An electron-hole rich dual-site nickel catalyst for efficient photocatalytic overall water splitting.

ABSTRACT: Photocatalysis offers an attractive strategy to upgrade H₂O to renewable fuel H₂. However, current photocatalytic hydrogen production technology often relies on additional sacrificial agents and noble metal cocatalysts, and there are limited photocatalysts possessing overall water splitting performance on their own. Here, we successfully construct an efficient catalytic system to realize overall water splitting, where hole-rich nickel phosphides (Ni₂P) with polymeric carbon-oxygen semiconductor (PCOS) is the site for oxygen generation and electron-rich Ni₂P with nickel sulfide (NiS) serves as the other site for producing H₂. The electron-hole rich Ni₂P based photocatalyst exhibits fast kinetics and a low thermodynamic energy

SUBMITTER: Yan X 

PROVIDER: S-EPMC10060254 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature