Insights into the Role of Nanorod-Shaped MnO₂ and CeO₂ in a Plasma Catalysis System for Methanol Oxidation.

ABSTRACT: Published papers highlight the roles of the catalysts in plasma catalysis systems, and it is essential to provide deep insight into the mechanism of the reaction. In this work, a coaxial dielectric barrier discharge (DBD) reactor packed with γ-MnO₂ and CeO₂ with similar nanorod morphologies and particle sizes was used for methanol oxidation at atmospheric pressure and room temperature. The experimental results showed that both γ-MnO₂ and CeO₂ exhibited good performance in methanol conversion (up to 100%), but the CO₂ selectivity of CeO₂ (up to 59.3%) was much higher than that of γ-MnO₂ (up to 28.6%). Catalyst characterization results indicated that CeO₂ contained more surface-active oxygen species, adsorbed more methanol and utilized more plasma-induced active species than γ-MnO₂. In addition, in situ Raman spectroscopy and Fourier transform infrared spectroscopy (FT-IR) were applied with a novel in situ cell to reveal the major factors affecting the catalytic performance in methanol oxidation. More reactive oxygen species (O₂^2-, O^2-) from ozone decomposition were produced on CeO₂ compared with γ-MnO₂, and less of the intermediate product formate accumulated on the CeO₂. The combined results showed that CeO₂ was a more effective catalyst than γ-MnO₂ for methanol oxidation in the plasma catalysis system.

SUBMITTER: Zhang G 

PROVIDER: S-EPMC10057529 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature