Hydrogen Exchange through Hydrogen Bonding between Methanol and Water in the Adsorbed State on Cu(111).

ABSTRACT: The interaction between submonolayers of methanol and water on Cu(111) is studied at 95-160 K temperature range with surface-sensitive infrared spectroscopy using isotopically labeled molecules. The initial interaction of methanol with the preadsorbed amorphous solid water at 95 K is through hydrogen-bonding with the dangling hydroxyl groups of water. Upon increasing the temperature up to 140 K, methanol and deuterated water form H-bonded structures which allow hydrogen-deuterium exchange between the hydroxyl group of methanol and the deuterated water. The evolution of the O-D and O-H stretching bands indicate that the hydrogen transfer is dominant at around 120-130 K, slightly below the desorption temperature of methanol. Above 140 K, methanol desorbs and a mixture of hydrogen-related wat

SUBMITTER: Ben David R 

PROVIDER: S-EPMC10026171 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature