One-step removal of hexavalent chromium in wide pH range using thiourea dioxide: the role of reactive species.

ABSTRACT: One-step removal of hexavalent chromium in a wide pH range is of great significance. In this paper, a single thiourea dioxide (TD) and two-components thiourea dioxide/ethanolamine (MEA) were used as a green reducing agent for the efficient removal of Cr(vi), respectively. The reduction of Cr(vi) and the precipitation of Cr(iii) were carried out simultaneously under this reaction system. The experimental results proved that TD was activated by amine exchange reaction with MEA. In other words, MEA promoted the generation of an active isomeride of TD by changing the equilibrium position of the reversible reaction. After adding MEA, the removal rate of Cr(vi) and total Cr could reach industrial water discharge standards in a wide pH range of 8-12. The change of pH, reduction potential and the

SUBMITTER: Lei B 

PROVIDER: S-EPMC10072199 | biostudies-literature | 2023 Apr

REPOSITORIES: biostudies-literature