Enhanced Desulfurization by Tannin Extract Absorption Assisted by Binuclear Sulfonated Phthalocyanine Cobalt Polymer: Performance and Mechanism.

ABSTRACT: Removal of hydrogen sulfide (H₂S) from coke oven gas has attracted increasing attention due to economic and environmental concerns. In this study, tannin extract (TE) absorption combined with binuclear sulfonated phthalocyanine cobalt organic polymer (OTS) and binuclear sulfonated phthalocyanine cobalt (PDS) with a fixed bed reactor is used for removal of H₂S. The effect of gas flow rate, concentration of H₂S, co-existence of organic sulfide compounds and O₂ were investigated. Then, the effect of total alkalinity content of TE, NaVO₃, OTS and PDS was studied in detail. The experimental results demonstrated that 100% H₂S conversion could maintain for 13 h at a total alkalinity of 5.0 g/L, TE concentration of 4.0 g/L, NaVO

SUBMITTER: Wang B 

PROVIDER: S-EPMC10057467 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature