Cu₃As: Uncommon Crystallographic Features, Low-Temperature Phase Transitions, Thermodynamic and Physical Properties.

ABSTRACT: The formation and crystal structure of the binary Cu₃As phase have been re-investigated. Some physical properties were then measured on both single crystal and polycrystalline bulk. Cu₃As melts congruently at 835 °C. At room temperature (RT), this compound has been found to crystallize in the hexagonal Cu₃P prototype (hP24, P63cm) with lattice parameters: a = 7.1393(1) Å and c = 7.3113(1) Å, rather than in the anti HoH₃-type (hP24, P-3c1) as indicated in literature. A small compositional range of 74.0-75.5 at.% Cu (26.0-24.5 at.% As) was found for samples synthesized at 300 and 400 °C; a corresponding slight understoichiometry is found in one out of the four Cu atomic sites, leading to the f

SUBMITTER: Modlinger M 

PROVIDER: S-EPMC10051385 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature