Magnetostructural Properties of Some Doubly-Bridged Phenoxido Copper(II) Complexes.

ABSTRACT: Three new tripod tetradentate phenolate-amines (H₂L¹, H₂L⁴ and H₂L⁹), together with seven more already related published ligands, were synthesized, and characterized. With these ligands, two new dinuclear doubly-bridged-phenoxido copper(II) complexes (3, 4), and six more complexes (1, 2, 5-8), a new trinuclear complex (9) with an alternative doubly-bridged-phenoxido and -methoxido, as well as the 1D polymer (10) were synthesized, and their molecular structures were characterized by spectroscopic methods and X-ray single crystal crystallography. The Cu(II) centers in these complexes exhibit distorted square-pyramidal arrangement in 1-4,

SUBMITTER: Massoud SS 

PROVIDER: S-EPMC10058975 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature