Palladium Schiff base complex-modified Cu(BDC-NH₂) metal-organic frameworks for C-N coupling.

ABSTRACT: In this study, the synthesis of a novel functionalized metal-organic-framework (MOF) [Cu(BDC-NH₂)@Schiff-base-Pd(ii)] catalyst via post-synthetic modification of Cu(BDC-NH₂) is reported. The targeted complex was prepared by chemically attaching N,N'-bis(5-formylpyrrol-2-ylmethyl) homopiperazine via a Schiff base reaction followed by complexation with Pd ions. Afterwards, the synthesized solid was applied as a very effective multifunctional catalyst in C-N coupling reactions. The synthesized compounds were identified by suitable techniques including N₂ isotherms, EDX spectroscopy, FT-IR spectroscopy, XRD, SEM, ICP-OES and TG-DTA. This nanocatalyst was used in C-N cross-coupling reactions, and it showed its usage in a diverse range

SUBMITTER: Rabiei K 

PROVIDER: S-EPMC10014173 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature