Dataset Information

Highly Permeable Reverse Osmosis Membranes via Molecular Layer-by-Layer Deposition of Trimesoyl Chloride and 3,5-Diaminobenzoic Acid.

ABSTRACT: We present a series of polyamide membranes synthesized via molecular layer-by-layer (mLbL) deposition of trimesoyl chloride (TMC) and 3,5-diaminobenzoic acid (BA). These membranes exhibit superior NaCl rejection compared to previously reported TMC-BA membranes prepared via interfacial polymerization, with the improved performance of the mLbL films attributable to higher cross-link density facilitated by the stepwise deposition process in good solvents. We compare the TMC-BA series with membranes synthesized from TMC and m-phenylenediamine (MPD), a conventional reverse osmosis membrane chemistry. At the minimum thickness capable of 90 % NaCl rejection, mLbL TMC-BA membranes exhibit 50 % greater water permeance than mLbL TMC-MPD.

SUBMITTER: Mulhearn WD

PROVIDER: S-EPMC10020955 | biostudies-literature | 2021

REPOSITORIES: biostudies-literature

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Highly Permeable Reverse Osmosis Membranes via Molecular Layer-by-Layer Deposition of Trimesoyl Chloride and 3,5-Diaminobenzoic Acid.

Mulhearn William D WD Stafford Christopher M CM

ACS applied polymer materials 20210101 1

We present a series of polyamide membranes synthesized via molecular layer-by-layer (mLbL) deposition of trimesoyl chloride (TMC) and 3,5-diaminobenzoic acid (BA). These membranes exhibit superior NaCl rejection compared to previously reported TMC-BA membranes prepared via interfacial polymerization, with the improved performance of the mLbL films attributable to higher cross-link density facilitated by the stepwise deposition process in good solvents. We compare the TMC-BA series with membranes ...[more]

PMID: 36936726

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Project description:Many companies in the food industry apply reverse osmosis (RO) membranes to ensure high-quality reuse of water. Biofouling is however, a common, recalcitrant and recurring problem that blocks transport over membranes and decreases the water recovery. Microorganisms adhering to membranes may form biofilm and produce an extracellular matrix, which protects against external stress and ensures continuous attachment. Thus, various agents are tested for their ability to degrade and disperse biofilms. Here, we identified industrially relevant bacterial model communities that form biofilms on RO membranes used for treating process water before reuse. There was a marked difference in the biofilm forming capabilities of bacteria isolated from contaminated RO membranes. One species, Raoultella ornithinolytica, was particularly capable of forming biofilm and was included in most communities. The potential of different enzymes (Trypsin-EDTA, Proteinase K, α-Amylase, β-Mannosidase and Alginate lyase) as biofouling dispersing agents was evaluated at different concentrations (0.05 U/ml and 1.28 U/ml). Among the tested enzymes, β-Mannosidase was the only enzyme able to reduce biofilm formation significantly within 4 h of exposure at 25 °C (0.284 log reduction), and only at the high concentration. Longer exposure duration, however, resulted in significant biofilm reduction by all enzymes tested (0.459-0.717 log reduction) at both low and high concentrations. Using confocal laser scanning microscopy, we quantified the biovolume on RO membranes after treatment with two different enzyme mixtures. The application of proteinase K and β-Mannosidase significantly reduced the amount of attached biomass (43% reduction), and the combination of all five enzymes showed even stronger reducing effect (71% reduction). Overall, this study demonstrates a potential treatment strategy, using matrix-degrading enzymes for biofouled RO membranes in food processing water treatment streams. Future studies on optimization of buffer systems, temperature and other factors could facilitate cleaning operations based on enzymatic treatment extending the lifespan of membranes with a continuous flux.

Dataset Information

Highly Permeable Reverse Osmosis Membranes via Molecular Layer-by-Layer Deposition of Trimesoyl Chloride and 3,5-Diaminobenzoic Acid.

Publications

Highly Permeable Reverse Osmosis Membranes via Molecular Layer-by-Layer Deposition of Trimesoyl Chloride and 3,5-Diaminobenzoic Acid.

Similar Datasets

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