Nickel substituted polyoxometalates in layered double hydroxides as metal-based nanomaterial of POM-LDH for green catalysis effects.

ABSTRACT: Three nickel substituted Keggin-type polyoxometalates, α-[SiW₉O₃₇{Ni(H₂O)}₃]^-10 (denoted as SiW₉Ni₃), was intercalated into Zn₃Al based Layered Double Hydroxide (Zn₃Al-LDH) by the selective ion-exchange technique. The as-synthesized nanocomposite, SiW₉Ni₃@Zn₃Al, was used as heterogeneous nanoreactor to promote the synthesis of drug-like aminoimidazopyridine small molecule skeletons via the well-known Ugi-type Groebke-Blackburn-Bienaymé reaction (GBB 3-CRs) in the absence of any acid/additive and under mild and solvent-free conditions. A synergistic catalytic effect between SiW₉Ni₃ polyoxometalate and Zn₃Al-LDH precursors is evi

SUBMITTER: Ghiasi Moaser A 

PROVIDER: S-EPMC10011597 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature