The role of Pb oxidation state of the precursor in the formation of 2D perovskite microplates.

ABSTRACT: Two-dimensional (2D) lead halide perovskites are an exciting class of materials currently being extensively explored for photovoltaics and other optoelectronic applications. Their ionic nature makes them ideal candidates for solution processing into both thin films and nanostructured crystals. Understanding how 2D lead halide perovskite crystals form is key towards full control over their physical properties, which may enable new physical phenomena and devices. Here, we investigate the effects of the Pb oxidation state of the initial inorganic precursor on the growth of pure-phase (n = 1) - Popper 2D perovskite BA₂PbI₄ in single-step synthesis. We examine the different crystallisation routes in exposing PbO₂ and PbI₂ powders to a BAI : IPA

SUBMITTER: Antony LSD 

PROVIDER: S-EPMC10065060 | biostudies-literature | 2023 Mar

REPOSITORIES: biostudies-literature