Dataset Information

Partial Miscibility and Concentration Distribution of Two-Phase Blends of Crosslinked NBR and PVC.

ABSTRACT: We found that the blends of nitrile butadiene rubber (NBR) and polyvinyl chloride (PVC) exhibited lower critical solution temperature (LCST)-type phase behavior in which a single-phase blend tends to phase separate at elevated temperatures when the acrylonitrile content of NBR was 29.0%. The tan δ peaks, which originated from the glass transitions of the component polymers measured by dynamic mechanical analysis (DMA), were largely shifted and broader in the blends when the blends were melted in the two-phase region of the LCST-type phase diagram, suggesting that NBR and PVC are partially miscible in the two-phase structure. The TEM-EDS elemental mapping analysis using a dual silicon drift detector revealed that each component polymer existed in the partner polymer-rich phase, and the PVC-rich domains consisted of aggregated small PVC particles the size of several ten nanometers. The partial miscibility of the blends was explained by the lever rule for the concentration distribution in the two-phase region of the LCST-type phase diagram.

SUBMITTER: Komori Y

PROVIDER: S-EPMC10058492 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature

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Partial Miscibility and Concentration Distribution of Two-Phase Blends of Crosslinked NBR and PVC.

Komori Yuka Y Taniguchi Aoi A Shibata Haruhisa H Goto Shinya S Saito Hiromu H

Polymers 20230310 6

We found that the blends of nitrile butadiene rubber (NBR) and polyvinyl chloride (PVC) exhibited lower critical solution temperature (LCST)-type phase behavior in which a single-phase blend tends to phase separate at elevated temperatures when the acrylonitrile content of NBR was 29.0%. The tan <i>δ</i> peaks, which originated from the glass transitions of the component polymers measured by dynamic mechanical analysis (DMA), were largely shifted and broader in the blends when the blends were me ...[more]

PMID: 36987164

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Project description:The addition of polyethylene glycol (PEG) chains to poly(lactic-co-glycolic acid) (PLGA) matrices is extensively used to modulate the biodegradation, drug loading and release, mechanical properties, and chemical stability of the original system. Multiple parameters, including the molecular weight, relative concentration, polarity, and solubility, affect the physicochemical properties of the polymer blend. Here, molecular dynamics simulations with the united-atom 2016H66 force field are used to model the behavior of PLGA and PEG chains and thus predict the overall physicochemical features of the resulting blend. First, the model accuracy is validated against fundamental properties of pure PLGA and PEG samples. In agreement with previous experimental and theoretical observations, the PLGA solubility results to be higher in acetonitrile than in water, with Flory parameters νACN = 0.63 ± 0.01 and νW = 0.21 ± 0.02, and the Young's modulus of PLGA and PEG equal to Y = 2.0 ± 0.43 and 0.32 ± 0.34 GPa, respectively. Next, four PEG/PLGA blending regimes are identified by varying the relative concentrations and molecular weights of the individual polymers. The computational results demonstrate that at low PEG concentrations (<8% w/w), homogeneous blends are generated for both low and high PEG molecular weights. In contrast, at comparable PEG and PLGA concentrations (∼50% w/w), short PEG chains are only partially miscible whereas long PEG chains segregate within the PLGA matrix. This behavior has been confirmed experimentally via differential scanning calorimetry and is in agreement with previous observations. Finally, the computed Young's modulus of PLGA/PEG blends is observed to decrease with the PEG content returning the lowest values for the partial and fully segregated regimens (Y ≈ 1.3 GPa). This work proposes a computational scheme for predicting the physicochemical properties of PLGA/PEG blends paving the way toward the rational design of polymer mixtures for biomedical applications.

Dataset Information

Partial Miscibility and Concentration Distribution of Two-Phase Blends of Crosslinked NBR and PVC.

Publications

Partial Miscibility and Concentration Distribution of Two-Phase Blends of Crosslinked NBR and PVC.

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