PH dependent electro-oxidation of arsenite on gold surface: Relative kinetics and sensitivity.

ABSTRACT: A detailed kinetic investigation of As(III) oxidation was performed on gold surface within pH between ∼3.0 and ∼9.0. It was found that the As(III) oxidation on the gold surface follows a purely adsorption-controlled process irrespective of pH. The evaluated adsorption equilibrium constant decreased from 3.21 × 10⁵ to 1.61 × 10⁵ mol L^-1 for acidic to basic medium, which implies the strong affinity of the arsenic species in the acidic medium. Besides, the estimation of Gibbs free energy revealed that an acidic medium promotes arsenic oxidation on gold surface. In mechanistic aspect, the oxidation reaction adopts a stepwise pathway for acidic medium and a concerted pathway for neutral and basic medium. From the substantial kinetic evaluation, it is established

SUBMITTER: Ahsan M 

PROVIDER: S-EPMC10023909 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature