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Closed-loop recyclable plastics from poly(ethyl cyanoacrylate)


ABSTRACT: Ethyl cyanoacrylate is a highly reactive monomer that has been used nearly exclusively to make Super Glue and related fast-setting adhesives. Here, we describe transformation of this highly abundant, readily available monomer into a closed-loop recyclable plastic that could supplant currently used (and often unrecycled/unrecyclable) plastics, such as poly(styrene). We report polymerization conditions, plastic-processing methods, and plastic-recycling protocols for poly(ethyl cyanoacrylate) plastics that make the Super Glue monomer a viable starting material for a next generation of closed-loop recyclable plastics. The processes described are scalable, and the plastics can be recycled in a closed-loop process with >90% yields, even when combined with a heterogeneous mixture of other types of plastic. Description Super Glue has been converted into a highly recyclable plastic with properties that are reminiscent of poly(styrene).

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PROVIDER: S-EPMC10032590 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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