Structural Evolution and Properties of Praseodymium Antimony Oxochlorides Based on a Chain-like Tertiary Building Unit.

ABSTRACT: Unveiling the structural evolution of single-crystalline compounds based on certain building units may help greatly in guiding the design of complex structures. Herein, a series of praseodymium antimony oxohalide crystals have been isolated under solvothermal conditions via adjusting the solvents used, that is, [HN(CH₂CH₃)₃][Fe^II(2,2'-bpy)₃][Pr₄Sb₁₂O₁₈Cl₁₅]·EtOH (1) (2,2'-bpy = 2,2'-bipyridine), [HN(CH₂CH₃)₃][Fe^II(2,2'-bpy)₃]₂[Pr₄Sb₁₂O₁₈Cl₁₄)₂Cl]·N(CH₂CH₃)₃·2H₂O (2), and (H₃O)[Pr₄Sb₁₂

SUBMITTER: Wen WY 

PROVIDER: S-EPMC10051633 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature