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A Family of Bisnaphthyl C₂-Symmetric and Asymmetric Clefts: Synthesis, Solid-State Structure, and Calculation of the Interplanar Angle.

ABSTRACT: The synthesis of a new family of naphthalenoid C₂-symmetric clefts has been realized through a four-step synthetic sequence giving three C₂-symmetric clefts and a rare nonsymmetric example. Subsequently, stereoselective reduction of the carbonyl groups at C-8 and C-16 then provides cleft molecules with hydrogen bonding potential. Using single-crystal X-ray and computational analysis, the cleft angle of the dione has been determined.

SUBMITTER: Mohammed Elgadi GS

PROVIDER: S-EPMC10028689 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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A Family of Bisnaphthyl C₂-Symmetric and Asymmetric Clefts: Synthesis, Solid-State Structure, and Calculation of the Interplanar Angle.

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A Family of Bisnaphthyl C2-Symmetric and Asymmetric Clefts: Synthesis, Solid-State Structure, and Calculation of the Interplanar Angle.

OmicsDI is part of the ELIXIR infrastructure

Tweets

A Family of Bisnaphthyl C₂-Symmetric and Asymmetric Clefts: Synthesis, Solid-State Structure, and Calculation of the Interplanar Angle.