Diphenyl Diselenide-Assisted Radical Addition Reaction of Diphenyl Disulfide to Unsaturated Bonds upon Photoirradiation.

ABSTRACT: The addition reaction of interelement compounds with heteroatom-heteroatom single bonds to unsaturated bonds under photoirradiation is an important method for the efficient and atom-economical construction of carbon-heteroatom bonds. However, in practice, the desired addition reaction is sometimes unable to proceed as expected due to the low efficiency of the desired addition reactions or the preferential polymerization of unsaturated compounds. In this study, by combining an interelement compound with homologous heteroatom compounds as a catalyst, we succeeded in suppressing the polymerization of the unsaturated compounds and in attaining a highly selective carbon-heteroatom bond formation through the desired addition reaction. In this paper, we have examined in detail whether such a "cat

SUBMITTER: Yamamoto Y 

PROVIDER: S-EPMC10059204 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature