Improving CO₂ photoconversion with ionic liquid and Co single atoms.

ABSTRACT: Photocatalytic CO₂ conversion promises an ideal route to store solar energy into chemical bonds. However, sluggish electron kinetics and unfavorable product selectivity remain unresolved challenges. Here, an ionic liquid, 1-ethyl-3-methylimidazolium tetrafluoroborate, and borate-anchored Co single atoms were separately loaded on ultrathin g-C₃N₄ nanosheets. The optimized nanocomposite photocatalyst produces CO and CH₄ from CO₂ and water under UV-vis light irradiation, exhibiting a 42-fold photoactivity enhancement compared with g-C₃N₄ and nearly 100% selectivity towards CO₂ reduction. Experimental and theoretical results reveal that the ionic liquid extracts electrons and facilitates CO₂ redu

SUBMITTER: Liu Y 

PROVIDER: S-EPMC10020152 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature