the Donnan dialysis-electrodialysis process (DD-ED) was proposed for sustainable and efficient ammonia recovery. In principle, DD removes the majority of ammonia in wastewater by exploring the concentration gradient of NH₄ ⁺ and driven cation (Na⁺) across the cation exchange membrane, given industrial sodium salt as a driving chemical. An additional ED stage driven by solar energy realizes a further removal of ammonia, recovery of driven cation, and replenishment of OH^- toward ammonia stripping. Our results demonstrated that the hybrid DD-ED process achieved ammonia removal efficiency >95%, driving cation (Na⁺) recovery efficiency >87.1% for synthetic streams, and reduced the OH^- loss by up to 78% compared to a standalone DD case. Ammonia fluxes of 98.2 g_N m^-2 d^-1 with the real anaerobic digestion effluent were observed using only solar energy input at 3.8 kWh kg_N ^-1. With verified mass transfer modeling, reasonably controlled operation, and beneficial recovery performance, the hybrid process can be a promising candidate for future nutrient recovery from wastewater in a rural, remote area.

SUBMITTER: Dai Z 

PROVIDER: S-EPMC10006519 | biostudies-literature | 2023 Jul

REPOSITORIES: biostudies-literature