Unraveling a bifunctional mechanism for methanol-to-formate electro-oxidation on nickel-based hydroxides.

ABSTRACT: For nickel-based catalysts, in-situ formed nickel oxyhydroxide has been generally believed as the origin for anodic biomass electro-oxidations. However, rationally understanding the catalytic mechanism still remains challenging. In this work, we demonstrate that NiMn hydroxide as the anodic catalyst can enable methanol-to-formate electro-oxidation reaction (MOR) with a low cell-potential of 1.33/1.41 V at 10/100 mA cm^-2, a Faradaic efficiency of nearly 100% and good durability in alkaline media, remarkably outperforming NiFe hydroxide. Based on a combined experimental and computational study, we propose a cyclic pathway that consists of reversible redox transitions of Ni^II-(OH)₂/Ni^III-OOH and a concomitant MOR. More importantly, it is proved that

SUBMITTER: Zhu B 

PROVIDER: S-EPMC10042884 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature