Isolation of dissolved organic matter from aqueous solution by precipitation with FeCl₃: mechanisms and significance in environmental perspectives.

ABSTRACT: Ferric ions can bind strongly with dissolved organic matter (DOM), including humic acids (HA), fulvic acids (FA), and protein-like substances, whereas isolation of Fe-DOM precipitates (Fe-DOM_P) and their biochemical characteristics remain unclear. In this work FeCl₃ was used to isolate DOM components from various sources, including river, lake, soil, cow dung, and standard tryptophan and tyrosine, through precipitation at pH 7.5-8.5. The Fe-DOM_P contribute to total DOM by approximately 38.6-93.8% of FA, 76.2% of HA and 25.0-30.4% of tryptophan and tyrosine, whilst fluorescence spectra allowed to monitor/discriminate the various DOM fractions in the samples. The relative intensity of the main infrared peaks such as 3406‒3383 cm^-1 (aromatic OH), 16

SUBMITTER: Zhang J 

PROVIDER: S-EPMC10027667 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature