Synthesis of Sulfonated Polyphenylene Block Copolymers via In Situ Generation of Ni(0).

ABSTRACT: Proton exchange membranes (PEMs) fabricated from sulfonated polyphenylenes (sPP) exhibit superior proton conductivity and electrochemical performance. However, the Ni(0) catalyst required for Colon's cross-coupling reaction for the synthesis of sPP block copolymers is expensive. Therefore, in this study, we generated Ni(0) in situ from an inexpensive Ni(II) salt in the presence of the reducing metal Zn and NaI. The sPP block copolymers were synthesized from neopentyl-protected 3,5- and 2,5-dichlorobenzenesulfonates and oligo(arylene ether ketone) using the catalyst NiBr₂(PPh₃)₂. The block copolymers synthesized using our strategy and the Ni(0) catalyst exhibited comparable polydispersity index values and high molecular weights. Thin, transparent, and bendab

SUBMITTER: Yadav V 

PROVIDER: S-EPMC10058434 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature