Interface engineering of CeO₂ nanoparticle/Bi₂WO₆ nanosheet nanohybrids with oxygen vacancies for oxygen evolution reactions under alkaline conditions.

ABSTRACT: Because of the interactive combination synergy effect, hetero interface engineering is used way for advancing electrocatalytic activity and durability. In this study, we demonstrate that a CeO₂/Bi₂WO₆ heterostructure is synthesized by a hydrothermal method. Electrochemical measurement results indicate that CeO₂/Bi₂WO₆ displays not only more OER catalytic active sites with an overpotential of 390 mV and a Tafel slope of 117 mV dec^-1 but also durability for 10 h (97.57%). Such outstanding characteristics are primarily attributed to (1) the considerable activities by CeO₂ nanoparticles uniformly distributed on Bi₂WO₆ nanosheets and (2) the plentiful Bi-O-Ce and W-O-Ce species playing the role of strong couples between CeO₂ nanoparticles and Bi₂WO₆ nanosheets and oxygen vacancy existence in CeO₂ nanoparticles, which can improve the electrochemical active surface area (ECSA) and activity, and enhance the conductivity for OERs. This CeO₂/Bi₂WO₆ consists of the heterojunction engineering that can open a modern method of thinking for high effective OER electrocatalysts.

SUBMITTER: Nam D 

PROVIDER: S-EPMC10018795 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature